The present disclosure provides a polymeric material including a polymerized reaction product of a polymerizable composition including components and has a solids content of 90% or greater. The components include a uretdione-containing material including a reaction product of a diisocyanate reacted with itself; a first hydroxyl-containing compound; an optional second hydroxyl-containing compound having a single OH group, wherein; and an epoxy component. The first hydroxyl-containing compound has more than one OH group and the optional second hydroxyl-containing compound is a primary alcohol or a secondary alcohol. The present disclosure also provides a two-part composition, in which the polymeric material is included in the first part and the second part includes at least one amine. Further, a method of adhering two substrates is provided, including obtaining a two-part composition; combining at least a portion of the first part with at least a portion of the second part to form a mixture; disposing at least a portion of the mixture on a first substrate; and contacting a second substrate with the mixture disposed on the first substrate. The disclosure also provides a polymeric material and a method of making a two-part composition. Advantageously, two-part compositions according to the present disclosure can be used as coatings and adhesive systems with handling and performance similar to existing two-part urethane systems, but with less sensitivity to water.

A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Provided is a method for producing a resin lens, comprising: A) mixing a polyisocyanate, a modified isocyanate, a catalyst and a release agent, and performing vacuum defoaming at 0˜30° C. for 10˜90 min to obtain a material a; B) mixing the material a with a sulfur-containing compound, and performing vacuum defoaming at 15˜20° C. for 20˜120 min to obtain mixed monomers; and C) completing casting of the mixed monomers, and curing to obtain a resin lens. The present disclosure uses polyisocyanate and a modified isocyanate at the same time to prepare a resin lens with higher glass transition temperature and higher surface hardness without producing bank mark and edge fogging. The present disclosure further provides a method for producing modified isocyanate. The obtained modified isocyanate used with polyisocyanate further improves the glass transition temperature and surface hardness of the resin lens without producing bank mark and edge fogging.

The present invention relates to a coating composition, a coating system comprising the coating composition, a coating method and application of the coating system, and a product coated with the coating system. The coating composition comprises: (A) at least one aqueous polyurethane dispersion and/or one aqueous polyacrylate dispersion, wherein the aqueous polyurethane dispersion comprises at least one polyurethane polymer (a), wherein the polyurethane polymer (a) is obtained by a reaction comprising at least one polyurethane prepolymer (a1) and at least one isocyanate-reactive component (a2), wherein the polyurethane prepolymer (a1) is obtained by a reaction comprising the following components: (a1-1) at least one polyisocyanate having an isocyanate functionality of no less than 2, and (a1-2) at least one polyfunctional polyether polyol having a hydroxyl functionality of no less than 3, wherein the polyfunctional polyether polyol has an amount of 1 wt % to 20 wt %, based on the amount of the components for preparing the polyurethane prepolymer being 100 wt %, and (B) at least one crosslinking agent.

Provided is a compound capable of forming a coating layer that has excellent scratch resistance and still has stain resistance (in particular, stain resistance against hair dyes) and workability (impact resistance) both at satisfactory levels. The urethane (meth)acrylate has a cyclic structure in a molecule. The urethane (meth)acrylate has a total weight of carbon, oxygen, nitrogen, and sulfur atoms constituting the ring or rings of the cyclic structure of 10 percent by weight or more based on the total amount (100 percent by weight) of the urethane (meth)acrylate. The urethane (meth)acrylate also has an average number of functional groups of 3.5 to 4.5.

A method of forming a three-dimensional object comprises the steps of forming a layer of a particulate composition, selectively depositing a liquid composition onto the layer of the particulate composition in accordance with computer data corresponding to the shape of at least a portion of a three-dimensional object, initiating polymerization, and repeating the steps a plurality of times to form a three-dimensional object. The particulate composition comprises a plurality of first particles that comprise a resin component comprising a first resin, the first resin comprising a first resin polymerizable group, the first resin polymerizable group comprising a carbon-carbon double bond directly attached to an electron withdrawing group, a thermal radical initiator dispersed or dissolved in the resin component, and a retardant dispersed or dissolved in the resin component.

Provided are a method of preparing a polyurethane prepolymer with high functionality and the polyurethane prepolymer with high functionality prepared therefrom and a curing agent comprising the same. The method includes the steps of: Step (A): providing an alcohol composition comprising a first polyol having 2 or 3 OH groups and a second polyol having 4 or more OH groups; Step (B): reacting the alcohol composition with a polyisocyanate to undergo a first polymerization, so as to obtain an intermediate; wherein a molar ratio of a total number of the OH groups of the alcohol composition to a total number of NCO groups of the polyisocyanate is from 1:2 to 1:6; and Step (C): adding a catalyst to carry out a second polymerization of the intermediate to obtain the polyurethane prepolymer with high functionality, which has four or more NCO groups.

This invention relates to a surface-deactivated solid polyisocyanate and a thermally curable adhesive composition comprising the same, which are suitable for assembling articles of various substrates such as plastic materials. In particular, the present invention relates to a surface-deactivated solid polyisocyanate and a thermally curable adhesive composition comprising the same which is storage stable at room temperature, can be cured at a temperature lower than 100 C. and meanwhile have excellent adhesion and mechanical properties when cured.

Pultrusion processes for producing fiber reinforced polyurethane composites are described. The processes utilize a polyurethane-forming reaction mixture comprises a chelated organometallic/metalorganic catalyst. Polyurethane-forming reaction mixtures suitable for use in such processes are also described.

A curable resin composition comprises a (meth)acrylic polyol, a polycarbonate-based polyol, and a polyisocyanate. The (meth)acrylic polyol includes a polymer having a hydroxyl value of 5 mg KOH/g or more and 150 mg KOH/g or less, a glass transition temperature of 70 C. or more and 40 C. or less, and a number average molecular weight of 500 or more and 20000 or less, and which is liquid at 25 C. An electrical component (1) comprises a sealing material (2) including a cured product of the curable resin composition.