D02G3/02

HIGH-PERFORMANCE POLYETHYLENE MULTIFILAMENT YARN

Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DR.sub.fluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DR.sub.solid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DR.sub.fluid=DR.sub.sp*DR.sub.ag of at least 150, wherein DR.sub.sp is the draw ratio in the spinholes and DR.sub.ag is the draw ratio in the air-gap, with DR.sub.sp being greater than 1 and DR.sub.ag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.

HIGH-PERFORMANCE POLYETHYLENE MULTIFILAMENT YARN

Processes for making high-performance polyethylene multi-filament yarn are disclosed which include the steps of a) making a solution of ultra-high molar mass polyethylene in a solvent; b) spinning of the solution through a spinplate containing at least 5 spinholes into an air-gap to form fluid filaments, while applying a draw ratio DR.sub.fluid; c) cooling the fluid filaments to form solvent-containing gel filaments; d) removing at least partly the solvent from the filaments; and e) drawing the filaments in at least one step before, during and/or after said solvent removing, while applying a draw ratio DR.sub.solid of at least 4, wherein in step b) each spinhole comprises a contraction zone of specific dimension and a downstream zone of diameter Dn and length Dn with Ln/Dn of from 0 to at most 25, to result in a draw ratio DR.sub.fluid=DR.sub.sp*DR.sub.ag of at least 150, wherein DR.sub.sp is the draw ratio in the spinholes and DR.sub.ag is the draw ratio in the air-gap, with DR.sub.sp being greater than 1 and DR.sub.ag at least 1. High-performance polyethylene multifilament yarn, and semi-finished or end-use products containing said yarn, especially to ropes and ballistic-resistant composites, are also disclosed.

POLYESTER YARN FOR INDUSTRIAL SEWING THREAD AND PREPARING METHOD THEREOF

A type of polyester yarn for an industrial sewing thread and preparing method thereof are provided. The preparing method is composed of a viscosity enhancing by a solid state polycondensation and a melt spinning for a modified polyester, and the modified polyester is a product of esterification and polycondensation of evenly mixed terephthalic acid, ethylene glycol, tert-butyl branched dicarboxylic acid, trimethylsilyl branched diol and a doped Sb.sub.2O.sub.3 powder, wherein the tert-butyl branched dicarboxylic acid is selected from the group consisting of 5-tert-butyl-1,3-benzoic acid, 2-tert-butyl-1,6-hexanedioic acid, 3-tert-butyl-1,6-hexanedioic acid and 2,5-di-tert-butyl-1,6-hexanedioic acid. Moreover, the modified polyester is dispersed with a doped ZrO.sub.2 powder. An obtained fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months.

POLYESTER YARN FOR INDUSTRIAL SEWING THREAD AND PREPARING METHOD THEREOF

A type of polyester yarn for an industrial sewing thread and preparing method thereof are provided. The preparing method is composed of a viscosity enhancing by a solid state polycondensation and a melt spinning for a modified polyester, and the modified polyester is a product of esterification and polycondensation of evenly mixed terephthalic acid, ethylene glycol, tert-butyl branched dicarboxylic acid, trimethylsilyl branched diol and a doped Sb.sub.2O.sub.3 powder, wherein the tert-butyl branched dicarboxylic acid is selected from the group consisting of 5-tert-butyl-1,3-benzoic acid, 2-tert-butyl-1,6-hexanedioic acid, 3-tert-butyl-1,6-hexanedioic acid and 2,5-di-tert-butyl-1,6-hexanedioic acid. Moreover, the modified polyester is dispersed with a doped ZrO.sub.2 powder. An obtained fiber has an intrinsic viscosity drop of 23-28% when stored at 25° C. and R.H. 65% for 60 months.

Artificial turf filament and articles incorporating same

Artificial turf filaments formed from polyethylene are provided that can have desirable properties. In one aspect, an artificial turf filament comprises a composition comprising a first composition, wherein the first composition comprises at least one ethylene-based polymer and wherein the first composition comprises a MWCDI value greater than 0.9, and a melt index ratio (I10/I2) that meets the following equation: I10/I2≥7.0−1.2×log (I2).

Artificial turf filament and articles incorporating same

Artificial turf filaments formed from polyethylene are provided that can have desirable properties. In one aspect, an artificial turf filament comprises a composition comprising a first composition, wherein the first composition comprises at least one ethylene-based polymer and wherein the first composition comprises a MWCDI value greater than 0.9, and a melt index ratio (I10/I2) that meets the following equation: I10/I2≥7.0−1.2×log (I2).

Turf reinforcement mats

Disclosed are exemplary embodiments of turf reinforcement mats that include spun yarns and/or multifilament yarns in either or both of the warp and weft directions.

Turf reinforcement mats

Disclosed are exemplary embodiments of turf reinforcement mats that include spun yarns and/or multifilament yarns in either or both of the warp and weft directions.

POLYMER FIBER ACTUATORS

Actuators (artificial muscles) comprising twist-spun nanofiber yarn or twist-inserted polymer fibers generate actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize polymer fibers non-coiled or coiled yarns and can be either neat or comprising a guest. Devices comprising these artificial muscles are also described. In some embodiments, thermally-powered polymer fiber torsional actuator has a twisted, chain-oriented polymer fiber that has a first degree of twist at a first temperature and a second degree of twist at a second temperature in which the bias angles of the first degree and second degree of twist are substantially different.

POLYMER FIBER ACTUATORS

Actuators (artificial muscles) comprising twist-spun nanofiber yarn or twist-inserted polymer fibers generate actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize polymer fibers non-coiled or coiled yarns and can be either neat or comprising a guest. Devices comprising these artificial muscles are also described. In some embodiments, thermally-powered polymer fiber torsional actuator has a twisted, chain-oriented polymer fiber that has a first degree of twist at a first temperature and a second degree of twist at a second temperature in which the bias angles of the first degree and second degree of twist are substantially different.