The present invention provides a dental adhesive material kit that exhibits high adhesive property to tooth structure and dental prosthesis through photopolymerization while maintaining good ease of handling with the paste properties that undergo little change during long storage. The present invention relates to a dental adhesive material kit comprising: an aqueous adhesive dental composition (X) comprising a radical polymerizable monomer (a) containing an acidic group, a polymerization accelerator (b), water (c), and a radical polymerizable monomer (d) containing no acidic group; and a curable dental composition (Y) comprising a hydrophilic radical polymerizable monomer (d-1) containing no acidic group, a hydrophobic radical polymerizable monomer (d-2) containing no acidic group, a chemical polymerization initiator (e), a photopolymerization initiator (f), and a filler (g), the filler (g) being a filler treated with a surface treatment agent, and having an average particle diameter of 0.01 to 50.0 μm, the surface treatment agent comprising a silane coupling agent (A) represented by general formula [1], and an organosilazane (B) represented by general formula [2].

The present invention provides a dental adhesive material kit that exhibits high adhesive property to tooth structure and dental prosthesis through photopolymerization while maintaining good ease of handling with the paste properties that undergo little change during long storage. The present invention relates to a dental adhesive material kit comprising: an aqueous adhesive dental composition (X) comprising a radical polymerizable monomer (a) containing an acidic group, a polymerization accelerator (b), water (c), and a radical polymerizable monomer (d) containing no acidic group; and a curable dental composition (Y) comprising a hydrophilic radical polymerizable monomer (d-1) containing no acidic group, a hydrophobic radical polymerizable monomer (d-2) containing no acidic group, a chemical polymerization initiator (e), a photopolymerization initiator (f), and a filler (g), the filler (g) being a filler treated with a surface treatment agent, and having an average particle diameter of 0.01 to 50.0 μm, the surface treatment agent comprising a silane coupling agent (A) represented by general formula [1], and an organosilazane (B) represented by general formula [2].

A photocurable composition includes a photopolymerizable component and a photopolymerization initiator, in which a diluted solution (D1) obtained by diluting the photocurable composition with ethanol such that the content of ethanol is 99% by mass would satisfy the following Condition (X): the transmittance at at least one wavelength within the wavelength range of from 365 nm to 405 nm, measured at an optical path length of 1 cm, is from 1.0% to 70.0%.

A photocurable composition includes a photopolymerizable component and a photopolymerization initiator, in which a diluted solution (D1) obtained by diluting the photocurable composition with ethanol such that the content of ethanol is 99% by mass would satisfy the following Condition (X): the transmittance at at least one wavelength within the wavelength range of from 365 nm to 405 nm, measured at an optical path length of 1 cm, is from 1.0% to 70.0%.

The present invention provides a resin composition for stereolithography that excels in strength, toughness, and water resistance in the form of a shaped article. The present invention relates to a resin composition for stereolithography that comprises a urethanized (meth)acrylic compound (A), a (meth)acrylate compound (B) containing no urethane bond, and a photopolymerization initiator (C), the compound (A) being a urethanized (meth)acrylic compound (A-1) having a polymer structure, and/or a urethanized (meth)acrylic compound (A-2) having no polymer structure, the compound (A-1) having a weight-average molecular weight of less than 1,000, the compound (A-2) having a molecular weight of less than 1,000, the compound (B) comprising at least one selected from the group consisting of a (meth)acrylate compound (b-I) represented by general formula (I), and a (meth)acrylate compound (b-II) represented by general formula (II).

##STR00001##

The present disclosure is directed to a polymeric layer comprising a catechol containing a monomer, polymer, or oligomer, wherein said catechol presents as a catechol and/or as a semi-quinone and/or as a quinone without the presence of a primary amine or a secondary amine; and wherein the polymeric layer optionally comprises a reactive material that is not reactive with catechol or quinone. The present disclosure is also directed to a polymeric layer comprising a catechol containing monomer, polymer, or oligomer disposed adjacent to and in contact with a bulk adhesive layer. The present disclosure is also directed to methods of coating a substrate using the layers described herein.

The present disclosure is directed to a polymeric layer comprising a catechol containing a monomer, polymer, or oligomer, wherein said catechol presents as a catechol and/or as a semi-quinone and/or as a quinone without the presence of a primary amine or a secondary amine; and wherein the polymeric layer optionally comprises a reactive material that is not reactive with catechol or quinone. The present disclosure is also directed to a polymeric layer comprising a catechol containing monomer, polymer, or oligomer disposed adjacent to and in contact with a bulk adhesive layer. The present disclosure is also directed to methods of coating a substrate using the layers described herein.

One aspect of the invention is a dental composition of a single-component dental composition including a (meth)acrylate, a photopolymerization initiator, a thiourea derivative, a water miscible organic solvent, and water, wherein the photopolymerization initiator contains a diaryliodonium salt.

One aspect of the invention is a dental composition of a single-component dental composition including a (meth)acrylate, a photopolymerization initiator, a thiourea derivative, a water miscible organic solvent, and water, wherein the photopolymerization initiator contains a diaryliodonium salt.

A photocurable composition includes a (meth)acrylic monomer component and a photopolymerization initiator, wherein an adhesive force of a cured product is less than or equal to 1.5 N, and a rupture elongation of the cured product is greater than or equal to 20%.