Patent classifications
D21B1/021
A Lignin-Containing Cellulose Nanofiber, a Paper and a Film Comprising the Said Lignin-Containing Cellulose Nanofiber
The present invention relates to a lignin-containing cellulose nanofiber characterized in that (a) the said lignin-containing cellulose nanofiber has a content of carboxyl group in a range of 0.2-1.5 mmol/g, (b) the said lignin-containing cellulose nanofiber has Zeta potential in a range of 100 to 35 mV, and (c) the said lignin-containing cellulose nanofiber has an average diameter in a range of 3-30 nm. In addition, the present invention further relates to a paper and a film comprising the said lignin-containing cellulose nanofiber. The present invention also relates to a process for preparing a lignin-containing cellulose nanofiber comprising steps of (i) treating a lignin-containing cellulosic material with an organic solvent, (ii) treating the cellulosic material treated from the step (i) with derivative of N-oxy radical compound and hypochlorite compound, and (iii) mechanical treating the cellulosic material treated from the step (ii).
METHOD AND SYSTEM FOR PROCESSING LIGNOCELLULOSE MATERIAL
A method for processing lignocellulose materials comprising the steps of hydrothermal treatment of the material with saturated or superheated steam in a hydrothermal pressure vessel, wherein the steam is provided by means of a steam boiler. The treatment is performed at a pressure of 5-30 bars, and at a temperature of 160-240 C. for a duration of 1-20 minutes. The method further comprises discharging hydrothermally treated lignocellulose material and steam from the pressure vessel by means of rapid pressure reduction, separating the steam and vapours released from the lignocellulose material, and burning the vapours together with additional fuel and combustion air in the furnace of said steam boiler. Furthermore, a corresponding system is provided.
ECONOMICAL METHODS FOR PERFORMING OXIDATIVE CATALYTIC PRETREATMENT OF PLANT BIOMASS USING A HOMOGENEOUS CATALYST SYSTEM
An improved alkaline pretreatment of biomass is provided that uses a homogenous catalyst with one or more metals and metal coordinating ligands, wherein the homogeneous catalyst is used with at least two oxidants in an oxidation reaction to catalytically pretreat lignocellulosic biomass. In one embodiment, hydrogen peroxide and oxygen are utilized as co-oxidants during alkaline-oxidative pretreatment to improve biomass pretreatment and increase enzymatic digestibility. In one embodiment, the homogenous catalyst is copper (II) 2,2-bipyridine (Cu(bpy)). Related methods are also disclosed to improve the economic feasibility of production of lignocellulose derived sugars.
METHOD OF PROVIDING A PAPER FIBRE COMPOSITION
The present invention relates to a method of production of a paper fibre composition, comprising the steps of: a) Providing a vessel, b) Providing Na.sub.2S0.sub.3 in the range of 12-122 kg/bdt combined with NaOH in the range of 0-97 kg/bdt, or NaHSO.sub.3 in the range of 10-100 kg/bdt combined with NaOH in the range of 10-100 kg/bdt to said vessel, c) Providing wood, preferably softwood chips to said vessel for pre-treatment, d) Providing heat and pressure to said vessel in order be able control the vessel to have a temperature T comprised in the range of 160 C.-184 C., e) Controlling the retention time t for the wood chips, in relation to the temperature T of the content of the vessel, wherein T is controlled to be within the range of step d) and t is controlled to be in the range of 2-27 min, preferably in the range of 2-25 min, more preferred in the range of 5-20 min, f) Providing a defibration device coupled to the outlet of said vessel, the defibriation device being a refiner, mill, defibrator, fiberizer, or the like, g) Providing the pre-treated wood chips to the defibration device, h) Providing an energy consumption of 75-1000 kWh/bdt in said defibration device. The invention also relates to a paper fibre composition prepared by the method and a paper or paperboard or molded pulp made from the paper fibre composition.
RHEOLOGY CONTROL OF NANOCELLULOSE TREATMENT FLUIDS
Included are methods and systems for controlling the rheology of a treatment fluid. An example method comprises selecting a cellulose feedstock source to provide a cellulose capable of being processed into a nanocellulose having an average desired aspect ratio, and processing the cellulose with a cellulose processing technique to provide the nanocellulose with the average desired aspect ratio. The method further comprises adding the nanocellulose to the treatment fluid; wherein the nanocellulose alters a rheological property of the treatment fluid to provide an altered treatment fluid, and introducing the altered treatment fluid into a wellbore.
