The present invention pertains to an aqueous ink containing mixtures of solvent dyes and disperse dyes suitable for printing on hydrophobic textile substrates.

The present invention is directed to dye mixtures comprising dye(s) of formula (1)

##STR00001##

and specific other dyes, the process for the production of these mixtures as well as their use for dyeing textiles.

The present invention relates to disperse azo dyes of formula

##STR00001##

wherein

R.sub.1 is bromo, nitro, cyano, methyl, methoxy or trifluoromethyl;

R.sub.2 is hydrogen, chloro, bromo or trifluoromethyl;

R.sub.3 is hydrogen, chloro, bromo, methoxy, trifluoromethyl, nitro or cyano; and

R.sub.4 is methyl, ethyl, n-propyl, 2-methoxyethyl, methoxycarbonylmethyl or 2-methoxycarbonylethyl;

with the proviso that R.sub.1 is cyano in case R.sub.2 denotes chloro or bromo,

to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.

The present invention relates to disperse azo dyes of formula

##STR00001##

wherein

R.sub.1 is bromo, nitro, cyano, methyl, methoxy or trifluoromethyl;

R.sub.2 is hydrogen, chloro, bromo or trifluoromethyl;

R.sub.3 is hydrogen, chloro, bromo, methoxy, trifluoromethyl, nitro or cyano; and

R.sub.4 is methyl, ethyl, n-propyl, 2-methoxyethyl, methoxycarbonylmethyl or 2-methoxycarbonylethyl;

with the proviso that R.sub.1 is cyano in case R.sub.2 denotes chloro or bromo,

to a process for the preparation of such dyes and to their use in the dyeing or printing of semi-synthetic and, especially, synthetic hydrophobic fibre materials, more especially textile materials.

The present invention is directed to high wet fast brilliant blue disperse dye mixtures comprising dye(s) of formula (I) ##STR00001##
and of formula (II) ##STR00002##
their production and their use for textile dyeing and printing.

The present invention is directed to high wet fast brilliant blue disperse dye mixtures comprising dye(s) of formula (I) ##STR00001##
and of formula (II) ##STR00002##
their production and their use for textile dyeing and printing.

An ink jet ink composition contains a dye having an azo group, water, and a hindered amine compound having a radical. The dissolved nitrogen concentration of the ink composition is 10 ppm or less.

An ink jet ink composition contains a dye having an azo group, water, and a hindered amine compound having a radical. The dissolved nitrogen concentration of the ink composition is 10 ppm or less.

The present invention relates to azo dyes of formula (1), wherein D is a radical of formula (2) or (3), R.sub.1 and R.sub.2 independently denote hydrogen; C.sub.6-C.sub.10 aryl which is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; C.sub.1-C.sub.12alkyl which may be interrupted one or more times by O, S, NR.sub.4, CO, COO or OOC, and is unsubstituted or substituted by cyano, carboxy, hydroxy, C.sub.6-C.sub.10 aryl, or C.sub.6-C.sub.10 aryloxy, which C.sub.6-C.sub.10 aryl or C.sub.6-C.sub.10 aryloxy is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; R.sub.3 and R.sub.4 are each independently of the other hydrogen, halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.5 is halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.6, R.sub.7, R.sub.8 and R.sub.9 independently of each other are hydrogen, hydroxy, halogen, cyano, nitro or C.sub.1-C.sub.4 alkanoylamino, and the radicals X independently denote N or CH, with the proviso that at least one radical X denotes CH, which are distinguished by their good lightfastness properties. ##STR00001##

The present invention relates to azo dyes of formula (1), wherein D is a radical of formula (2) or (3), R.sub.1 and R.sub.2 independently denote hydrogen; C.sub.6-C.sub.10 aryl which is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; C.sub.1-C.sub.12alkyl which may be interrupted one or more times by O, S, NR.sub.4, CO, COO or OOC, and is unsubstituted or substituted by cyano, carboxy, hydroxy, C.sub.6-C.sub.10 aryl, or C.sub.6-C.sub.10 aryloxy, which C.sub.6-C.sub.10 aryl or C.sub.6-C.sub.10 aryloxy is unsubstituted or substituted by cyano, carboxy, hydroxy, halogen, C.sub.1-C.sub.6alkyl, or C.sub.1-C.sub.6alkoxy; R.sub.3 and R.sub.4 are each independently of the other hydrogen, halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.5 is halogen, nitro, cyano, trifluoromethyl, carboxy, C.sub.1-C.sub.6alkyl, C.sub.1-C.sub.6alkoxy, C.sub.1-C.sub.6alkylcarbonyl, C.sub.6-C.sub.10 arylcarbonyl, C.sub.1-C.sub.6alkoxycarbonyl, C.sub.1-C.sub.6alkylsulfonyl, C.sub.1-C.sub.6alkylsulfonylamino or C.sub.1-C.sub.4 alkanoylamino; and R.sub.6, R.sub.7, R.sub.8 and R.sub.9 independently of each other are hydrogen, hydroxy, halogen, cyano, nitro or C.sub.1-C.sub.4 alkanoylamino, and the radicals X independently denote N or CH, with the proviso that at least one radical X denotes CH, which are distinguished by their good lightfastness properties. ##STR00001##