A coated microfibrous web, a method for producing the same, the use thereof as a covering of a radiation protection material, and a radiation protection device are described. The coated microfibrous web contains: (i) a microfibrous web containing one or more polyesters and/or one or more polyamides and/or one or more polyamide-polyester copolymers and having an impregnation composition containing (a) an aromatic dicarboxylic acid, the dicarboxylic groups of which are each esterified with a diol, and/or (b) one or more oligomers, each containing 2 to 10 repeat units consisting of a monoester of an aromatic dicarboxylic acid impregnated with a diol; and (ii) a layer comprising polyurethane which is present only on one side of the microfibrous web.

A coated microfibrous web, a method for producing the same, the use thereof as a covering of a radiation protection material, and a radiation protection device are described. The coated microfibrous web contains: (i) a microfibrous web containing one or more polyesters and/or one or more polyamides and/or one or more polyamide-polyester copolymers and having an impregnation composition containing (a) an aromatic dicarboxylic acid, the dicarboxylic groups of which are each esterified with a diol, and/or (b) one or more oligomers, each containing 2 to 10 repeat units consisting of a monoester of an aromatic dicarboxylic acid impregnated with a diol; and (ii) a layer comprising polyurethane which is present only on one side of the microfibrous web.

The present invention provides a water-repellent woven or knitted article that overcomes the problems of the related art and exhibits water-repellent properties and is excellent in abrasion resistance and durability. The water-repellent woven or knitted article of the present invention is a woven or knitted article subjected to a water repellent treatment using a water repellent having a perfluorooctanoic acid (PFOA) concentration of 5 ng/g or less, wherein the woven or knitted article includes, as constituent fibers, fibers having a transverse cross-sectional shape, each fiber has a plurality of grooves at an outer circumference of the transverse cross section, each groove has a wide part, and a size of the grooves in the fibers satisfies the following Formulae (Formula 1) and (Formula 2):

w2/w1≥1.3  (Formula 1)

0.15≤h/d≤0.25  (Formula 2) where w1 represents a groove entrance width, w2 represents a groove wide part width, h represents a groove depth, and d represents a diameter of the fiber, a droplet contact angle between the woven or knitted article and water is 135° or more after 20 times of washing in accordance with a method of JIS L 0217 103 and a water repellency is grade 4 or more in accordance with a spray method of JIS L 1092.

In one embodiment, a fabric is treated by creating a treatment solution comprising a fluid repellant and an antimicrobial compound, creating a treatment foam from the treatment solution, and applying the treatment foam to only an outer side of a fabric so as to coat the outer side of the fabric with the fluid repellant and the antimicrobial compound without coating an inner side of the fabric with the fluid repellant and the antimicrobial compound.

The present invention relates to a surfactant composition capable of making a liquid oil highly remain on the solid surface, which is a surfactant composition containing an anionic surfactant (A), a cationic surfactant (B), a liquid oil (C), and water, wherein the water constitutes a continuous phase; the following molar ratio R.sub.A is 0.25 or more and 0.60 or less; and the following molar ratio R.sub.b is 0.6 or more: R.sub.A: a molar ratio {(A)/[(A)+(B)]} of the amount of the anionic surfactant (A) to the total amount of the anionic surfactant (A) and the cationic surfactant (B) R.sub.b: a molar ratio {[(a1)+(b1)]/[(A)+(B)]} of the total amount of a branched-type anionic surfactant (a1) and a branched-type cationic surfactant (b1) to the total amount of the anionic surfactant (A) and the cationic surfactant (B).

The invention relates to a formulation which is used on textile surfaces, tissues, non-crimp fabrics, knitted fabrics, fibers, non-woven fabrics and weft knitted fabrics and which demonstrates an improved resistance to abrasion. The invention also relates to a process of preparing a formulation for improving abrasion resistance of textiles and the process of treating textiles, non-woven fabrics and leather articles for improving abrasion resistance.

The invention relates to a formulation which is used on textile surfaces, tissues, non-crimp fabrics, knitted fabrics, fibers, non-woven fabrics and weft knitted fabrics and which demonstrates an improved resistance to abrasion. The invention also relates to a process of preparing a formulation for improving abrasion resistance of textiles and the process of treating textiles, non-woven fabrics and leather articles for improving abrasion resistance.

Composition, comprising at least components (A) and (B) and optionally at least one of components (C) to (E): (A) polyacrylate obtained in the polymerisation of components (M1) CH.sub.2═CR.sup.3COO—R.sup.1 with (M2) CH.sub.2═CR.sup.3COO—R.sup.2 and optionally (M3) CH.sub.2═CR.sup.3—X—R.sup.4
(B) wax
(C) blocked isocyanate
(D) organic polysiloxane;
(E) melamine resin;
wherein
R.sup.1 is a residue containing from 1 to 8 carbon atoms;
R.sup.2 is a residue containing from 9 to 40 carbon atoms;
R.sup.3=H, CH.sub.3, C.sub.2H.sub.5;
X=COO, CONH
R.sup.4=glycidyl or CH.sub.2(CH.sub.2).sub.n—OR.sup.5, wherein n is an integer in the range of from 1-10 and R.sup.5 is H or a residue containing from 1 to 6 carbon atoms;
and wherein the composition is based on water and/or an organic solvent and is fluorine-free.

Composition, comprising at least components (A) and (B) and optionally at least one of components (C) to (E): (A) polyacrylate obtained in the polymerisation of components (M1) CH.sub.2═CR.sup.3COO—R.sup.1 with (M2) CH.sub.2═CR.sup.3COO—R.sup.2 and optionally (M3) CH.sub.2═CR.sup.3—X—R.sup.4
(B) wax
(C) blocked isocyanate
(D) organic polysiloxane;
(E) melamine resin;
wherein
R.sup.1 is a residue containing from 1 to 8 carbon atoms;
R.sup.2 is a residue containing from 9 to 40 carbon atoms;
R.sup.3=H, CH.sub.3, C.sub.2H.sub.5;
X=COO, CONH
R.sup.4=glycidyl or CH.sub.2(CH.sub.2).sub.n—OR.sup.5, wherein n is an integer in the range of from 1-10 and R.sup.5 is H or a residue containing from 1 to 6 carbon atoms;
and wherein the composition is based on water and/or an organic solvent and is fluorine-free.

To provide a method for forming a transparent coating that is highly adherent to the skin and through which the skin is visible.

A method for forming a coating on a skin surface using a nanofiber sheet, the method comprising:

(1) Step (1) of applying to the skin a sheet transparentizing agent comprising 2 mass or more of one or more oil agents; and

(2) Step (2) of transferring a white nanofiber sheet mainly composed of a water-insoluble polymer to the skin after Step (1).