[Problem]

To provide a dental curable composition having good mechanical property and good storage stability before and after curing.

Solution

The dental curable composition of the present disclosure comprises (A) polymerizable monomer, (BC) polymerization initiator, (D) polymerization accelerator and (E) filler, wherein, the (BC) polymerization initiator comprises (B) photopolymerization initiator and/or (C) chemical polymerization initiator, the (B) photopolymerization initiator comprises (B1) photosensitizer and (B2) photoacid generator, the (C) chemical polymerization initiator comprises (C1) organic peroxide, the (E) filler comprises (E1) surface-treated basic filler, and the (E1) surface-treated basic filler is treated with (F1) surface treatment agent represented by the formula (1) and/or condensate thereof.

[Formula (1)]

MX.sub.n  [Chemical formula 1]

(In the formula, M is a metal atom selected from Si, Ti, Zr, and Al, X is H, OH or a hydrolyzable group, and may be the same or different from each other. In the case that M is Si, Ti or Zr, n is 4. In the case that M is Al, n is 3.)

Disclosed are a dental material with transmittance and color gradients and a method of preparing the dental material. The method includes (1) preparing at least three types of composite resin material precursor powders; (2) sequentially adding the precursor powders into a mold and performing dry pressing to obtain a preform body; alternatively, (2′) dry pressing the first type of precursor powder into a first green body, wrapping the first green body with the second type of precursor powder and then performing dry pressing to obtain a second green body, and repeating the wrapping and dry pressing operations until all types of precursor powder are dry pressed to obtain a preform body; and (3) performing hot-pressing consolidation on the preform body to obtain the desired dental material.

Dental material, which contains at least one radically polymerizable monomer, at least one radiopaque filler, at least one composite filler, at least one inorganic filler and at least one initiator for the radical polymerization. The dental material is particularly suitable as dental filling material.

Dental material, which contains at least one radically polymerizable monomer, at least one radiopaque filler, at least one composite filler, at least one inorganic filler and at least one initiator for the radical polymerization. The dental material is particularly suitable as dental filling material.

A dental curable composition includes a polymerizable monomer (A), a filler (B), and a polymerization initiator (C). The polymerizable monomer (A) contains a polyfunctional (meth)acrylic monomer (A-1) having no aromatic ring but having a moiety (X) constituted by an alkoxylene repeating unit having 1 to 15 carbon atoms, and a polyfunctional (meth)acrylic monomer (A-2) having an aromatic ring but no hydroxyl group. The moiety (X) has a C/O of 2.5 to 10 as a ratio of a total number of carbon atoms to a total number of oxygen atoms in the moiety (X). The moiety (X) has a backbone with a total of 25 to 60 constituent carbon atoms and oxygen atoms altogether. A content of the polyfunctional (meth)acrylic monomer (A-1) is 3 to 60 parts by mass in 100 parts by mass of the polymerizable monomer (A).

A dental curable composition includes a polymerizable monomer (A), a filler (B), and a polymerization initiator (C). The polymerizable monomer (A) contains a polyfunctional (meth)acrylic monomer (A-1) having no aromatic ring but having a moiety (X) constituted by an alkoxylene repeating unit having 1 to 15 carbon atoms, and a polyfunctional (meth)acrylic monomer (A-2) having an aromatic ring but no hydroxyl group. The moiety (X) has a C/O of 2.5 to 10 as a ratio of a total number of carbon atoms to a total number of oxygen atoms in the moiety (X). The moiety (X) has a backbone with a total of 25 to 60 constituent carbon atoms and oxygen atoms altogether. A content of the polyfunctional (meth)acrylic monomer (A-1) is 3 to 60 parts by mass in 100 parts by mass of the polymerizable monomer (A).

The present invention relates to a dental composition comprising a photoinitiator system comprising a particulate carrier supporting a coinitiator covalently bonded to the surface of the carrier. Furthermore, the present invention relates to a use of the particulate carrier in a dental composition.

The particulate carrier displays multiple covalently bonded tertiary amino groups and/or tertiary phosphine groups on the surface, for crosslinking monomers, oligomers and/or polymers having one or more polymerizable double bonds.

The present invention relates to a dental composition comprising a photoinitiator system comprising a particulate carrier supporting a coinitiator covalently bonded to the surface of the carrier. Furthermore, the present invention relates to a use of the particulate carrier in a dental composition.

The particulate carrier displays multiple covalently bonded tertiary amino groups and/or tertiary phosphine groups on the surface, for crosslinking monomers, oligomers and/or polymers having one or more polymerizable double bonds.

The present invention provides a resin composition for stereolithography that is easily shapable with good shape precision while reducing sedimentation of inorganic particles during storage, and a obtained three-dimensional shaped article thereby excels in mechanical characteristics such as flexural strength and flexural modulus, in addition to having a desirable shade and good shade stability. The present invention relates to a resin composition for stereolithography comprising a polymerizable monomer (a), a photopolymerization initiator (b), an inorganic particle (c) having an average particle diameter of 5 to 500 nm, and a hindered phenolic compound (d), wherein the content of the photopolymerization initiator (b) is 0.1 to 10 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), the content of the inorganic particle (c) is 50 to 400 parts by mass relative to 100 parts by mass of the polymerizable monomer (a), and the content of the hindered phenolic compound (d) is 0.1 to 500 parts by mass relative to 100 parts by mass of the photopolymerization initiator (b).

Provided is a dental bulk block made from a glass-ceramic material having a crystalline phase embedded in an amorphous glass matrix. The crystalline phase includes eucryptite and at least one lithium silicate-based crystalline phase selected from the group consisting of lithium metasilicate and lithium disilicate. The dental bulk block is a functionally graded material having a crystalline size gradient with respect to a depth thereof and having no interface at a point of change in main crystalline size gradient value. The bulk block that is heat-treated at 820° C. for 40 minutes exhibits a characteristic peak of a spodumene crystalline phase in an X-ray diffraction analysis result graph unlike the bulk block that is heat-treated at 820° C. for 2 minutes.