Patent classifications
C08G18/755
METHODS AND COMPOSITIONS FOR PRODUCING GRAPHENE POLYURETHANE FOAMS
Provided herein is a method of producing a polyurethane foam. The method includes dispersing turbostratic graphene in a polymerization solution. The polymerization solution includes a first component for polymerization into a polymer. The method includes adding a second component for polymerizing with the first component to chemically convert the polymerization solution into a polyurethane foam. Provided herein is also a polyurethane foam which includes a turbostratic graphene and a polymer formed from the polymerization of a polyol with an isocyanate. Provided herein is also a turbostratic graphene dispersion which includes a turbostratic graphene and a solvent for dispersing the turbostratic graphene.
AQUEOUS DISPERSION COMPRISING POLYURETHANE OR POLYURETHANE-UREA, PREPARATION METHOD THEREFOR AND USE THEREOF
Aqueous dispersion comprising polyurethane or polyurethane-urea, a preparation method therefor and a use thereof. The polyurethane or polyurethane-urea is prepared by reacting raw materials comprising the following components: a compound having a tertiary amine group and at least one NCO reactive functional group, a polyester polyol having a number average molecular weight of 400 to 5000 and a functionality of 2 to 3, an organic compound having at least two isocyanate groups, a hydrophilic compound having one or more of an ionic group, a potential ionic group and a non-ionic group and having 2 to 3 NCO reactive functional groups, and a mono-functional non-ionic hydrophilic compound having at least one NCO reactive functional group. The aqueous dispersion can be stably stored for a prolonged period of time, and an adhesive prepared from the aqueous dispersion has an improved hydrolysis resistance while maintaining good bonding strength and heat resistance.
RESIN COMPOSITION, METHOD FOR PRODUCING RESIN COMPOSITION, OPTICAL FIBER, AND METHOD FOR PRODUCING OPTICAL FIBER
The method for producing a resin composition for a secondary coating of an optical fiber comprises a step of reacting a polyol, a diisocyanate and a hydroxyl group-containing (meth)acrylate in the presence of a (meth)acrylate not having a hydroxyl group to obtain a mixture of urethane (meth)acrylate and the (meth)acrylate not having a hydroxyl group, and a step of adding a photopolymerization initiator to the mixture to obtain a resin composition, and a hydroxyl value of the (meth)acrylate not having a hydroxyl group is 12.0 mgKOH/g or less.
Photopolymerizable compositions including a urethane component and a reactive diluent, articles, and methods
The present disclosure provides a photopolymerizable composition comprising 50-90 wt % of at least one urethane component, 5-50 wt % of at least one reactive diluent, 0.1-5 wt % of a photoinitiator, and optionally an inhibitor, wherein said composition has a viscosity at a temperature of 40 degrees Celsius of 10 Pa.Math.s or less, as determined using a magnetic bearing rheometer using a 40 mm cone and plate measuring system at a shear rate of 0.1 l/s. The present disclosure also provides an article including the reaction product of the photopolymerizable composition, in which the article exhibits an elongation at break of 25% or greater. Further, the present disclosure provides a method of making an article including (i) providing a photopolymerizable composition and (ii) selectively curing the photopolymerizable composition to form an article. The method optionally also includes (iii) curing unpolymerized urethane component and/or reactive diluent remaining after step (ii). Further, methods are provided, including receiving, by a manufacturing device having one or more processors, a digital object comprising data specifying an article; and generating, with the manufacturing device by an additive manufacturing process, the article based on the digital object. A system is also provided, including a display that displays a 3D model of an article; and one or more processors that, in response to the 3D model selected by a user, cause a 3D printer to create a physical object of an article.
Single-component polysiloxane non-skid / non-slip coatings
Disclosed is a composition having: an organosilane polymer, a polyamide polymer; and an abrasive aggregate. The organosilane is made by: reacting an amino-functional alkoxysilane with one or more polyisocyanates to form one or more adducts having an unreacted isocyanate group; and reacting the adducts with one or more polyfunctional amino- and/or hydroxyl compounds so that the polymer contains no unreacted isocyanate groups. The polyfunctional amino- and/or hydroxyl compound has a cycloaliphatic group or an aromatic group. The composition can be used to make a single-component polysiloxane non-skid/non-slip coating that is applied by rolling, spraying, or troweling and cures with atmospheric moisture.
HIGH THROUGHPUT MANUFACTURE OF POLYURETHANE FOAM LAYERS
Described is an at least partly continuous process for making polyurethane foam layers that are suitable for medical applications, in particular in wound dressings, at a high throughput rate. The described process includes a step of accelerated curing of the polyurethane foam performed at a stage of the overall curing process at which the risk of a run-away reaction is minimized.
RETORT ADHESIVE COMPOSITION
A solvent-based polyurethane retort adhesive composition for producing laminates including: (A) at least one isocyanate compound, Component A; and (B) at least one isocyanate (NCO)-reactive component, Component B, comprising (i) at least one phosphate ester compound and (ii) at least one polyester polyol having an average molecular weight of greater than 3,000 g/mol; a process for producing the above adhesive; a multi-layer laminate product including the above adhesive; and a process for producing a laminate product using the above adhesive.
PHOSPHONIUM-CONTAINING POLYURETHANE COMPOSITIONS
A phosphonium-containing polyurethane composition can include an aqueous liquid vehicle including water, organic co-solvent, and surfactant, and polyurethane particles including a polyurethane polymer with a polyurethane backbone. The polyurethane polymer can have pendant side chain groups along the polyurethane backbone as well as end cap groups terminating the polyurethane polymer. The pendant side chain groups and the end cap groups can collectively include aliphatic phosphonium salts and polyalkylene oxides.
RESIN COMPOSITION FOR GOLF BALL COVER
The present disclosure provides a resin composition for a golf ball cover. The resin composition includes a thermoplastic polyurethane resin including 55 to 70 parts by weight of a polyol, 30 to 40 parts by weight of an isocyanate, and 0.2 to 0.4 parts by weight of a polysiloxane. The polysiloxane includes at least one hydroxyl group or a carboxyl group in the terminal alkyl group. The polyol and the isocyanate constitute a silicone-free thermoplastic polyurethane resin, and the polysiloxane and the isocyanate constitute a thermoplastic polyurethane resin that includes silicone in the main chain, thereby improving the scuff resistance and slip property required for a golf ball cover.
METHOD OF APPLYING A ONE-COMPONENT WATERBORNE COATING COMPOSITION TO A SUBSTRATE UTILIZING A HIGH TRANSFER EFFICIENCY APPLICATOR
A method includes applying a coating composition to a substrate through a high transfer efficiency applicator wherein the coating composition has a pH of greater than about 7 and comprises: A. a resin dispersion comprising a latex, a polyurethane, or combinations thereof; B. an optional cross-linker; C. an optional pigment; D. water; E. a water-soluble solvent; and F. at least one rheology control agent chosen from an alkali swellable emulsion, a layered silicate, and combinations thereof; wherein the coating composition has a viscosity of about 20 to about 100 cps as determined using ASTM 7867-13 with cone-and-plate or parallel plates at a shear rate of 1000 sec-1, and wherein the coating composition has a wet film thickness of at least 20 microns measured at about 45 degrees without visible sag.