Patent classifications
D01F6/84
Fibers formed from a blend of a modified aliphatic-aromatic copolyester and theremoplastic starch
A fiber formed from a thermoplastic composition that contains a thermoplastic starch and an aliphatic-aromatic copolyester is provided. The copolyester enhances the strength of the starch-containing fibers and facilitates the ability of the starch to be melt processed. Due to its relatively low melting point, the copolyester may also be extruded with the thermoplastic starch at a temperature low enough to avoid substantial removal of the moisture in the starch. Furthermore, the copolyester is also modified with an alcohol to contain one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the conditions of the alcoholysis reaction (e.g., alcohol and copolymer concentrations, temperature, etc.), the resulting modified aliphatic-aromatic copolyester may have a relatively low molecular weight. Such low molecular weight polymers have the combination of a higher melt flow index and lower apparent viscosity, which is useful in a variety of fiber forming applications, such as meltblowing nonwoven webs.
Fibers formed from a blend of a modified aliphatic-aromatic copolyester and theremoplastic starch
A fiber formed from a thermoplastic composition that contains a thermoplastic starch and an aliphatic-aromatic copolyester is provided. The copolyester enhances the strength of the starch-containing fibers and facilitates the ability of the starch to be melt processed. Due to its relatively low melting point, the copolyester may also be extruded with the thermoplastic starch at a temperature low enough to avoid substantial removal of the moisture in the starch. Furthermore, the copolyester is also modified with an alcohol to contain one or more hydroxyalkyl or alkyl terminal groups. By selectively controlling the conditions of the alcoholysis reaction (e.g., alcohol and copolymer concentrations, temperature, etc.), the resulting modified aliphatic-aromatic copolyester may have a relatively low molecular weight. Such low molecular weight polymers have the combination of a higher melt flow index and lower apparent viscosity, which is useful in a variety of fiber forming applications, such as meltblowing nonwoven webs.
Cationic dyeable polyester fiber and preparing method thereof
A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: ##STR00001## The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.
Cationic dyeable polyester fiber and preparing method thereof
A type of cationic dyeable polyester fiber and preparing method thereof are disclosed. The preparing method is to manufacture a fiber from a cationic modified polyester through a fully drawn yarn (FDY) process, wherein the cationic modified polyester is composed of terephthalic acid segments, ethylene glycol segments, sodium salt of diethylene ester of 5-sulfoisophthalic acid segments and tert-butyl branched diol segments and a molecular formula of tert-butyl branched diol is as following: ##STR00001## The cationic modified polyester is further dispersed with a high temperature calcined solid heteropolyacid. A final fiber has a dye uptake of 87.8-92.2% and a K/S value of 23.27-25.67 when dyed at 120° C., as well as an intrinsic viscosity drop of 13-17% when stored at 25° C. and R.H. 65% for 60 months.
METHODS OF MODULATING POLYMER RHEOLOGY FOR ADDITIVE MANUFACTURING
A method includes adding about 5 weight percent to about 25 weight percent of carbon nanotubes to a crystalline or semi-crystalline polymer to form a composite and forming a filament or particles from the composite, the filament or particles having a size suitable for use in additive manufacturing, in the absence of the carbon nanotubes a melt viscosity of the crystalline or semi-crystalline polymer is below 100 Pa.Math.s, preventing its use in additive manufacturing. The filament or particles comprising carbon nanotubes can be used in methods of additive manufacturing.
Functionally Gradient Material for Guided Periodontal Hard and Soft Tissue Regeneration and A Preparation Method Thereof
A functionally gradient material for guided periodontal hard and soft tissue regeneration includes a 3D printed scaffold layer and an electrospun fibrous membrane layer. The content of hydroxyapatite in the 3D printed scaffold layer is higher than the content of hydroxyapatite in the electrospun fibrous membrane layer. The pore size of the 3D printed scaffold layer is larger than the pore size of the electrospun fibrous membrane layer. The pore size of the 3D printed scaffold layer is 100-1000 μm, and the fiber diameter of the electrospun fibrous membrane layer is 300-5000 nm. The electrospun fibrous membrane layer is in a random distribution or an oriented arrangement or has a mesh structure. The thickness of the electrospun fibrous membrane layer is 0.08-1 mm.
PHOTOPOLYMERIZABLE COMPOSITIONS FOR SOLVENTLESS FIBER SPINNING
Disclosed are methods of fiber spinning and polymer fibers that utilize multifunctional thiol and enes compounds. Also, the subject matter disclosed herein relates to uses of polymer fibers and articles prepared from such fibers.
PHOTOPOLYMERIZABLE COMPOSITIONS FOR SOLVENTLESS FIBER SPINNING
Disclosed are methods of fiber spinning and polymer fibers that utilize multifunctional thiol and enes compounds. Also, the subject matter disclosed herein relates to uses of polymer fibers and articles prepared from such fibers.
DRUG-LOADED NANOFIBER MEMBRANE, METHOD FOR PREPARING THE SAME, AND APPLICATION THEREOF
A drug-loaded nanofiber membrane includes a first fiber, a second fiber, and a drug. The drug is dispersed into the first fiber. The first fiber includes poly(lactic-co-glycolic acid) copolymer (PLGA copolymer), and the second fiber includes poly(p-dioxanone) (PDO).
LIQUID CRYSTAL POLYESTER FIBERS
Liquid crystal polyester fibers containing a liquid crystal polyester, in which the liquid crystal polyester has a repeating unit represented by Formula (1), a repeating unit represented by Formula (2), and a repeating unit represented by Formula (3), at least one repeating unit selected from the group consisting of the repeating unit represented by Formula (1), the repeating unit represented by Formula (2), and the repeating unit represented by Formula (3) contains a 2,6-naphthylene group, a content of the repeating unit containing the 2,6-naphthylene group is 40 mol % or greater with respect to a total content of all the repeating units of the liquid crystal polyester, and an orientation degree of the liquid crystal polyester in a length direction of the fiber is 89% to 95%. (1) —O—Ar.sup.1—CO—, (2) —CO—Ar.sup.2—CO—, and (3) —X—Ar.sup.3—Y—, wherein Ar.sup.1 represents a phenylene group, a naphthylene group, or a biphenylylene group, Ar.sup.2 and Ar.sup.3 each independently represent a phenylene group, a naphthylene group, or a biphenylylene group, and at least one selected from the group consisting of Ar.sup.1, Ar.sup.2, and Ar.sup.3 contains a 2,6-naphthylene group. X and Y each independently represent an oxygen atom or an imino group (—NH—). Hydrogen atoms of the group represented by Ar.sup.1, Ar.sup.2, or Ar.sup.3 may be each independently substituted with a halogen atom, an alkyl group having 1 to 10 carbon atoms, or an aryl group having 6 to 20 carbon atoms.