The present disclosure is relates to an artificial leather and a manufacturing method thereof. The artificial leather includes a substrate, an adhering glue layer, a moldable surface layer, a TPU adhering layer, a TPU layer and a bottom layer. The substrate includes a first surface and a second surface. The adhering glue layer is disposed on the first surface of the substrate. The moldable surface layer is disposed on the adhering glue layer. The TPU adhering layer is disposed on the second surface of the substrate. The TPU is disposed on a surface of the TPU adhering layer. The bottom layer is disposed on a surface of the TPU layer. The moldable surface layer of the artificial leather has a texture of leather and color effect. The bottom layer has a villus effect and high wear resistance.

The present invention concerns a process for preparing a microfibrous multilayer composite material comprising: 1) realizing a non-woven microfibrous semi-finished product made up of microfibres of one or more polymers dispersed in a polyurethane matrix (semi-finished product IE); 2) cutting the semi-finished product lengthwise into two layers; 3) buffing at least one layer on one side (side N) so as to extract the microfibres and form the nap, thereby obtaining a semi-finished raw product; 4) cutting at least one semi-finished raw product lengthwise parallel to the surfaces, producing an non-woven intermediate product, containing the buffed side (side N) and a waste layer (containing the side that has not been buffed—side S); 5) coupling the non-woven intermediate product (on the side opposite side N) to a fabric made of polyethylene terephthalate fibres by means of the application of a thermoplastic polyurethane adhesive that can be cross-linked between the non-woven intermediate product and the fabric; 6) submitting the multilayer composite material to a jet dyeing process. The invention also concerns a multilayer composite material that can be obtained by the process of the invention and the use thereof for covering the internal side of roofs or headliners of vehicles and for covering furnishing elements.

A sheet material includes a polymeric elastomer and a fiber-entangled body including, as a constituent element, a nonwoven fabric including ultrafine fibers having an average single fiber diameter of 1.0 μm or more and 10.0 μm or less. The ultrafine fibers include a polyester-based resin including a black pigment (a.sub.1). The black pigment (a.sub.1) has an average particle diameter of 0.05 μm or more and 0.20 μm or less and has a coefficient of variation (CV) of the average particle diameter of 75% or less. The polymeric elastomer includes a polyurethane including a black pigment (b). The sheet material has a nap coverage of 70% or more and 100% or less on a surface having a nap.

A purpose of the present invention is to provide a sheet-shaped article and a manufacturing method therefor, said sheet-shaped article demonstrating both a supple texture and superior wear resistance. In order to achieve this purpose, a sheet-shaped article according to the present invention is a sheet-shaped article that includes, in a fibrous base material, a polymer elastic body with a hydrophilic group, said fibrous base material comprising extremely fine fibers with an average individual fiber fineness of 0.1 μm to 10 μm, wherein the sheet-shaped article has N-acylurea bonding or isourea bonding within the polymer elastic body, and a monovalent positive ion-including inorganic salt is present at a rate of 0.1 mass % to 5 mass % with regard to the mass of the polymer elastic body.

Disclosed is a napped artificial leather including: an artificial leather base material that includes a non-woven fabric of polyester fibers having a Young's modulus of 1 to 6 GPa, an average fiber-toughness of 8 to 40 cN.Math.%, and a crystallinity of 35% or less, and an elastic polymer, the artificial leather base material having, on at least one surface thereof, a napped surface on which the polyester fibers are napped. Also disclosed are polyester fibers having a Young's modulus of 1 to 6 GPa, an average fiber-toughness of 8 to 40 cN.Math.%, and a crystallinity of 35% or less, and a non-woven fabric including the polyester fibers.

A napped artificial leather including a non-woven fabric including ultrafine fibers and a polyurethane, the napped artificial leather including a napped surface formed by napping the ultrafine fibers on a surface thereof, wherein the napped surface has, after a Martindale abrasion test in accordance with JIS L 1096 (6.17.5E method, Martindale method) under a pressing load of 12 kPa and 50000 times of abrasions, a ratio of the polyurethane observed by a surface observation using an electron microscope in a portion that has been subjected to the Martindale abrasion test, of 4.0% or less.

Disclosed is a colored napped artificial leather including: a fiber-entangled body including ultrafine fibers having an average single fiber fineness of 0.5 dtex or less; and an elastic polymer impregnated into the fiber-entangled body, the napped artificial leather having, at least on one side thereof, a napped surface formed by napping the ultrafine fibers, wherein the napped artificial leather further includes particles of a fatty acid amide-based compound that are at least attached to surfaces of the ultrafine fibers and that have an average particle size of 0.1 to 10 μm.

A napped artificial leather includes: a fiber-entangled body obtained by entangling ultrafine fibers: and an elastic polymer impregnated into the fiber-entangled body. The napped artificial leather has, on at least one side thereof, a napped surface formed by napping the ultrafine fibers. The ultrafine fibers contain 0.2 to 8 mass% of carbon black and 0.1 to 5 mass% of a chromatic pigment, and a total ratio of the carbon black and the chromatic pigment is 0.3 to 10 mass%. A content ratio of the elastic polymer is 0.1 to 15 mass% in the napped artificial leather. The elastic polymer is uncolored and the ultrafine fibers are undyed.

Disclosed is a napped artificial leather including: a fiber-entangled body including ultrafine fibers having a fineness of 0.5 dtex or less; and an elastic polymer impregnated into the fiber-entangled body, the napped artificial leather having a thickness of 0.25 to 1.5 mm, and including a main surface that is a napped surface formed by napping the ultrafine fibers. The napped artificial leather further includes phosphorous-based flame retard ant particles attached to the elastic polymer such as a polyurethane, the phosphorous-based flame retardant particles being locally present in a range of a thickness of 200 pm or less from a back surface opposite to the main surface. The phosphorous-based flame retardant particles have an average particle size of 0.1 to 30 μm, a phosphorus atom content of 14 mass % or more, and a solubility in water at 30° C. of 0.2 mass % or less, and a melting point, or, in the absence of a melting point, a decomposition temperature, of 150° C. or more, and a content ratio of the phosphorous-based flame retardant particles is 1 to 6 mass % as a content ratio in terms of phosphorus atoms.

An artificial leather is provided that, due to excellent texture and mechanical strength (abrasion resistance, etc.), can be appropriately used in, for example, clothing products, or sheets of skin material or interior material, etc. for interiors, automobiles, airplanes, rail cars, etc. One embodiment of the present invention is an artificial leather that includes a fiber sheet and a polyurethane resin, wherein the fiber sheet includes a scrim that is a woven or knitted fabric, and a fiber layer (A) that constitutes a first outer surface of the artificial leather, such that in a thickness direction cross-section of the fiber layer (A), the ratio (d/D) of the total area (d) of the polyurethane resin that forms a closed shape having an area of 100 μm2 or more to the total area (D) of the polyurethane resin satisfies the following formula (1): 5≤(d/D)×100≤50 (%).