Patent classifications
D21C9/007
NANOCELLULOSE-REINFORCED CORRUGATED MEDIUM
The present invention provides a pulp product (e.g., paper) comprising cellulose and nanocellulose, wherein the nanocellulose is derived from the cellulose in a mechanical and/or chemical step that is separate from the main pulping process. The pulping process may be thermomechanical pulping or hydrothermal-mechanical pulping, for example. The pulp product is stronger and smoother with the presence of the nanocellulose. The nanocellulose further can function as a retention aid, for a step of forming the pulp product (e.g., in a paper machine). Other embodiments provide a corrugated medium pulp composition comprising cellulose pulp and nanocellulose, wherein the nanocellulose includes cellulose nanofibrils and/or cellulose nanocrystals and the nanocellulose may be hydrophobic. The nanocellulose improves the strength properties of the corrugated medium. In some embodiments, the cellulose pulp is a GreenBox+® pulp and the nanocellulose is derived from the AVAP® process.
POLYOLEFIN RESIN COMPOSITION
A polyolefin resin composition containing: 100 parts by weight of a resin mixture of (A) 1-60% by weight of cellulose nanofibers having an average thickness of 10-200 nm and (B) 99-40% by weight of a polyolefin resin, and (C) 0.2-30 parts by weight of a terpene phenolic compound; the cellulose nanofibers having been obtained by circulating a pulp slurry in a polysaccharide slurry supply path 3 via chamber (2), and on the other hand, circulating an originally polysaccharide-free slurry in a second fluid medium supply path (4).
METHOD OF PRODUCING NANOCELLULOSE
A method of producing nanocellulose includes defibrillating cellulosic raw material by oxidation with an oxidant such as NaClO or H202 and sonication in the presence of a swelling agent. The nanocellusose produced by the method can be used in a method of recycling cellulosic material such as paper, card, cardboard or wood to produce recycled paper.
RE-DISPERSED MICROFIBRILLATED CELLULOSE
Methods of improving the re-dispersibility of dried or at least partially dried microfibrillated cellulose, methods of re-dispersing dried or at least partially dried microfibrillated cellulose, compositions comprising re-dispersed microfibrillated cellulose and the use of re-dispersed microfibrillated cellulose in an article, product or composition; and methods of improving the physical and/or mechanical properties of re-dispersed dried or partially dried microfibrillated cellulose.
Method for producing nanofibrillar cellulose
In a method for preparing nanofibrillar cellulose, fibrous dispersion of ionically charged cellulose is repeatedly passed through a mechanical process of disrupting fibers into fibrils until the viscosity starts to decrease. The number average diameter of the nanofibrillar cellulose after the mechanical process is in the range of 2-10 nm, and the zero-shear viscosity is below 10 Pa.Math.s, preferably below 1 Pa.Math.s, when measured in the concentration of 0.5 wt-%. The nanofibrillated cellulose is low aspect ratio nanofibrillated cellulose (NFC-L).
Process for refining fiber and deriving chemical co-products from biomass
The invention herein disclosed and claimed is a process for refining fiber from lignocellulosic biomass. The process provides refined fiber and agriculturally amenable co-products, with a virtually waste-free systems design.
Liquefaction of biomass at low pH
The present invention relates to regulation of the p H of a liquefaction process. Presented is a method for treatment of a biomass feedstock wherein the biomass feedstock is subjected to liquefaction, at a p H of at most 4, by treatment with hot compressed liquid water (HCW) at subcritical and/or supercritical conditions to improve the conversion efficiency. The present invention is also directed to quenching of a liquefaction process according to above, preventing, minimizing or eliminating clogging and/or fouling of sticky biomass components in process equipment during processing as according to above, and to the use of additives in a biomass liquefaction process.
EFFICIENT METHODS AND COMPOSITIONS FOR RECOVERY OF PRODUCTS FROM ORGANIC ACID PRETREATMENT OF PLANT MATERIALS
The invention is directed to compositions and processes concerning efficient downstream processing of products derived from organic acids pretreatment of plant materials.
Microfibrillated cellulose with enhanced properties and methods of making the same
Methods of re-dispersing and de-agglomerating dewatered, partially dried and dried compositions of microfibrillated cellulose and compositions of microfibrillated cellulose and inorganic particulate material, into liquid compositions comprising same, by applying ultrasonic energy to such liquid compositions of dewatered, partially dried and dried compositions of microfibrillated cellulose, or compositions of microfibrillated cellulose and inorganic particulate material. Methods for preparing an aqueous suspension comprising microfibrillated cellulose and, optionally, inorganic particulate material, with enhanced viscosity and tensile strength properties, suitable for use in methods of making paper or coating paper, and to filled and coated papers made from such aqueous suspensions.
SULFITE-BASED PROCESSES FOR PRODUCING NANOCELLULOSE, AND COMPOSITIONS AND PRODUCTS PRODUCED THEREFROM
Processes disclosed are capable of converting biomass into high-crystallinity nanocellulose with low mechanical energy input. In some variations, the process includes fractionating biomass with sulfur dioxide or a sulfite compound and water, to generate cellulose-rich solids and a liquid containing hemicellulose and lignin; and mechanically treating the cellulose-rich solids to form nanofibrils and/or nanocrystals. The total mechanical energy may be less than 500 kilowatt-hours per ton. The crystallinity of the nanocellulose material may be 80% or higher, translating into good reinforcing properties for composites. The nanocellulose material may include nanofibrillated cellulose, nanocrystalline cellulose, or both. In some embodiments, the nanocellulose material is hydrophobic via deposition of some lignin onto the cellulose surface. Optionally, sugars derived from amorphous cellulose and hemicellulose may be separately fermented, such as to monomers for various polymers. These polymers may be combined with the nanocellulose to form completely renewable composites.