The present invention is related to a novel high fixation ink composition for digital textile printing, which comprises: (A) at least one reactive dye compound with two reactive groups in an amount of 1% to 50% by weight; (B) an organic buffer in an amount of 0.05% to 10% by weight; (C) a humectant in an amount of 10% to 50% by weight; and (D) a solvent in remaining amount. When the aforesaid ink composition is applied in digital textile printing, fixation rate of dye on fabrics is high.

Disclosed are reactive dyes and preparation methods thereof. The reactive dye may be prepared using heterocyclic primary amine as a diazo component, 4,4-diamino-2,2-stilbenedisulfonic acid, s-triazine, or ethylenediamine as a bridging group, and a dimonochlortriazine group as an active group. The color-changing compound is covalently bonded into the fiber chemical structure by nucleophilic substitution reaction between monochlorotriazine and the hydroxyl group in a textile structure, and the size of the conjugated system and the range of electron delocalization of the dye are changed by a reversible isomerization reaction of the hydroxyl group adjacent to the diazo group and the diazo group under different pH regulations. Moreover, the dye has a double color changing structure, which improves the capability of the dye combined with H/OH. The pH value range that can cause color changes in the dye is effectively expanded to include weak alkali, weak acid or even neutral conditions.

An ink jet ink composition for textile printing including a dye and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 15 to 80 degrees.

An ink jet ink composition for textile printing including a dye containing copper or chromium and 5% to 30% by mass of a cyclic amide that is liquid at normal temperature and that has a normal boiling point in the range of 190 C. to 260 C., wherein the hue angle h defined by the CIELAB color space on a recording medium ranges from 260 to 310 degrees.

An ink jet textile printing ink composition includes water; a color material; and a metal chelating agent. In the ink composition described above, the metal chelating agent includes at least one selected from methyl glycine diacetic acid, L-glutamate diacetic acid, L-aspartic diacetic acid, hydroxyethylimino diacetic acid, 3-hydroxy-2,2-iminodisuccucinic acid, dicarboxymethyl glutamic acid, (S,S)-ethylenediaminedisuccinic acid, and salts thereof, and the pH of the ink composition is 6 to 10.

The present invention refers to a process for the direct cationization of cotton fiber and its dyeing with reactive dyes. The opening of the initial fiber is carried out with two cylinders with rounded tips. Subsequently, the fiber is impregnated with cationizing agents in a vat and then sent to an autoclave with soft water. The soft water vapor present in the autoclave heats the fiber and allows the fixation of the reagents in a homogeneous way. The fiber is rinsed, neutralized and centrifuged before being dried. The fiber obtained is converted into yarn. The cationized yarn forms a fabric to be dyed.

The present invention refers to a process for the direct cationization of cotton fiber and its dyeing with reactive dyes. The opening of the initial fiber is carried out with two cylinders with rounded tips. Subsequently, the fiber is impregnated with cationizing agents in a vat and then sent to an autoclave with soft water. The soft water vapor present in the autoclave heats the fiber and allows the fixation of the reagents in a homogeneous way. The fiber is rinsed, neutralized and centrifuged before being dried. The fiber obtained is converted into yarn. The cationized yarn forms a fabric to be dyed.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2) ##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

A process for the simultaneous tanning and dyeing of collagen containing fibrous material, wherein the said material is treated with a liquor containing at least one reactive dyestuff selected from the group of formula (1) and (2) ##STR00001## wherein A.sub.1, A.sub.2 and A.sub.3 are each independently of the others the radical of a monoazo, polyazo, metal-complexed azo, anthraquinone, phthalocyanine, formazan or dioxazine chromophore having at least one sulfo group, B is an organic bridge member, Q.sub.1, Q.sub.2, Q.sub.3 and Q.sub.4 are each independently of the others hydrogen or unsubstituted or substituted C.sub.1-C.sub.4alkyl, G.sub.1 and G.sub.2 are halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, (Z.sub.1).sub.2-3 is 2 to 3 identical or different fiber reactive radicals, Z.sub.2 and Z.sub.3 are each independently of the other identical or different fiber reactive radicals, and b is the number 0 or 1, by combining two steps of leather production, tanning and dyeing, into a single step, thus, preserving resources and reducing the environmental impact.

A dye mixture comprising at least one dye of formula (formula) and at least one dye of formula (formula), wherein R.sub.1 is hydrogen or C.sub.1-C.sub.4alkyl, R.sub.2 is hydrogen or C.sub.1-C.sub.4alkyl, C.sub.1-C.sub.4alkoxy or sulfo, Q.sub.1 is a fibre-reactive radical of formula (CH.sub.2).sub.2- 3SO.sub.2Y.sub.2 (3a) or (CH.sub.2).sub.2-3O(CH.sub.2).sub.2-3SO.sub.2Y.sub.3 (3b), Q.sub.2 has the meaning of Q.sub.1, or is hydrogen or C.sub.1-C.sub.4alkyl, X.sub.1 and X.sub.2 are each independently of the other halogen, 3-carboxypyridin-1-yl or 3-carbamoylpyridin-1-yl, Y.sub.1, Y.sub.2 and Y.sub.3 are each independently of the others vinyl or a radical CH.sub.2CH.sub.2U and U is a group removable under alkaline conditions, Z.sub.1 and Z.sub.2 are each independently of the other S0.sub.2-Y, wherein Y is vinyl or a radical CH.sub.2CH.sub.2U and U is a group removable under alkaline conditions, M is hydrogen, an alkali metal or one equivalent of an alkaline earth metal, k and n are each independently of the other the number 0, 1 or 2, I and q are each independently of the other the number 0 or 1, m is the number 0 or 1, and wherein the diazo component of the dye of formula (1) and the diazo component of the dye of formula (2) each independently of the other are a benzene radical or a naphthyl radical, are suitable especially for the dyeing or printing of cellulosic fibre materials, exhibit a good build-up, a good fixation rate and good washing off properties of the unfixed dyes, and good all-round fastness properties. ##STR00001##