Methods for obtaining natural colorants from plant material (e.g., tobacco material) and for using such natural colorants to dye various substrates are provided. Natural colorants are obtained using particular enzymes and particular conditions (e.g., time, temperature, and pH profiles). Such colorants can be used to dye substrates, for example, using conventional dyeing techniques or using unique in situ methods.

Methods for obtaining natural colorants from plant material (e.g., tobacco material) and for using such natural colorants to dye various substrates are provided. Natural colorants are obtained using particular enzymes and particular conditions (e.g., time, temperature, and pH profiles). Such colorants can be used to dye substrates, for example, using conventional dyeing techniques or using unique in situ methods.

A leuco polymer includes a leuco monomer and an alkene. The leuco polymer has a molecular weight of at least 500 and is obtainable by polymerization of the leuco monomer and one or more alkene co-monomers. The leuco monomer consists of an alkene covalently bound to a leuco moiety and the leuco monomer has a molar extinction coefficient at a wavelength in the range 400 to 750 nm of less than 1000 M.sup.1cm.sup.1. The alkene monomer(s) have a molar extinction coefficient at a wavelength in the range 400 to 750 nm that is less than 100 M.sup.1cm.sup.1. Methods of making the leuco polymer, laundry care compositions comprising the leuco polymer and methods of treating textiles with such laundry care compositions.

The present invention relates to a method of colouring polymer substrates at low temperatures. The method comprises subjecting the polymer substrate that is to be coloured to a colouring liquor comprising a solvent in which the colourant has a high solubility and then adding a solvent in which the colourant has a low solubility, typically water.

The present invention relates to a method of colouring polymer substrates at low temperatures. The method comprises subjecting the polymer substrate that is to be coloured to a colouring liquor comprising a solvent in which the colourant has a high solubility and then adding a solvent in which the colourant has a low solubility, typically water.

Functionalizing a fibrous material having a plurality of hydroxyl groups includes reacting the fibrous material with a compound of Formula I: ##STR00001##
where X is a monovalent counteranion for the quaternary ammonium cation of Formula I and Hal is a halogen atom, to obtain the functionalized fibrous material. Also provided is a functionalized fibrous material prepared by any one of the methods described herein (e.g., a functionalized fiber including a moiety of Formula II: ##STR00002##
having an odor of free amine below the threshold of detection, or having an odor of free amine with degree of offensiveness of about 3 or less. The functionalized fibrous material may be dyed, and articles of clothing may be made from the dyed functionalized fibrous material.

Functionalizing a fibrous material having a plurality of hydroxyl groups includes reacting the fibrous material with a compound of Formula I: ##STR00001##
where X is a monovalent counteranion for the quaternary ammonium cation of Formula I and Hal is a halogen atom, to obtain the functionalized fibrous material. Also provided is a functionalized fibrous material prepared by any one of the methods described herein (e.g., a functionalized fiber including a moiety of Formula II: ##STR00002##
having an odor of free amine below the threshold of detection, or having an odor of free amine with degree of offensiveness of about 3 or less. The functionalized fibrous material may be dyed, and articles of clothing may be made from the dyed functionalized fibrous material.

An aqueous dispersion of capsules including a resin having at least one repeating unit of formula I, II, and/or III and which is obtainable by contacting, in a liquid including water, a compound A including at least 2 functional groups selected from the functional groups XC(O)CHR1-C(O)R2, XC(O)CCR2; or XC(O)CR1CR2-NR11R12, with a compound B including at least two of NH.sub.2, NH.sub.3.sup.++, or NCO. A method of producing the aqueous dispersion further relates to an aqueous ink jet ink including the resin capsules.

##STR00001##

A method for coloring of cellulose in a supercritical CO.sub.2 medium by an uncharged hydrophobic dye, including at least the steps including of: (i) provision of cellulose fibers, (ii) placing the cellulose fibers in the presence of: a) an effective quantity of at least one uncharged mono organo-urea primer of formula RNHCONH.sub.2, where R represents a linear or branched, saturated or unsaturated, hydrocarbon chain possessing at least 3 carbon atoms, or a saturated or unsaturated cyclic hydrocarbon radical, which is bonded directly or via a methylene or ethylene group to a nitrogen atom, and if appropriate substituted under conditions conducive to the forming of a covalent carbamatic bond between the cellulose and the molecules of the organo-urea; and b) at least one hydrophobic dye in a supercritical CO.sub.2 medium, under conditions conducive to the immobilization of the dye on the fibers.

A method for coloring of cellulose in a supercritical CO.sub.2 medium by an uncharged hydrophobic dye, including at least the steps including of: (i) provision of cellulose fibers, (ii) placing the cellulose fibers in the presence of: a) an effective quantity of at least one uncharged mono organo-urea primer of formula RNHCONH.sub.2, where R represents a linear or branched, saturated or unsaturated, hydrocarbon chain possessing at least 3 carbon atoms, or a saturated or unsaturated cyclic hydrocarbon radical, which is bonded directly or via a methylene or ethylene group to a nitrogen atom, and if appropriate substituted under conditions conducive to the forming of a covalent carbamatic bond between the cellulose and the molecules of the organo-urea; and b) at least one hydrophobic dye in a supercritical CO.sub.2 medium, under conditions conducive to the immobilization of the dye on the fibers.