CELLULOSE NANOFIBER, SHEET-LIKE MATERIAL OBTAINED THEREFROM, AND METHOD FOR PRODUCING CELLULOSE NANOFIBER AND SHEET-LIKE MATERIAL
The present invention provides: a cellulose nanofiber enabling the provision of a high-performance sheet-like material; a method for producing the cellulose nanofiber; and a sheet-like material obtained from the cellulose nanofiber. A bamboo-derived cellulose nanofiber having a cellulose purity of at least 90%, a fiber diameter of 10-20 nm, and a crystallinity of at least 70% can be obtained by a method comprising: (1) a step for subjecting a bamboo material to an alkali treatment and a mechanical treatment to prepare bamboo fibers; (2) a step for delignificating the obtained bamboo fibers; (3) a step for mechanically spreading the delignificated bamboo fibers; (4) a step for removing hemicellulose from the spread bamboo fibers; and (5) a step for removing metal components from the bamboo fibers from which hemicellulose has been removed. A high strength sheet material having a tensile strength of 7-200 N for a basis weight of 10-210 g/m.sup.2 or a high strength sheet material having a tensile strength of 7-200 N for a density of 0.3-1.1 g/cm.sup.3 can be obtained by making this cellulose nanofiber into a sheet.
METHOD FOR CONTROLLING THERMOPLASTICITY AND TOUGHNESS OF REDOX-MODIFIED PLANT FIBER AND USE THEREOF
The present disclosure relates to a method for controlling thermoplasticity and toughness of a redox-modified plant fiber, comprising following steps: (1) pretreating a plant fiber; (2) obtaining an oxidation-modified plant fiber by adding an oxidant solution, then filtering, and washing; and obtaining the redox-modified plant fiber by adding a reductant solution, then filtering, and washing; and (3) fully mixing a plasticizer with the redox-modified plant fiber; the plasticizer being a hydroxyl plasticizer, an ionic liquid plasticizer, a deep eutectic solvent, an ester plasticizer, an amine plasticizer, a glycidyl plasticizer, or an inorganic salt plasticizer. The method according to the present disclosure can improve the toughness of the redox-modified plant fiber material, reduce the processing temperature of the plant fiber material, and broaden the processing window of the plant fiber material.
METHODS OF DEFIBRILLATING CELLULOSIC SUBSTRATES AND PRODUCING CELLULOSES USING A NEW FAMILY OF FUNGAL LYTIC POLYSACCHARIDE MONOOXYGENASES (LPMO)
Celluloses, notably nanocelluloses, and more particularly processes for manufacturing cellulose fibers and for defibrillating cellulose-based substrates. Most particularly, processes for defibrillating cellulose-based substrates and manufacturing celluloses, in particular nanocelluloses (NC), using a new family of fungal lytic polysaccharide monooxygenases (LPMOs).
Preparation Method of Tea Residue Fiber Raw Materials and Application Thereof
A preparation method of tea residue fiber raw materials includes steps of (1) sun-drying tea residues, crushing the sun dried tea residues, and treating them with concentrated hydrochloric acid and a strong base in succession; (2) extracting water from the treated tea residues to obtain tea polyphenols and pulp respectively, cooking the pulp, and then pressing and dehydrating it to obtain coarse pulp; (3) sequentially grinding and sieving the pulp, and beating it; and (4) adding -cyclodextrin, carboxymethylcellulose sodium, and reinforced starch after the beating, adjusting the pH to 7-8, diluting, adding the tea polyphenols obtained in the second step, stirring uniformly, pressing and dehydrating, and drying to obtain the tea residue fiber raw material.
Nanofibrillar cellulose product
The present invention relates to nanofibrillar cellulose. Furthermore, the invention relates to a method for the manufacture of nanofibrillar cellulose, and to a nanofibrillar cellulose obtainable by said method. The invention also relates to uses of the nanofibrillar cellulose.