A Mg compound based catalyst precursor made from or containing up to 50% by mols, with respect to Mg, of a compound of formula K(OR.sup.1) wherein R.sup.1 is H or a C.sub.1-C.sub.10 hydrocarbon group. When treated with transition metal compounds, the precursor is converted into catalyst with high activity in olefin polymerization.

A Mg compound based catalyst precursor made from or containing up to 50% by mols, with respect to Mg, of a compound of formula K(OR.sup.1) wherein R.sup.1 is H or a C.sub.1-C.sub.10 hydrocarbon group. When treated with transition metal compounds, the precursor is converted into catalyst with high activity in olefin polymerization.

Disclosed is a method for preparing a solid catalyst capable of controlling a molecular weight distribution and polydispersity according to an organic compound as used in a polymerization reaction, in which the solid catalyst contains titanium tetrachloride and a diester or diether organic compound. The catalyst having excellent polymerization activity, and allowing uniform particle size and high apparent density of the ultra-high molecular weight polyethylene, and easily controlling the molecular weight distribution and polydispersity of the ultra-high molecular weight polyethylene may be prepared simply and efficiently.

Disclosed is a method for preparing a solid catalyst capable of controlling a molecular weight distribution and polydispersity according to an organic compound as used in a polymerization reaction, in which the solid catalyst contains titanium tetrachloride and a diester or diether organic compound. The catalyst having excellent polymerization activity, and allowing uniform particle size and high apparent density of the ultra-high molecular weight polyethylene, and easily controlling the molecular weight distribution and polydispersity of the ultra-high molecular weight polyethylene may be prepared simply and efficiently.

Disclosed is a method for preparing a titanium solid catalyst supported on magnesium dichloride that may be used to prepare ultra-high molecular weight polyethylene having a high apparent density. Performing a polymerization reaction using a solid catalyst containing titanium tetrachloride and a phthalate compound may allow ultra-high molecular weight polyethylene having uniform particle size and high apparent density to be prepared.

Disclosed is a method for preparing a titanium solid catalyst supported on magnesium dichloride that may be used to prepare ultra-high molecular weight polyethylene having a high apparent density. Performing a polymerization reaction using a solid catalyst containing titanium tetrachloride and a phthalate compound may allow ultra-high molecular weight polyethylene having uniform particle size and high apparent density to be prepared.

The instant invention relates to the use of titanium-based oxopolymers for preparing suitable catalysts for reactions of olefin polymerization and/or olefin and alpha-olefin copolymerization. The instant invention further discloses the synthesis of catalyst formulated from titanium-based oxopolymers, as well as its use for olefin polymerization and/or copolymerization reactions.

The instant invention relates to the use of titanium-based oxopolymers for preparing suitable catalysts for reactions of olefin polymerization and/or olefin and alpha-olefin copolymerization. The instant invention further discloses the synthesis of catalyst formulated from titanium-based oxopolymers, as well as its use for olefin polymerization and/or copolymerization reactions.

A phthalate-free procatalyst composition is disclosed for olefin polymerization that exhibits excellent polymerization activity and response to hydrogen, and can produce a polyolefin exhibiting high stereoregularity, high melt flow rate, and desirable molecular weight distribution. The method for producing the procatalyst composition includes reaction of a magnesium support precursor with a tetravalent titanium halide and a combination of different internal electron donors. The first internal electron donor may comprise one or more substituted phenylene aromatic diester and the second internal electron donor may comprise a polyether, preferably a 1,3-diether. In one embodiment, the support precursor comprises a spherical spray crystalized MgCl.sub.2-EtOH adduct.

A phthalate-free procatalyst composition is disclosed for olefin polymerization that exhibits excellent polymerization activity and response to hydrogen, and can produce a polyolefin exhibiting high stereoregularity, high melt flow rate, and desirable molecular weight distribution. The method for producing the procatalyst composition includes reaction of a magnesium support precursor with a tetravalent titanium halide and a combination of different internal electron donors. The first internal electron donor may comprise one or more substituted phenylene aromatic diester and the second internal electron donor may comprise a polyether, preferably a 1,3-diether. In one embodiment, the support precursor comprises a spherical spray crystalized MgCl.sub.2-EtOH adduct.