A laundry additive composition is provided that includes at least one zeta potential modifier, a fluoropolymer, a hydrophobic agent with a melting point or glass transition temperature below 100 C., and an antimicrobial active for imparting fabric protection benefits to a fabric, such as improved stain and soil resistance, oil repellency, water repellency, softness, wrinkle and damage resistance, and better hand feel, as well as imparting microbiocidal or microbiostatic properties to the fabric and/or washing machine surfaces. Laundry additive compositions can be used as a pretreatment prior to washing, through soaking a fabric or garment. Alternately, they can be added to a washing treatment liquor that comprises either the wash or rinse cycle of an automatic washing machine, to first provide and then maintain and refresh fabric protection benefits imparted to the fabric. Following use of a first treatment composition, protective benefits are maintained and refreshed by means of a second treatment operation employing a second treatment composition. The second treatment composition may have lower active levels of the protective agents to provide for economical and periodic maintenance of the imparted fabric protection benefits and/or refresh the microbiocidal or microbiostatic properties imparted to fabrics and/or washing machine surfaces.

A fabric includes a fabric body and a backing resin layer laminated on a rear surface of the fabric body. The fabric body includes a fluorine-containing organic compound adhered to at least the surface thereof, and the fluorine-containing organic compound has six carbon atoms and at least one fluorine atom. The backing resin layer contains a resin, a flame retardant, and an organic fluorine based oil repellent in which the carbon number is six.

A soil resistant fiber structure, including a fiber and a soil resistant resin fixed to at least a part of a surface of the fiber, wherein the resin has, in at least a part inside the resin, one or more regions dyed with osmium oxide as observed with a transmission electron microscope, at least one of the regions is circular, the regions have a maximum diameter of 100 nm or more and 500 nm or less, and the soil resistant fiber structure has a mass concentration ratio of oxygen atoms to fluorine atoms (O/F) of 3 or more as obtained by measuring the surface of the fiber with an energy dispersive X-ray analyzer. The present invention provides a fiber structure having high anti-adhesion property against aqueous soils and oily soils as well as soil release property by washing.

A method of treatment of one or more articles may comprise locating a stain on an article based on a tag on the article; placing the stain on a nose of a spotting board; positioning a steam gun at least two or more inches away from the stain; simultaneously activating a steam supply and a vacuum supply of the spotting board; moving the steam gun in a defined motion relative to the stain for at least 30 seconds; simultaneously activating the vacuum supply and an air supply of the spotting board; moving the steam gun in the defined motion relative to the stain until the article is at least partially dry; and inspecting the stain.

A surface treatment agent which is an aqueous emulsion containing: (a) a fluorine-free polymer including: (i) repeating units derived from a long-chain (meth)acrylate ester monomer represented by the formula: CH.sub.2CA.sup.11-C(O)O-A.sup.12, wherein A.sup.11 is a hydrogen atom or a methyl group, and A.sup.12 is a linear or branched aliphatic hydrocarbon group having 10-30 carbon atoms; (b) a surface active agent including both of a nonionic surface active agent and an anionic surface active agent, wherein the amount of the anionic surface active agent is at least 22% by weight, based on the total of the nonionic surface active agent and the anionic surface active agent; and (c) a liquid medium comprising water.

Provided are a fluorine-free soil resistant agent and a soil resistant treatment method which give excellent water-repellency and excellent antifouling property to a substrate, especially a carpet. The soil resistant agent contains (1) a fluorine-free copolymer having (a) a repeating unit formed from an acrylic monomer having a hydrocarbon group containing 7 to 40 carbon atoms, and (b) a repeating unit formed from an acrylic monomer having a hydrophilic group, and (2) water or a mixture of water and an organic solvent dispersing the fluorine-free copolymer (1). A method of treating the substrate, includes applying the soil resistant agent to the substrate.

A system and method for applying a polymer surface treatment to carpets and other textiles is provided. The system and method include the use of a surfactant-free emulsion of a surface treatment polymer. The use of the surfactant-free emulsion of a surface treatment polymer reduces or eliminates the need to use pH adjusting agents and/or ionic salt solutions when applying surface treatment polymers to carpets or other textiles. By reducing the need to remove surfactants, emulsifiers, pH adjusting agents, and/or salts, the total volume of water used in treating carpets or other textiles is reduced.

A fabric includes a fabric body and a backing resin layer laminated on a rear surface of the fabric body. The fabric body includes a fluorine-containing organic compound adhered to at least the surface thereof, and the fluorine-containing organic compound has six carbon atoms and at least one fluorine atom. The backing resin layer contains a resin, a flame retardant, and an organic fluorine based oil repellent in which the carbon number is six.

A manufacturing method for functionalized dyed textile, where the textile is preferably a textile or a knit, including the following steps: getting a dyed textile having a majority by mass of natural fibers, preferably cellulose fibers; bleaching of the dyed textile in order to get a bleached dyed textile whose dye has not been altered; and chemical functionalizing of the bleached dyed textile in order to get a hydrophobic dyed textile, where the functionalization has an increased attachment to the dyed textile because of the prior bleaching. Also, a functionalized dyed textile and the use of a bleaching solution for increasing the hold on the dyed textile of the chemical functionalization.

An application method of enhancing the water repellence of a textile and/or enhancing a textiles ability to repel water soluble dirt, includes the steps of: a) applying an emulsified liquid composition on a textile, wherein said emulsified liquid composition includes only water, alkylalkoxysilane with said alkyl chain having a length of 10-30 carbons or carbon atoms higher than 12 but equal to or less than 18, at least one emulsifier, surfactant, thickener and/or stabilizer, a water soluble acid catalyst, and unavoidable impurities; b) optionally adding to the composition amino silicones for softness and durability enhancement of the water repellency; c) optionally adjusting the amount of the composition applied on textile; d) drying the treated textile until dry; e) curing the treated textile at a temperature of between 100-200 C.; and f) optionally removing the non-reacted composition residue from the treated textile by washing with water and optionally redrying the treated textile.