A high-strength creep-resistant polyester industrial yarn and preparation method thereof are provided. The high-strength creep-resistant polyester industrial yarn is prepared by spinning, winding and coordination treatment of a modified polyester after solid-state polycondensation to increase viscosity. The condition of coordination treatment is 60-72 hours at 80-100° C. The coordination agent is AgNO.sub.3, FeCl.sub.2, CuCl.sub.2, or NiCl.sub.2. The polyester segments of the prepared high-strength creep-resistant polyester industrial yarn includes a terephthalic acid segment, an ethylene glycol segment and a 2-(4-pyridine) terephthalic acid segment, and 2-(4-pyridine) terephthalic acid segments of different polyester segments are coordinated by metal ions (Ag.sup.+, Fe.sup.2+, Cu.sup.2+ or Ni.sup.2). The molar ratio of the terephthalic acid segment to the 2-(4-pyridine) terephthalic acid segment is 1:(0.03-0.05). The N atom on the pyridine of the 2-(4-pyridine) terephthalic acid segment is involved in coordination. Metal ions are coordinated with 2-(4-pyridine) terephthalic acid to greatly reduce the creep degree of the polyester fiber.

In one aspect, the disclosure relates to cooling films comprising a substrate and one or more cooling materials deposited on the substrate. The disclosed cooling films can be used to prepare the disclosed cooling masterbatch materials. The disclosed cooling masterbatch materials can be used to prepare disclosed cooling yarns. The one or more cooling materials deposited on the substrate of a disclosed cooling film, dispersed in a disclosed cooling masterbatch material, or in disclosed cooling yarn are nano-sized particles. In still further aspects, the present disclosure pertains to a fabric comprising a disclosed cooling yarn. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

In one aspect, the disclosure relates to cooling films comprising a substrate and one or more cooling materials deposited on the substrate. The disclosed cooling films can be used to prepare the disclosed cooling masterbatch materials. The disclosed cooling masterbatch materials can be used to prepare disclosed cooling yarns. The one or more cooling materials deposited on the substrate of a disclosed cooling film, dispersed in a disclosed cooling masterbatch material, or in disclosed cooling yarn are nano-sized particles. In still further aspects, the present disclosure pertains to a fabric comprising a disclosed cooling yarn. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

Actuators (artificial muscles) comprising twist-spun nanofiber twist-inserted polymer fibers generate tensile actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize coiled polymer fibers and can be either neat or comprising a guest. In some embodiments, the coiled polymer fibers actuator can be incorporated into an article, such as a textile, braid, clothing, smart packaging, or a mechanical system, and the coiled polymer fiber in the coiled polymer fiber actuator can have a stroke amplification factor of 5 or greater.

Actuators (artificial muscles) comprising twist-spun nanofiber twist-inserted polymer fibers generate tensile actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize coiled polymer fibers and can be either neat or comprising a guest. In some embodiments, the coiled polymer fibers actuator can be incorporated into an article, such as a textile, braid, clothing, smart packaging, or a mechanical system, and the coiled polymer fiber in the coiled polymer fiber actuator can have a stroke amplification factor of 5 or greater.

A label and related method of manufacture that includes a fabric made of yarn, in either cut individual singles or continuous ribbon format in any length. The yarn includes a fiber that has been recycled, that is recyclable, that is organic, that is biodegradable, and/or that can be derived from a material that is known to be environmentally friendly. The yarn, in one embodiment, may include a fiber defined as “high filament count” material, above the current industry standard of 24 filaments, being in the range of 72 to 96 to 144 filaments or higher per individual yarn, in any denier range of 30 denier to 150 denier thickness, in natural raw white, optical dyed white, or dyed colors. These yarns can be independent of each other.

A method of making a carbon nanotube composite yarn, the method including growing floating carbon nanotubes in a reactor, forming a mat of carbon nanotubes from the floating carbon nanotubes, a deposition step including depositing secondary particles on at least a portion of the mat of carbon nanotubes to provide a carbon nanotube composite mat, and a densification step including densifying the carbon nanotube composite mat to provide a carbon nanotube composite yarn.

A method of making a carbon nanotube composite yarn, the method including growing floating carbon nanotubes in a reactor, forming a mat of carbon nanotubes from the floating carbon nanotubes, a deposition step including depositing secondary particles on at least a portion of the mat of carbon nanotubes to provide a carbon nanotube composite mat, and a densification step including densifying the carbon nanotube composite mat to provide a carbon nanotube composite yarn.

Actuators (artificial muscles) comprising twist-spun nanofiber yarn or twist-inserted polymer fibers generate torsional actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize coiled yarns/polymer fibers and can be either neat or comprising a guest. In some embodiments, the actuator system includes a twisted and coiled polymer fiber actuator, and at least one of (i) wire connections that enable electrical heating of the twisted and coiled polymer fiber actuator, (ii) a radiation source and radiation pathway that enables photothermal heating of the twisted and coiled polymer fiber actuator, and (iii) a delivery system for delivering chemicals whose reaction produces heating of the twisted and coiled polymer fiber actuator.

Actuators (artificial muscles) comprising twist-spun nanofiber yarn or twist-inserted polymer fibers generate torsional actuation when powered electrically, photonically, chemically, thermally, by absorption, or by other means. These artificial muscles utilize coiled yarns/polymer fibers and can be either neat or comprising a guest. In some embodiments, the actuator system includes a twisted and coiled polymer fiber actuator, and at least one of (i) wire connections that enable electrical heating of the twisted and coiled polymer fiber actuator, (ii) a radiation source and radiation pathway that enables photothermal heating of the twisted and coiled polymer fiber actuator, and (iii) a delivery system for delivering chemicals whose reaction produces heating of the twisted and coiled polymer fiber actuator.