To provide an organic-inorganic composite filler containing; a polymerizable monomer (a) having at least one functional group selected from the group consisting of —OH group, —NH— group, and —NH.sub.2 group, a polymerizable monomer (b) having no functional group selected from the group consisting of —OH group, —NH— group, and —NH.sub.2 group, a polymerization initiator (c), an inorganic filler (d), and a silane compound (e) which generates —OH group by hydrolysis.

Addition-fragmentation oligomers of the general formula Z—B.sub.y-A-(B-A).sub.x-B-A-B.sub.y—Z, where the A monomers units are derived from a diester or diacid, the B monomer units are derived from a difunctional monomer having functional groups co-reactive with the acid or ester groups of the A monomer, x+y is zero to 60, Z comprises an ethylenically unsaturated, polymerizable group, A monomers comprise a 1-methylene-3,3-dimethylpropyl group, and at least one B monomer unit comprises a high refractive index group.

Radically polymerizable dental material which contains (a) at least one polyfunctional radically polymerizable monomer, (b) at least one further radically polymerizable monomer which can be monofunctional or polyfunctional, (c) at least one photoinitiator for the radical polymerization and (d) at least one filler. The material is characterized in that the mixture of the monomers (a) and (b) has a refractive index of from 1.50 to 1.70 and in that the refractive index of the monomer mixture before the curing corresponds to the refractive index of the filler used or is higher by up to 0.013 and after the curing is higher than the refractive index of the filler by at least 0.02.

Provided is a composite material which comprises a resin matrix and inorganic particles dispersed therein, wherein the inorganic particles comprise: one or more groups (G-PID) of spherical particles uniform in particle diameter which comprise aggregates of inorganic spherical particles having a specific average primary-particle diameter, have a narrow particle-size-distribution width, and have a lower refractive index than the resin matrix; and a group (G-SFP) of ultrafine particles. The inorganic spherical particles which constitute all the groups of spherical particles uniform in particle diameter contained in the resin matrix have an arrangement structure which is a short-range order structure satisfying a specific requirement. Also provided are a curable composition giving the composite material and a method for producing the curable composition.

Provided is a composite material which comprises a resin matrix and inorganic particles dispersed therein, wherein the inorganic particles comprise: one or more groups (G-PID) of spherical particles uniform in particle diameter which comprise aggregates of inorganic spherical particles having a specific average primary-particle diameter, have a narrow particle-size-distribution width, and have a lower refractive index than the resin matrix; and a group (G-SFP) of ultrafine particles. The inorganic spherical particles which constitute all the groups of spherical particles uniform in particle diameter contained in the resin matrix have an arrangement structure which is a short-range order structure satisfying a specific requirement. Also provided are a curable composition giving the composite material and a method for producing the curable composition.

Dental compositions and methods of formulating a dental composition are described. In one embodiment, the dental composition comprises a polymerizable resin comprising one or more ethylenically unsaturated monomers or oligomers and nano-particles. The nanoparticles have a refractive index of at least 1.600 and an average discrete or aggregate particle size of no greater than 100 nm. The dental composition further comprises inorganic metal oxide filler having a discrete or aggregate average particle size of at least 200 nm. The nanoparticles are present at a concentration to provide a refractive index differential between the cured polymerizable resin and inorganic metal oxide filler such that the contrast ratio of the dental composition is at least 40.

Dental compositions and methods of formulating a dental composition are described. In one embodiment, the dental composition comprises a polymerizable resin comprising one or more ethylenically unsaturated monomers or oligomers and nano-particles. The nanoparticles have a refractive index of at least 1.600 and an average discrete or aggregate particle size of no greater than 100 nm. The dental composition further comprises inorganic metal oxide filler having a discrete or aggregate average particle size of at least 200 nm. The nanoparticles are present at a concentration to provide a refractive index differential between the cured polymerizable resin and inorganic metal oxide filler such that the contrast ratio of the dental composition is at least 40.

Pre-sintered blanks based on lithium metasilicate glass ceramic are described which are suitable in particular for the preparation of dental restorations.

To provide a liquid for improving translucency for dental zirconia calcined body which may impart high translucency which is similar to an enamel of a natural tooth to a zirconia sintered body and a method for using thereof.

The liquid for improving translucency for dental zirconia calcined body of the present disclosure contains a solvent and an indium compound, wherein a content of the indium compound based on the total amount of the liquid improving translucency for dental zirconia calcined body is within a range of 2.0 wt. % to 20.0 wt. % in terms of indium.

[Problem]

A technique for imparting high translucency which is similar to an enamel of a natural tooth to a zirconia sintered body, has been required.

[Solution]

To provide a zirconia mill blank for dental cutting and machining, containing, an yttrium compound and an indium compound as stabilizers, wherein, an amount of the yttrium compound is within a range of 3.0 mol % to 6.0 mol % in terms of oxide, an amount of the indium compound is within a range of 0.2 mol % to 3.0 mol % in terms of oxide, and a total amount of the yttrium compound and the indium compound is within a range of 5.5 mol % to 7.0 mol % in terms of oxide.