Provided herein are devices, systems, and methods for capturing toxic pollutants, such as polycyclic aromatic hydrocarbons. Certain embodiments of the present disclosure are related to a pollutant-absorbing material that includes an absorbent compound, such as sodium copper chlorophyllin, capable of binding to and capturing a toxic pollutant, and methods of making and using the material for the capture of toxic pollutants. The pollutant-absorbing material can be incorporated into an article worn by a person, such as a shirt or a facemask.

An improved flow rate metering device that provides for the mixing and dispensing of two or more fluids to form final mixture, for example, for automatic washing of cars and trucks. More specifically, the invention is a system that mixes and ejects chemicals, creating a very precise mixture of one or more chemicals with a dilutant, such as water. The device also has the capability of monitoring an entire chemical dilution and release system, comprising multiple chemicals, and using software to document past and current usage rates, along with predicting future usage rates based upon both past usage rates and environmental conditions.

Embodiments of the present disclosure relates generally to methods of providing biomimetic superhydrophobic coatings to substrates, and more specifically to providing biomimetic inorganic silica or silane-based coatings that enable tunable hierarchical surface structures with high coating-to-substrate adhesion, resistance to various mechanical abradents, durability, shelf stability, and enhanced non-wettability or water-repellency.

Embodiments of the present disclosure relates generally to methods of providing biomimetic superhydrophobic coatings to substrates, and more specifically to providing biomimetic inorganic silica or silane-based coatings that enable tunable hierarchical surface structures with high coating-to-substrate adhesion, resistance to various mechanical abradents, durability, shelf stability, and enhanced non-wettability or water-repellency.

A process of fabricating the composition coating may include selecting a textile material substrate, utilizing a sol-gel comprising a silane or silane derivative and metal oxide precursor to coat the substrate, and optionally coating the substrate with a hydrophobic chemical agent and/or other chemical agents to create a surface with nanoscopic or microscopic features. The process may utilize an all solution process or controlled environment for fabricating a composition coating that prevent wetting or staining of a substrate. The composition coatings for treating textile materials improve soil-resistance and stain-resistance of the textile materials. The composition coatings and their use for treating textile materials can also impart water repellency, oil repellency, ease of cleaning stains and removing particulates. In addition, the composite solution may impart additional properties such as physical strength to the textile whilst retaining the original appearance.

A process of fabricating the composition coating may include selecting a textile material substrate, utilizing a sol-gel comprising a silane or silane derivative and metal oxide precursor to coat the substrate, and optionally coating the substrate with a hydrophobic chemical agent and/or other chemical agents to create a surface with nanoscopic or microscopic features. The process may utilize an all solution process or controlled environment for fabricating a composition coating that prevent wetting or staining of a substrate. The composition coatings for treating textile materials improve soil-resistance and stain-resistance of the textile materials. The composition coatings and their use for treating textile materials can also impart water repellency, oil repellency, ease of cleaning stains and removing particulates. In addition, the composite solution may impart additional properties such as physical strength to the textile whilst retaining the original appearance.

A process of fabricating the waterproof coating may include selecting a substrate, utilizing a sol-gel comprising a silane or silane derivative and metal oxide precursor to coat the substrate, and optionally coating the substrate with a hydrophobic chemical agent and/or other chemical agents to create a surface with nanoscopic or microscopic features. The process may utilize an all solution process or controlled environment for fabricating self-cleaning and waterproof coating that prevent wetting or staining of a substrate, or may utilize a controlled environment.

A process of fabricating the waterproof coating may include selecting a substrate, utilizing a sol-gel comprising a silane or silane derivative and metal oxide precursor to coat the substrate, and optionally coating the substrate with a hydrophobic chemical agent and/or other chemical agents to create a surface with nanoscopic or microscopic features. The process may utilize an all solution process or controlled environment for fabricating self-cleaning and waterproof coating that prevent wetting or staining of a substrate, or may utilize a controlled environment.

A water repellent composition that contains (A) a trialkylsiloxysilicate represented by average composition formula (1): 100 mass parts, (B) an organopolysiloxane having at least two hydroxyl groups or alkoxy groups in the molecule represented by formula (2): 1-100 mass parts, (C) one or more selected from tetraalkoxytitaniums represented by general formula (3)

##STR00001##

(in the formula, M is titanium or zirconium, X are each independently a C1-8 alkyl group): 10-300 mass parts, and (D) an organic solvent: 100-30,000 mass parts,
has an excellent water repellency-imparting effect, and can impart good softness to treated fibers.

A water repellent composition that contains (A) a trialkylsiloxysilicate represented by average composition formula (1): 100 mass parts, (B) an organopolysiloxane having at least two hydroxyl groups or alkoxy groups in the molecule represented by formula (2): 1-100 mass parts, (C) one or more selected from tetraalkoxytitaniums represented by general formula (3)

##STR00001##

(in the formula, M is titanium or zirconium, X are each independently a C1-8 alkyl group): 10-300 mass parts, and (D) an organic solvent: 100-30,000 mass parts,
has an excellent water repellency-imparting effect, and can impart good softness to treated fibers.