[Problem] To provide a dental photocurable composition having sufficient mechanical property and being excellent in color tone selectivity because of having a small color difference between before curing and after curing. [Solution] To provide a dental photocurable composition, comprising (A) polymerizable monomer, (B) photosensitizer, (C) photoacid generator, (D) photopolymerization accelerator and (E) filler, wherein, the dental photocurable composition comprises (B-1) α-diketone compound as the (B) photosensitizer, and the dental photocurable composition comprises, with respect to 100 parts by mass of the (A) polymerizable monomer, 0.15 parts by mass or less of the (B-1) α-diketone compound, 0.5 parts by mass or more of the (C) photoacid generator, and 100 parts by mass or more of the (E) filler.

The invention relates to a material for use as construction material for energy-pulse-induced transfer printing, which contains (a) at least one polymerizable binder, (b) at least one volume expansion component, (c) at least one initiator for the polymerization and (d) preferably at least one energy transformation component. The invention furthermore relates to a process for producing three-dimensional objects using the material.

The invention relates to a material for use as construction material for energy-pulse-induced transfer printing, which contains (a) at least one polymerizable binder, (b) at least one volume expansion component, (c) at least one initiator for the polymerization and (d) preferably at least one energy transformation component. The invention furthermore relates to a process for producing three-dimensional objects using the material.

[Problem]

To provide a dental curable composition having good mechanical property and good storage stability before and after curing.

Solution

The dental curable composition of the present disclosure comprises (A) polymerizable monomer, (BC) polymerization initiator, (D) polymerization accelerator and (E) filler, wherein, the (BC) polymerization initiator comprises (B) photopolymerization initiator and/or (C) chemical polymerization initiator, the (B) photopolymerization initiator comprises (B1) photosensitizer and (B2) photoacid generator, the (C) chemical polymerization initiator comprises (C1) organic peroxide, the (E) filler comprises (E1) surface-treated basic filler, and the (E1) surface-treated basic filler is treated with (F1) surface treatment agent represented by the formula (1) and/or condensate thereof.

[Formula (1)]

MX.sub.n  [Chemical formula 1]

(In the formula, M is a metal atom selected from Si, Ti, Zr, and Al, X is H, OH or a hydrolyzable group, and may be the same or different from each other. In the case that M is Si, Ti or Zr, n is 4. In the case that M is Al, n is 3.)

[Problem]

To provide a dental curable composition having good mechanical property and good storage stability before and after curing.

Solution

The dental curable composition of the present disclosure comprises (A) polymerizable monomer, (BC) polymerization initiator, (D) polymerization accelerator and (E) filler, wherein, the (BC) polymerization initiator comprises (B) photopolymerization initiator and/or (C) chemical polymerization initiator, the (B) photopolymerization initiator comprises (B1) photosensitizer and (B2) photoacid generator, the (C) chemical polymerization initiator comprises (C1) organic peroxide, the (E) filler comprises (E1) surface-treated basic filler, and the (E1) surface-treated basic filler is treated with (F1) surface treatment agent represented by the formula (1) and/or condensate thereof.

[Formula (1)]

MX.sub.n  [Chemical formula 1]

(In the formula, M is a metal atom selected from Si, Ti, Zr, and Al, X is H, OH or a hydrolyzable group, and may be the same or different from each other. In the case that M is Si, Ti or Zr, n is 4. In the case that M is Al, n is 3.)

Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Radically polymerizable dental material, which contains at least one ABA or AB block copolymer, preferably at least one monofunctional, radically polymerizable monomer (a) and preferably at least one radically polymerizable urethane di(meth)acrylate telechel (b).

Dental material, which contains at least one radically polymerizable monomer, at least one radiopaque filler, at least one composite filler, at least one inorganic filler and at least one initiator for the radical polymerization. The dental material is particularly suitable as dental filling material.

Dental material, which contains at least one radically polymerizable monomer, at least one radiopaque filler, at least one composite filler, at least one inorganic filler and at least one initiator for the radical polymerization. The dental material is particularly suitable as dental filling material.

A dental tissue regenerative composition. The composition includes a combination of (1) human dental pulp stem cells and (2) at least one of human umbilical vein endothelial cells or vascular endothelial growth factor. The combination is encapsulated in a light-activated gelatin methacrylate hydrogel.