Release base papers with improved surface properties and more efficient manufacturing potential are made using cellulose nanofibrils (CNF) along with high freeness, less refined pulp. Release papers serve as the backing for common adhesive labels, for industrial film coatings, and also for certain food processing uses. The CNF may be added to the furnish and processed to paper, or the CNF may be added as a coating onto a partially dried web of paper. The CNF may optionally be combined with a starch and a starch crosslinker.

A prefabricated tile-type coating, whose manufacture is based on the development of a polymeric composite including mainly recycled synthetic rubber obtained from the grinding of scrap automotive waste tires, virgin rubber, or a combination of both, using as a binder a novel cross-linkable acrylic resin with the ability to be processed by pultrusion. The upper layer of the tile is made of a resin with thermochromic effect that integrates an encapsulated pigment of thermochromic material with a transition temperature in the range of 20-35 C. which changes color from white under high-temperature conditions, i.e. C. or greater than dark in conditions of low temperature, that is, 20 C. or less. The tile of elastomeric character obtained has notable competitive advantages compared to other technologies in terms of thermal resistance, solar reflectance, and resistance to the impact caused by hail or other meteorological phenomena.

An organopolysiloxane emulsion composition for release paper or a release film, said composition being produced by dispersing a mixture comprising components (A) to (D) as mentioned below in water: (A) an alkenyl-group-containing diorganopolysiloxane having at least two alkenyl groups per molecule and having a viscosity of 1,000 Pa.Math.s or less at 25 C., in an amount of 100 parts by mass; (B) an organohydrogenpolysiloxane having at least two SiH groups per molecule and having a viscosity of 1 Pa.Math.s or less at 25 C., in such an amount that the number of moles of an SiH group can become 0.5 to 10 times the number of moles of an alkenyl group in the component (A); (C) a curing catalyst, in an amount of 0.01 to 3 parts by mass; and (D) a polyether-modified and/or polyol-modified organosilicon compound, in an amount of 0.01 to 10 parts by mass.

Release paper base paper includes a substrate; and a coating agent containing a modified polyvinyl alcohol (A) and sodium acetate, the substrate coated with the coating agent, wherein the modified polyvinyl alcohol (A) has 0.005 mol % or more and less than 10 mol % of double bonds derived from unsaturated carboxylic acid or a derivative thereof (B) in side chains, has 1.4 mol % or more and 2.0 mol % or less of 1,2-glycol bond, units, and is water soluble, and a content of the sodium acetate relative to the modified polyvinyl alcohol (A) is 0.01 mass % or more and 10 mass % or less. The release paper base paper of the present invention is excellent in sealing properties for silicone. Use of the release paper base paper allows acceleration of curing of silicone in a release layer and improvement in adhesion between the substrate and the release layer.

Release paper base paper, includes; a substrate; and a coating agent containing a polyvinyl alcohol (A) and a compound (B), the substrate coated with the coating agent, wherein the compound (B) is unsaturated carboxylic acid or a derivative thereof having a pKa of less than 4.00, and 0.1 part by mass or more and 20 parts by mass or less of the compound (B) is contained based on 100 parts by mass of the polyvinyl alcohol (A). The release paper base paper of the present invention is excellent in sealing properties for silicone and waterproofness. The release paper base paper of the present invention is also capable of accelerating curing of silicone in a release layer.

A cellulose and/or synthetic fibre-based support of which at least one surface is coated with a layer containing at least one water-soluble polymer comprising hydroxyl or primary-secondary amino functional groups, at least some of which have been functionalized beforehand with at least one organic compound comprising at least one epoxy functional group, and at least one R.sup.1 group wherein R.sup.1 is a vinyl functional group or at least one Si(R.sup.2).sub.3 functional group and wherein R.sup.2=hydrogen atom, hydroxyl, alkoxy, alkyl, and combinations thereof.

The invention relates to a method for manufacturing thermoplastic poly(vinyl alcohol) derivative in a melt state reaction and a product thereof, wherein the method thermoplastic poly(vinyl alcohol) that has been dried is heated and admixed with an organic acid anhydride that has a catenated carbon structure which ends into a vinyl group, such that a mixture is obtained which is above the melting point of the mixture, thereby causing an ester bond forming condensation reaction in a melt state, wherein at least some of the organic acid anhydride reacts with hydroxyl groups of the thermoplastic poly(vinyl alcohol), such that reaction product is formed which contains carboxylic acid residue and thermoplastic poly(vinyl alcohol) derivative which contains ester bonded pendant chains of which at least some end into vinyl groups. The invention further relates to a method for manufacturing a paper substrate and a product thereof, which contains a primer layer that contains the reaction product.

There is provided a composition (C) comprising a modified PVA (A) and a compound (B), wherein the modified PVA (A) contains 0.01 mol % or more and less than 2 mol % of double bonds derived from an unsaturated carboxylic acid or a derivative thereof in side chains; the compound (B) is a compound having a conjugated double bond and two or more hydroxy groups bonded to the conjugated double bond, or a salt or oxide thereof; and a content of the compound (B) in the composition (C) is 0.001 parts by mass or more and less than 5 parts by mass based on 100 parts by mass of the modified PVA (A). The composition (C) has excellent hue, contains less insolubles in water, and has excellent water solubility.

The invention relates to a method for manufacturing thermoplastic poly(vinyl alcohol) derivative in a melt state reaction and a product thereof, wherein the method thermoplastic poly(vinyl alcohol) that has been dried is heated and admixed with an organic acid anhydride that has a catenated carbon structure which ends into a vinyl group, such that a mixture is obtained which is above the melting point of the mixture, thereby causing an ester bond forming condensation reaction in a melt state, wherein at least some of the organic acid anhydride reacts with hydroxyl groups of the thermoplastic poly(vinyl alcohol), such that reaction product is formed which contains carboxylic acid residue and thermoplastic poly(vinyl alcohol) derivative which contains ester bonded pendant chains of which at least some end into vinyl groups. The invention further relates to a method for manufacturing a paper substrate and a product thereof, which contains a primer layer that contains the reaction product.

Provided are: an additive reaction-type silicone composition that is for release paper or for a release film, that is non-migratory, and that exhibits light releasability with respect to various adhesives, said silicone composition for release paper or for a release film making it possible to form a cured film that does not adversely affect residual adhesive strength or releasability; and a release paper or a release film obtained by applying the composition to a substrate and curing the result. In a silicone composition for release paper or a release film cured by additive reaction, an organopolysiloxane containing an alkenyl group having a terminal unsaturated bond is used as a base polymer, and a specific amount of an organopolysiloxane that has a lower molecular weight than the base polymer and that contains an alkenyl group having a terminal unsaturated bond is mixed with the base polymer.