The present disclosure relates to the development of high performance light weight carbon fiber fabric-electrospun carbon nanofibers hybrid polymer composites and a process thereof. In this process continuous carbon nanofiber sheets of diameter in the range of few hundred nanometers are developed from electrospun PAN nanofibers and sandwich between the carbon fiber fabric epoxy resin prepregs to develop hybrid polymer composites by compression molding technique with low content of carbon fibers.

The present disclosure relates to the development of high performance light weight carbon fiber fabric-electrospun carbon nanofibers hybrid polymer composites and a process thereof. In this process continuous carbon nanofiber sheets of diameter in the range of few hundred nanometers are developed from electrospun PAN nanofibers and sandwich between the carbon fiber fabric epoxy resin prepregs to develop hybrid polymer composites by compression molding technique with low content of carbon fibers.

A method of manufacturing a stabilized fiber bundle is described, which includes subjecting an acrylic fiber bundle aligned, to a heat treatment in an oxidizing atmosphere, with the acrylic fiber bundle being turned around by a guide roller placed on each of both ends outside a hot air heating-type oxidation oven, wherein an air velocity Vm of first hot air sent through a supply nozzle(s) disposed above and/or under a fiber bundle travelled in the oxidation oven, in a substantially horizontal direction to a travelling direction of the fiber bundle, and an air velocity Vf of second hot air flowing in a fiber bundle passing a flow channel in which the fiber bundle is travelled that satisfies expression 1)
0.2?Vf/Vm?2.01)
to produce a high-quality stabilized fiber bundle and a high-quality carbon fiber bundle at high efficiencies without any process troubles.

The inventive concepts relate to a member for a gas sensor, a gas sensor using the same and a manufacturing method thereof, and more particularly, to a member for a gas sensor using a one-dimensional metal oxide nanofiber complex material containing hetero nanoparticle catalysts synthesized using apo-ferritins, a gas sensor using the same, and a manufacturing method thereof.

According to embodiments of the inventive concepts, apo-ferritins containing hetero nanoparticle catalysts are mixed with an electrospinning solution, the mixture solution is electrospun to form complex nanofibers, and then a high-temperature thermal treatment process is performed to remove the apo-ferritins. Thus, the hetero nanoparticle catalysts are uniformly fastened to an inside and a surface of one-dimensional metal oxide nanofibers to form a member for a gas sensor. As a result, the member for a gas sensor has a high-sensitivity characteristic capable of sensing a very small amount of a gas and excellent selectivity capable of sensing various gases. In addition, a catalyst effect is maximized by the hetero nanoparticle catalysts uniformly distributed without aggregation. Furthermore, the member for a gas sensor and the gas sensor using the same can be mass-produced by a process method capable of effectively forming pores and of fastening high-performance catalysts.

The inventive concepts relate to a member for a gas sensor, a gas sensor using the same and a manufacturing method thereof, and more particularly, to a member for a gas sensor using a one-dimensional metal oxide nanofiber complex material containing hetero nanoparticle catalysts synthesized using apo-ferritins, a gas sensor using the same, and a manufacturing method thereof.

According to embodiments of the inventive concepts, apo-ferritins containing hetero nanoparticle catalysts are mixed with an electrospinning solution, the mixture solution is electrospun to form complex nanofibers, and then a high-temperature thermal treatment process is performed to remove the apo-ferritins. Thus, the hetero nanoparticle catalysts are uniformly fastened to an inside and a surface of one-dimensional metal oxide nanofibers to form a member for a gas sensor. As a result, the member for a gas sensor has a high-sensitivity characteristic capable of sensing a very small amount of a gas and excellent selectivity capable of sensing various gases. In addition, a catalyst effect is maximized by the hetero nanoparticle catalysts uniformly distributed without aggregation. Furthermore, the member for a gas sensor and the gas sensor using the same can be mass-produced by a process method capable of effectively forming pores and of fastening high-performance catalysts.

An article having a superhydrophobic or oleophobic ceramic polymer composite surface is formed by the coating of the surface with a fluid comprising a polymer, copolymer, or polymer precursor and a plurality of glass, ceramic, or ceramic-polymer particles. The particles have fluorinated surfaces and at least a portion of the polymer's repeating units that are fluorinated or perfluorinated. The composite can be a cross-linked polymer.

An article having a superhydrophobic or oleophobic ceramic polymer composite surface is formed by the coating of the surface with a fluid comprising a polymer, copolymer, or polymer precursor and a plurality of glass, ceramic, or ceramic-polymer particles. The particles have fluorinated surfaces and at least a portion of the polymer's repeating units that are fluorinated or perfluorinated. The composite can be a cross-linked polymer.

The inventive concepts relate to a member for a gas sensor, a gas sensor using the same and a manufacturing method thereof, and more particularly, to a member for a gas sensor using a one-dimensional metal oxide nanofiber complex material containing hetero nanoparticle catalysts synthesized using apo-ferritins, a gas sensor using the same, and a manufacturing method thereof. According to embodiments of the inventive concepts, apo-ferritins containing hetero nanoparticle catalysts are mixed with an electrospinning solution, the mixture solution is electrospun to form complex nanofibers, and then a high-temperature thermal treatment process is performed to remove the apo-ferritins. Thus, the hetero nanoparticle catalysts are uniformly fastened to an inside and a surface of one-dimensional metal oxide nanofibers to form a member for a gas sensor. As a result, the member for a gas sensor has a high-sensitivity characteristic capable of sensing a very small amount of a gas and excellent selectivity capable of sensing various gases. In addition, a catalyst effect is maximized by the hetero nanoparticle catalysts uniformly distributed without aggregation. Furthermore, the member for a gas sensor and the gas sensor using the same can be mass-produced by a process method capable of effectively forming pores and of fastening high-performance catalysts.

The inventive concepts relate to a member for a gas sensor, a gas sensor using the same and a manufacturing method thereof, and more particularly, to a member for a gas sensor using a one-dimensional metal oxide nanofiber complex material containing hetero nanoparticle catalysts synthesized using apo-ferritins, a gas sensor using the same, and a manufacturing method thereof. According to embodiments of the inventive concepts, apo-ferritins containing hetero nanoparticle catalysts are mixed with an electrospinning solution, the mixture solution is electrospun to form complex nanofibers, and then a high-temperature thermal treatment process is performed to remove the apo-ferritins. Thus, the hetero nanoparticle catalysts are uniformly fastened to an inside and a surface of one-dimensional metal oxide nanofibers to form a member for a gas sensor. As a result, the member for a gas sensor has a high-sensitivity characteristic capable of sensing a very small amount of a gas and excellent selectivity capable of sensing various gases. In addition, a catalyst effect is maximized by the hetero nanoparticle catalysts uniformly distributed without aggregation. Furthermore, the member for a gas sensor and the gas sensor using the same can be mass-produced by a process method capable of effectively forming pores and of fastening high-performance catalysts.

A crystalline silicon carbide fiber containing silicon carbide and boron nitride, the crystalline silicon carbide fiber having a content of Si of 64% to 72% by weight, a content of C of 28% to 35% by weight, and a content of B of 0.1% to 3.0% by weight, and including, at a surface portion, a composition gradient layer in which a content of silicon carbide increases while a content of boron nitride decreases toward a depth direction.