[Problem]

To provide a dental adhesive composition having excellent storage stability and adhesive strength.

[Solution]

To provide a dental adhesive composition, comprising (A) polymerizable monomer, (D) photopolymerization accelerator, and (F) volatile organic solvent, wherein, the dental adhesive composition comprises (A-1) polymerizable monomer having an acidic group as the (A) polymerizable monomer, and the dental adhesive composition comprises (D-1) aliphatic tertiary amine compound represented by formula (1) as the (D) photopolymerization accelerator.

##STR00001##

(wherein R.sub.1 represents a substituent consisting of three or more carbons having an electron-withdrawing group at α-carbon and/or β-carbon of an amine starting from N, R.sub.2 represents a substituent consisting of three or more carbons which may have an electron-withdrawing group, R.sub.3 represents a substituent consisting of one or more carbons which may have an electron-withdrawing group, and α-carbon of N in the formula (1) is not an electron-withdrawing group.)

[Problem]

To provide a photocurable composition having a high curing depth.

[Solution]

To provide a photocurable composition of the present disclosure comprises (A) polymerizable monomer, (B) photosensitizer, (C) photoacid generator, and (D) photopolymerization accelerator, wherein, the photocurable composition comprises (D-1) amine compound represented by formula (1) as the (D) photopolymerization accelerator.

##STR00001##

(In the formula (1), R.sub.1 is a substituent represented by formula (2), and R.sub.2 and R.sub.3 are substituents represented by formula (2) or substituents selected from —OH group, —O— group, —S— group, —NH—C(O)—NH— group, —C(O)—O— group, —OC(O)— group, —OC(O)—NH— group, —NH—C(O)—O— group, halogen, an organic group which may have an alkoxysilyl group, an aromatic ring which may have a substituent and an alicyclic heterocycle which may have a substituent. Further, R.sub.2 and R.sub.3 may be H when at least one or more R.sub.4s of the formula (2) are an aromatic ring, and R.sub.3 may be H when R.sub.2 is a substituent represented by the formula (2).)

To provide a dental photocurable composition which can exhibit excellent mechanical characteristics even after returning from a low temperature to room temperature.

To provide a dental photocurable composition, comprising (A) polymerizable monomer, (B) photosensitizer, (C) photoacid generator and (D) photopolymerization accelerator and the (C) photoacid generator may include only (C-1) iodonium salt-based compound of an anion having log S of −4 or less.

[Problem]

To provide a dental photocurable composition having sufficient mechanical property and being excellent in color tone selectivity because of having a small color difference between before curing and after curing.

[Solution]

To provide a dental photocurable composition, comprising (A) polymerizable monomer, (B) photosensitizer, (C) photoacid generator, (D) photopolymerization accelerator and (E) filler, wherein, the dental photocurable composition comprises (B-1) α-diketone compound as the (B) photosensitizer, and the dental photocurable composition comprises, with respect to 100 parts by mass of the (A) polymerizable monomer, 0.15 parts by mass or less of the (B-1) α-diketone compound, 0.5 parts by mass or more of the (C) photoacid generator, and 100 parts by mass or more of the (E) filler.

[Problem]

To provide a dental photocurable composition having sufficient mechanical property and being excellent in color tone selectivity because of having a small color difference between before curing and after curing.

[Solution]

To provide a dental photocurable composition, comprising (A) polymerizable monomer, (B) photosensitizer, (C) photoacid generator, (D) photopolymerization accelerator and (E) filler, wherein, the dental photocurable composition comprises (B-1) α-diketone compound as the (B) photosensitizer, and the dental photocurable composition comprises, with respect to 100 parts by mass of the (A) polymerizable monomer, 0.15 parts by mass or less of the (B-1) α-diketone compound, 0.5 parts by mass or more of the (C) photoacid generator, and 100 parts by mass or more of the (E) filler.

Monochromatic dental shaped body, which has an opacity of from 70 to 78%, and a process for its production.

Monochromatic dental shaped body, which has an opacity of from 70 to 78%, and a process for its production.

A dental mill blank can be fabricated, through a milling process, into a highly aesthetic dental prosthesis having an opalescent quality characteristic of natural teeth and also having a sufficient chroma level. Such a dental mill blank may include: 40 mass % or more of an inorganic filler, the dental mill blank satisfying conditions (1) and (2): (1) a specimen with a thickness of 1.20±0.01 mm has a chromaticity satisfying −0.5≤a*.sub.black≤2.5 and 12.0≤b*.sub.black≤25.0 in the L*a*b* color system when measured against a black background; and (2) the specimen with a thickness of 1.20±0.01 mm has an opalescence value of 17.5 or more.

A method for producing an implant blank (100), in particular a dental implant blank from a starting body, said implant blank (100) comprising at least one first area, which is a surface area (102), and a second area, which is a core area (101), wherein the surface area (102) has at least one bioactive surface material (502) and extends from at least one first surface (103) in the direction of the core area (101), and the core area (101) has at least one carrier material that can be subjected to mechanical load. The starting body has a porosity for controlling a targeted distribution of the bioactive surface material (502) within the starting body and is loaded with a solution (500) of the bioactive surface material (502) in a first step, which is a loading step. In a second step, which is a distribution control step, the distribution of the bioactive surface material (502) within the starting body is controlled such that the solution (500) has a higher concentration within the surface area (102) than within the core area (101), the control being effected by regulating one or more environmental parameters in a closed environment (200), in particular by regulating the humidity and/or the pressure and/or the temperature.

A method for producing an implant blank (100), in particular a dental implant blank from a starting body, said implant blank (100) comprising at least one first area, which is a surface area (102), and a second area, which is a core area (101), wherein the surface area (102) has at least one bioactive surface material (502) and extends from at least one first surface (103) in the direction of the core area (101), and the core area (101) has at least one carrier material that can be subjected to mechanical load. The starting body has a porosity for controlling a targeted distribution of the bioactive surface material (502) within the starting body and is loaded with a solution (500) of the bioactive surface material (502) in a first step, which is a loading step. In a second step, which is a distribution control step, the distribution of the bioactive surface material (502) within the starting body is controlled such that the solution (500) has a higher concentration within the surface area (102) than within the core area (101), the control being effected by regulating one or more environmental parameters in a closed environment (200), in particular by regulating the humidity and/or the pressure and/or the temperature.