The disclosed methods and apparatus improve the fabrication of solid fibers and microstructures. In many embodiments, the fabrication is from gaseous, solid, semi-solid, liquid, critical, and supercritical mixtures using one or more low molar mass precursor(s), in combination with one or more high molar mass precursor(s). The methods and systems generally employ the thermal diffusion/Soret effect to concentrate the low molar mass precursor at a reaction zone, where the presence of the high molar mass precursor contributes to this concentration, and may also contribute to the reaction and insulate the reaction zone, thereby achieving higher fiber growth rates and/or reduced energy/heat expenditures together with reduced homogeneous nucleation. In some embodiments, the invention also relates to the permanent or semi-permanent recording and/or reading of information on or within fabricated fibers and microstructures. In some embodiments, the invention also relates to the fabrication of certain functionally-shaped fibers and microstructures. In some embodiments, the invention may also utilize laser beam profiling to enhance fiber and microstructure fabrication.

The disclosed methods and apparatus improve the fabrication of solid fibers and microstructures. In many embodiments, the fabrication is from gaseous, solid, semi-solid, liquid, critical, and supercritical mixtures using one or more low molar mass precursor(s), in combination with one or more high molar mass precursor(s). The methods and systems generally employ the thermal diffusion/Soret effect to concentrate the low molar mass precursor at a reaction zone, where the presence of the high molar mass precursor contributes to this concentration, and may also contribute to the reaction and insulate the reaction zone, thereby achieving higher fiber growth rates and/or reduced energy/heat expenditures together with reduced homogeneous nucleation. In some embodiments, the invention also relates to the permanent or semi-permanent recording and/or reading of information on or within fabricated fibers and microstructures. In some embodiments, the invention also relates to the fabrication of certain functionally-shaped fibers and microstructures. In some embodiments, the invention may also utilize laser beam profiling to enhance fiber and microstructure fabrication.

The present invention relates to gels and processes for making bundles of aligned ceramic nanofibers, ceramic nanostructures made by such processes, and methods of using such ceramic nanostructures. Such process is templated via block copolymer self-assembly but does not require any post processing thermal and/or solvent annealing steps. As a result, such process is significantly more efficient and scalable than other processes that are templated via block copolymer self-assembly. The resulting fibers are aligned according to the direction of deposition, making steps where individual fibers are bundled unnecessary.

The present invention relates to gels and processes for making bundles of aligned ceramic nanofibers, ceramic nanostructures made by such processes, and methods of using such ceramic nanostructures. Such process is templated via block copolymer self-assembly but does not require any post processing thermal and/or solvent annealing steps. As a result, such process is significantly more efficient and scalable than other processes that are templated via block copolymer self-assembly. The resulting fibers are aligned according to the direction of deposition, making steps where individual fibers are bundled unnecessary.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a geometric arrangement is described. A method for producing such a filament is also described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of a filament or fiber with a wide range of applications. A method is also described for including an interior thread that adds structural reinforcement or functional properties, such as electrical conductivity or optical waveguiding, to the filament.

A thermoplastic filament comprising multiple polymers of differing flow temperatures in a geometric arrangement is described. A method for producing such a filament is also described. Because of the difference in flow temperatures, there exists a temperature range at which one polymer is mechanically stable while the other is flowable. This property is extremely useful for creating thermoplastic monofilament feedstock for three-dimensionally printed parts, wherein the mechanically stable polymer enables geometric stability while the flowable polymer can fill gaps and provide strong bonding and homogenization between deposited material lines and layers. These multimaterial filaments can be produced via thermal drawing from a thermoplastic preform, which itself can be three-dimensionally printed. Furthermore, the preform can be printed with precisely controlled and complex geometries, enabling the creation of a filament or fiber with a wide range of applications. A method is also described for including an interior thread that adds structural reinforcement or functional properties, such as electrical conductivity or optical waveguiding, to the filament.

A process, for example a continuous process, for making an oral care article of manufacture containing a fibrous composition, for example a composite structure, and more particularly to a process for making an oral care article of manufacture containing a fibrous composition, such as a soluble fibrous composition, containing soluble filaments is provided.

A process, for example a continuous process, for making an oral care article of manufacture containing a fibrous composition, for example a composite structure, and more particularly to a process for making an oral care article of manufacture containing a fibrous composition, such as a soluble fibrous composition, containing soluble filaments is provided.

Provided is an eco-friendly filament using a biomass manufactured by extruding a bioplastic pellet which is formed from a bioplastic pellet composition including mixed particles including a coffee byproduct with a fatty acid content of 0.01 to 2.5 wt % or less and inorganic particles and having a size of 50 μm or less; an additive; and a plastic raw material. The inorganic particles are one or more selected from the group consisting of calcium carbonate, silica, starch, alumina, titanium dioxide, talc, kaolin, mica, sericite, zinc oxide, barium carbonate, barium sulfate, diatomaceous earth, magnesium carbonate, magnesium silicate, boron nitride, alumina, zirconium oxide, iron oxide and mica titanium. The additive is one or more selected from the group consisting of an amide-based active compound, copolyamide, ethyl methane sulfonate (EMS), ethylene bis stearamide (EBS), and D-sorbitol.

Provided is an eco-friendly filament using a biomass manufactured by extruding a bioplastic pellet which is formed from a bioplastic pellet composition including mixed particles including a coffee byproduct with a fatty acid content of 0.01 to 2.5 wt % or less and inorganic particles and having a size of 50 μm or less; an additive; and a plastic raw material. The inorganic particles are one or more selected from the group consisting of calcium carbonate, silica, starch, alumina, titanium dioxide, talc, kaolin, mica, sericite, zinc oxide, barium carbonate, barium sulfate, diatomaceous earth, magnesium carbonate, magnesium silicate, boron nitride, alumina, zirconium oxide, iron oxide and mica titanium. The additive is one or more selected from the group consisting of an amide-based active compound, copolyamide, ethyl methane sulfonate (EMS), ethylene bis stearamide (EBS), and D-sorbitol.