The present disclosure is directed to articles that include a cured coating that includes a matrix of crosslinked polymers and optionally a colorant (e.g., pigment particles or dye or both). The cured coating can include a matrix of crosslinked polymers. The cured coating is a product of crosslinking a coating composition comprising uncrosslinked polymers (e.g., a dispersion of uncrosslinked polymers in a carrier to form the matrix of crosslinked polymers), wherein the uncrosslinked polymers are crosslinked to form the matrix of crosslinked polymers. The matrix of crosslinked polymers can be elastomeric. The present disclosure is also directed to articles including these bladders, methods of forming these bladders, and methods of making articles including these bladders, where the bladders include the cured coating.

Fabrics are treated with a hydrophobic treatment that includes at least one hydrophobic monomer and a crosslinker. The treatment is low in volatile organic compounds and water. It is a liquid at 22 C. or a suspension having a phase that is liquid at 22 C. The monomer and crosslinker are cured in a free radical polymerization to form a hydrophobic coating on a fibrous substrate. The curing is performed by removing interstitial air from the fabric and then curing the fabric in a low oxygen environment without allowing it contact with oxygen or air from the time the interstitial air is removed until conversion of monomers reaches at least 50%.

According to one embodiment, a system for manufacturing a fully impregnated thermoplastic prepreg includes a mechanism for moving a fabric or mat and a drying mechanism that removes residual moisture from at least one surface of the fabric or mat. The system also includes a resin application mechanism that applies a reactive resin to the fabric or mat and a press mechanism that presses the coated fabric or mat to ensure that the resin fully saturates the fabric or mat. The system further includes a curing oven through which the coated fabric or mat is moved to polymerize the resin and thereby form a thermoplastic polymer so that upon exiting the oven, the fabric or mat is fully impregnated with the thermoplastic polymer. During at least a portion of the process, humidity in the vicinity of the coated fabric or mat is maintained at substantially zero.

The present disclosure is directed to articles that include one or more coated fiber(s) (i.e., fiber(s) with a cured coating disposed thereon), where the coating includes a matrix of crosslinked polymers and optionally a colorant (e.g., pigment particles or dye or both). The cured coating is a product of crosslinking a coating composition including uncrosslinked polymers (e.g., a dispersion of uncrosslinked polymers in a carrier, wherein the uncrosslinked polymers are crosslinked to form the matrix of crosslinked polymers). The present disclosure is also directed to articles including the coated fibers, methods of forming the coated fibers and articles, and methods of making articles including the coated fibers.

The present disclosure is directed to articles that include one or more coated fiber(s) (i.e., fiber(s) with a cured coating disposed thereon), where the coating includes a matrix of crosslinked polymers and optionally a colorant (e.g., pigment particles or dye or both). The cured coating is a product of crosslinking a coating composition including uncrosslinked polymers (e.g., a dispersion of uncrosslinked polymers in a carrier, wherein the uncrosslinked polymers are crosslinked to form the matrix of crosslinked polymers). The present disclosure is also directed to articles including the coated fibers, methods of forming the coated fibers and articles, and methods of making articles including the coated fibers.

A thermoplastic prepreg includes a web or mesh of fibers in which the web or mesh of fibers includes chopped fibers. The thermoplastic prepreg also includes a thermoplastic material that fully impregnates the web or mesh of fibers so that the thermoplastic prepreg has a void content of less than 5%. The thermoplastic material is polymers that are formed by in-situ polymerization of monomers or oligomers in which greater than 90% of the monomers or oligomers react to form the thermoplastic material. The thermoplastic prepreg includes between 5 and 95 weight percent of the thermoplastic material and the chopped fibers that form the web or mesh of fibers are un-bonded.

According to one embodiment, a system for manufacturing a polymethyl methacrylate (PMMA) prepreg includes a mechanism for continuously moving a fabric or mat and a resin application component that applies a methyl methacrylate (MMA) resin to the fabric or mat. The system also includes a press mechanism that presses the fabric or mat during the continuous movement subsequent to the application of the MMA resin to ensure that the MMA resin fully saturates the fabric or mat. The system further includes a curing oven through which the fabric or mat is continuously moved. The curing oven is maintained at a temperature of between 40 C. and 100 C. to polymerize the MMA resin and thereby form PMMA so that upon exiting the curing oven, the fabric or mat is fully impregnated with PMMA.

A method for improving the translation efficiency of fiber strength into composite strength is provided. A single unidirectional tape, single unidirectional fiber web or a stack of unidirectional web/unidirectional tape plies formed from partially oriented fibers/tapes is primed under mild conditions followed by subjecting the primed plies to an axial extension stress in the axial fiber direction of each fiber ply by passage through a compression apparatus. The axial extension stress extends the fibers, strengthening them, while also compacting the plies together and thereby forming a composite having improved strength. Production yield is improved by avoiding maximal fiber stretching and thereby avoiding typical manufacturing loss, and low weight composite armor having increased strength is achieved.

A method for improving the translation efficiency of fiber strength into composite strength is provided. A single unidirectional tape, single unidirectional fiber web or a stack of unidirectional web/unidirectional tape plies formed from partially oriented fibers/tapes is primed under mild conditions followed by subjecting the primed plies to an axial extension stress in the axial fiber direction of each fiber ply by passage through a compression apparatus. The axial extension stress extends the fibers, strengthening them, while also compacting the plies together and thereby forming a composite having improved strength. Production yield is improved by avoiding maximal fiber stretching and thereby avoiding typical manufacturing loss, and low weight composite armor having increased strength is achieved.

The application relates to a process for forming a nonwoven composite. The process includes forming a lofty nonwoven layer, obtaining a thermoplastic polymer, and applying the thermoplastic polymer to the second surface of the nonwoven layer, where the thermoplastic polymer is in the form of a molten polymer, semi-molten polymer, or solid film. Next, pressure and optionally heat is applied to the nonwoven layer and thermoplastic polymer, where the thermoplastic polymer and the second surface of the nonwoven layer are subjected to a textured surface forming a plurality of peak regions and a plurality of valley regions in the second surface of the nonwoven layer and embedding a portion of the primary fibers from the nonwoven layer into the thermoplastic polymer within the valley regions. The thermoplastic polymer is cooled forming a thermoplastic film and the nonwoven layer which together form the nonwoven composite.