Foamable aqueous compositions can be foamed and applied to porous substrates to make light-blocking dry opacifying elements. Such compositions have 0.05-15 weight % of porous particles; at least 20 weight % of a binder; at least 0.0001 weight % of additives (including a surfactant); water; and at least 0.001 weight % of an opacifying colorant. Each porous particle includes a continuous polymeric phase and discrete pores; a mode particle size of 2-50 m; and a porosity of 20-70 volume %. The continuous polymeric phase T.sub.g is >80 C. and has a polymer viscosity of 80-500 centipoises at an ethyl acetate shear rate of 100 sec.sup.1 at a concentration of 20 weight % at 25 C. The dry opacifying element light blocking value is at least 4 and has a luminous reflectance >40% as measured by the color space Y tristimulus value. The foamed aqueous composition has a foam density of 0.1-0.5 g/cm.sup.3.

A waterborne polyurethane dispersion for the polyurethane foam of synthetic leather application, derived from (1) a prepolymer derived from the reaction of reactants comprising at least one aromatic isocyanate compound, an ethylene oxide-capped polyether triol, at least one polyether diol, and at least one polyester diol; (2) water; and (3) surfactant, is disclosed. The waterborne polyurethane dispersion can be used to prepare a synthetic leather product having superior wrinkle resistance, hand-feeling and peel strength. A synthetic leather article prepared with said waterborne polyurethane dispersion is also disclosed.

The invention relates to flame-retardant foam coatings for textile sheet products, wherein the coatings include plate-like expandable graphite which has a reduced salt content and a particle distribution with a proportion of >80 percent by weight having a diameter of at least 0.2 mm, and/or a minimum proportion of 70% having a mesh size of >50 mesh (0.3 mm), at least one binder and at least one foam stabilizer, and also processes for the production thereof, the use thereof for producing textile sheet products and also textile sheet products having such flame-retardant foam coatings.

The present disclosure is drawn to a fabric print medium including a fabric substrate, a primary coating layer, and a secondary coating layer. The fabric substrate can have a first side and a second side. The primary coating layer can be applied to the first side of the fabric substrate at a thickness from 2 m to 250 m with a dry coat weight ranging from about 5 gsm to about 300 gsm and can include a polymeric binder and filler particles. The secondary coating layer can be applied to the primary coating layer at a thickness from 1 m to 50 m with a dry coat weight ranging from 0.5 gsm to 50 gsm and can include a first crosslinked polymeric network and a second crosslinked polymeric network. The primary coating layer can be two or more times thicker than the secondary coating layer.

Foamed, opacifying element comprising a thermal colorant image is prepared using a porous substrate having an opposing external surface and an internal surface, and a dry foamed composition disposed on the internal surface of the porous substrate as a dry opacifying layer that has a light blocking value of at least 4 as well as a luminous reflectance that is greater than 40% as measured by the Y tristimulus value. A thermal colorant image is provided on either the opposing external surface, the dry opacifying layer, or both the opposing external surface and the dry opacifying layer, by thermal colorant transfer from a thermal donor element comprising a colorant donor layer having one or more thermal colorants.

Foamable aqueous compositions can be foamed and applied to porous substrates to make light-blocking dry opacifying elements. Such compositions have 0.05-15 weight % of porous particles; at least 20 weight % of a binder; at least 0.0001 weight % of additives (including a surfactant); water; and at least 0.001 weight % of an opacifying colorant. Each porous particle includes a continuous polymeric phase and discrete pores; a mode particle size of 2-50 m; and a porosity of 20-70 volume %. The continuous polymeric phase T.sub.g is >80 C. and has a polymer viscosity of 80-500 centipoises at an ethyl acetate shear rate of 100 sec.sup.1 at a concentration of 20 weight % at 25 C. The dry opacifying element light blocking value is at least 4 and has a luminous reflectance >40% as measured by the Y tristimulus value. The foamed aqueous composition has a foam density of 0.1-0.5 g/cm.sup.3.

A foamed, opacifying element has a thermal colorant image on either an opposing external surface and an internal surface of a porous substrate. The internal surface has a dry foamed composition disposed thereon as a dry opacifying layer that comprises: (a) 0.1-40 weight % of porous particles; (b) at least 10 weight % of an at least partially cured binder material; (c) at least 0.2 weight % of one or more additives comprising a surfactant; (d) less than 5 weight % of water; and (e) at least 0.002 weight % of an opacifying colorant different from all of the one or more (c) additives, which opacifying colorant absorbs predetermined electromagnetic radiation. The thermal colorant image is derived from thermal colorant transfer of sublimable colorants from a thermal donor element.

A foamed, opacifying element has a thermal colorant image on either an opposing external surface and an internal surface of a porous substrate. The internal surface has a dry foamed composition disposed thereon as a dry opacifying layer that comprises: (a) 0.1-40 weight % of porous particles; (b) at least 10 weight % of an at least partially cured binder material; (c) at least 0.2 weight % of one or more additives comprising a surfactant; (d) less than 5 weight % of water; and (e) at least 0.002 weight % of an opacifying colorant different from all of the one or more (c) additives, which opacifying colorant absorbs predetermined electromagnetic radiation. The thermal colorant image is derived from thermal colorant transfer of sublimable colorants from a thermal donor element.

Foamed, opacifying element comprising a thermal colorant image is prepared using a porous substrate having an opposing external surface and an internal surface, and a dry foamed composition disposed on the internal surface of the porous substrate as a dry opacifying layer that has a light blocking value of at least 4 as well as a luminous reflectance that is greater than 40% as measured by the Y tristimulus value. A thermal colorant image is provided on either the opposing external surface, the dry opacifying layer, or both the opposing external surface and the dry opacifying layer, by thermal colorant transfer from a thermal donor element comprising a colorant donor layer having one or more thermal colorants.

A foamed, opacifying element has a porous substrate composed of woven yarn strands composed of a thermoplastic polymer-coated multifilament core. It has a dry foamed composition on an opposing surface of the substrate, which includes: (a) 0.1-40 weight % of porous particles; (b) 10-80 weight %; (c) 0.2-50 weight % of one or more additives selected from the group consisting of dispersants, plasticizers, flame retardants, optical brighteners, thickeners, biocides, fungicides, tinting colorants, metal flakes, and inert inorganic or organic fillers; (d) less than 5 weight % of water; and (e) at least 0.002 weight % of an opacifying colorant different from all of the one or more additives of (c), which opacifying colorant absorbs electromagnetic radiation having a wavelength of 380-800 nm. The elements have a light-blocking value (LBV) of at least 4 and can have a bending stiffness that is greater than 0.15 milliNewtons-meter.