The present disclosure relates to compositions A composition comprising a polymerization product of an anionic polysaccharide, a diisocyanate, and a linker, wherein the linker comprises i) an ether group, an ester group, or a combination thereof and, ii) a chain extender comprising a hydroxyl group, a thiol group, an amine group, or a combination thereof. The disclosure further relates to medical devices comprising the aforementioned compositions, and to methods of using the compositions and devices. More particularly, the compositions, devices and methods described herein are useful for preventing protein adhesions in vivo, particularly the Vroman effect.

1) Ionic silylated copolyurethane of formula:

##STR00001##

in which R.sup.1 is a hydrocarbon radical; R.sup.2 is a C2-C4 alkylene; n is an integer such that the molecular mass of —[OR.sup.2].sub.n is 2500-20 000 g/mol; R.sup.∘ is H or C1-C18 alkyl; R, R′ and R″ are a hydrocarbon-based radical; x and y are integers from 1 à 8; z is an integer from 0 to 8; m and q are an integer of greater than or equal to 1, such that q/m ranges from 0.04 to 20; F.sup.1 is a radical of formula (IIa) and F.sup.2 is a radical of formula (IIb):

##STR00002## in which R.sup.3 is methylene or n-propylene; R.sup.4 and R.sup.5 are methyl or ethyl; p is equal to 0 or 1; R.sup.6 is a C1-C4 alkyl.

2) Process for preparing copolyurethane 1), comprising: (i) polyaddition between a polyisocyanate, a polyether diol and a carboxylic diol; (ii) neutralization of the product formed with the amine N(R)(R′)(R″); then (iii) reaction with an aminosilane derived from a secondary amine.

3) Composition, usable as sealant and/or adhesive, comprising copolyurethane 1) and a filler.

Provided is an aqueous coating composition which has excellent storage stability and whereby high coating film performance in terms of hardness, water resistance, etc., can be exhibited even when the aqueous coating composition is cured at a relatively low temperature. Disclosed is an aqueous coating composition which contains (A) a resin containing hydroxyl groups and carboxyl groups, (B) a blocked polyisocyanate compound, (C) a phosphate-group-containing compound, and (D) a basic compound, and which has a pH in the range of 7.0-8.2, wherein the basic compound (D) contains a specific quantity of (D1) a basic compound which has an acid dissociation constant (PKa) in the range of 7.0-8.5 and a boiling point in the range of 100-200° C.

A urethane resin composition including water, the urethane resin composition being produced using a biomass raw material and having high oleic-acid resistance, excellent low-temperature flexibility, and high peel strength. A urethane resin composition including an anionic urethane resin (X) and water (Y), in which the anionic urethane resin (X) is produced using a polyol (a) including a biomass-derived polycarbonate polyol (a1), a polyisocyanate (b), and an alkanolamine (c), as essential raw materials. Furthermore, An adhesive including the urethane resin composition and a synthetic leather having an adhesive layer formed from the adhesive.

Provided is a water-based coating composition capable of exhibiting high coating film performance even when cured at relatively low temperatures. Disclosed is a water-based coating composition including (A) a hydroxyl group-containing resin and (B) a hardener, wherein at least one type of (A) the hydroxyl group-containing resin is a hydroxyl group-containing acrylic resin particle (A1) having a core-shell structure containing a gradient polymer layer.

Described is a curable composition, and particularly a two-component composition comprising a silane modified polymer; an epoxy resin terminated with epoxy terminal group; wherein the composition further comprises a hardening-compatibilizing agent which has at least one silane group and at least two amine groups. The curable composition exhibits enhanced adhesion strength and good elongation at break. A method for applying the curable composition on the surface of a substrate is also provided.

A polymerizable composition according to an embodiment includes a first polymerizable compound including isophorone diisocyanate and hexamethylene diisocyanate, and a second polymerizable compound including 4-mercaptomethyl-3,6-dithia-1,8-octanedithiol and pentaerythritol tetrakis(mercaptoacetate). An optical material which is fabricated from the polymerizable composition and has improved optical, mechanical and thermal properties is provided.

A thermally-conductive structural adhesive for new energy power batteries, including: composition A including 3.3-14 wt. % of a block polymerized telechelic carboxyl compound and/or a block polymerized telechelic amino compound; 0.1-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3.0 wt. % of a flame retardant agent; and composition B including 3.3-14 wt. % of a block polymerized telechelic isocyanate compound and/or a block polymerized telechelic epoxy compound; 0-1.0 wt. % of a coupling agent and/or a modifier; 0-1.6 wt. % of a curing accelerator; 84-92 wt. % of a thermally-conductive powder; and 0.3-3 wt. % of a flame retardant agent. The composition A and the composition B are mixed evenly in a weight or volume ratio of 1:(0.25-2) and cured to obtain the thermally-conductive structural adhesive. A preparation of the thermally-conductive structural adhesive is also provided.

A mixture of water-emulsifiable isocyanates is described. The mixture contains (A) at least one polyisocyanate (a), (B) at least one emulsifier obtained by reacting at least one polyisocyanate with at least one polyether alcohol having a molecular weight of less than 400 g/mol, (C) at least one emulsifier obtained by reacting at least one polyisocyanate with at least one polyether alcohol having a molecular weight of greater than 450 g/mol, and (D) optionally at least one emulsifier obtained by reacting a polyisocyanate with at least one compound (d) having at least one hydrophilic, non-isocyanate-reactive group and precisely one isocyanate-reactive group (group D2). The weight ratio of component (B) to component (C) in the mixture is from 30:70 to 70:30, preferably from 40:60 to 60:40.

Adhesion promoter compositions, containing: a) between 40 and 80 parts by weight of a binder composition, including i) 20-40 wt % of at least one silane-terminated polyurethane polymer STP, which can be obtained from at least one polyol P, aliphatic polyisocyanate I and organosilane OS1, ii) 4-20 wt % of at least one organosilane OS2 and/or organotitanate OT, iii) 0-3 wt % of at least one desiccant, iv) 40-80 wt % of solvent L1; b) between 0-30 parts by weight of industrial carbon black; c) between 0-1 parts by weight of UV marker; d) so much of solvent L2 that sum of a)-d) is 100 parts by weight; OS1 having secondary amino, mercapto or hydroxyl group on organic moiety and the at least one STP having been produced in absence of OS2, and the at least one P having an average OH functionality of at least 2 and equivalent weight of at most 500.