A method for optimizing reduction and content of total titratable alkali of green liquor of a recovery boiler. The method comprises producing green liquor in a dissolving tank by conveying smelt and weak white liquor into the dissolving tank and measuring at least the contents of sodium sulphate, sodium hydroxide, sodium sulphide, and sodium carbonate of the green liquor. The method comprises controlling at least a process parameter of a recovery boiler to maximize the reduction of the recovery boiler and controlling the flow of the weak white liquor into the dissolving tank to optimize the content of total titratable alkali of the green liquor. In addition, a system for producing green liquor with optimized reduction and content of total titratable alkali. The system comprises a first sensor arrangement, a first and a second regulator, and a processing unit arrangement configured to perform the method.

A method for handling spent wash solution produced in the washing of lignin that has been precipitated and then separated from spent alkaline pulping liquor. At least part of the spent wash solution is introduced into the chemical recovery cycle at a location in that part of the cycle which starts at, and includes, the smelt dissolving stage and ends at, and includes, the pulping stage. In preferred embodiments, input of other water and/or aqueous solution into the chemical recovery cycle after the recovery boiler is adjusted so that, as a consequence of the introduction of the spent wash solution, the amount of water in the white liquor going to the pulping line is not significantly increased. Among others, two preferred locations for the introduction of the spent wash solution are (1) the smelt dissolver and (2) the location where unwashed lime mud is diluted.

A method and a liquor filter, in which liquor filter sealing medium is fed via a sealing medium channel (3) into an innermost sealing zone formed by an innermost sealing member (1), an outer seal (2) and the space between them at a causticizing plant of a chemical pulp mill. The sealing medium used is an alkaline sealing liquid and/or gas, which does not substantially dilute the liquor being filtered. Advantageously the sealing medium is filtrate from the liquor filter and/or gas taken from the interior of the liquor filter.

A method associated for treating a precoat on a rotating filtering surface of lime sludge filter including: accumulating a precoat of lime sludge on the filtering surface by rotating the filtering surface in a first direction through a lime sludge slurry; after accumulating the precoat, rotating the filtering surface in an opposite direction to the first direction; while rotating the filtering surface in the opposite direction, spraying a liquid onto the precoat on the filtering surface wherein the spraying is applied to the precoat above a scraper adjacent the filtering surface and the spraying removes at least a portion of the precoat from the filtering surface, and flowing the removed precoat over the scraper and into a basin.

A method for processing black liquor includes operations of: (A1) ultrafiltering the black liquor; (A2) mixing the ultrafiltration concentrate with carbon dioxide and/or sulfuric acid to precipitate lignin in the ultrafiltration concentrate, and obtaining a first inorganic aqueous solution; (A3) mixing the first inorganic aqueous solution with the ultrafiltration permeate to obtain a mixture, and nanofiltering the mixture; (A4) mixing the nanofiltration concentrate with carbon dioxide and/or sulfuric acid to precipitate lignin in the nanofiltration concentrate, and obtaining a second inorganic aqueous solution; (A5) performing a first electrodialysis treatment or reverse osmosis treatment on the second inorganic aqueous solution, and obtaining a remaining inorganic aqueous solution; (A6) mixing the remaining inorganic aqueous solution with the lignin obtained from operation (A2) and/or operation (A4) to obtain a first fuel liquid; and (A7) processing the first fuel liquid to produce sodium sulfide, sodium carbonate, carbon dioxide, and steam.