A method for producing a support for polyurethane-based imitation leather free of dimethylformamide or other solvents or water involves preparing a base. A two-component polyurethane layer is sprayed on the base which includes preparing a first component and a second component. The first and second components are combined to obtain a mixture, and the mixture is sprayed uniformly on the base forming the polyurethane layer. A backing is applied on the two-component polyurethane layer forming a support and the support is dried.

The present invention provides a synthetic leather including at least a base (i), an adhesive layer (ii), and a skin layer (iii). The adhesive layer (ii) and the skin layer (iii) are both formed of a urethane resin composition including a urethane resin and water, the urethane resin being produced using an aromatic polyisocyanate as a raw material. The urethane resin composition forming the adhesive layer (ii) preferably includes a urethane resin (A) and water (B), the urethane resin (A) being produced using an aromatic polyisocyanate (a1) as a raw material. The aromatic polyisocyanate (a1) preferably includes toluene diisocyanate. It is preferable that the urethane resin (A) include an anionic group and the concentration of the anionic group in the urethane resin (A) be 0.35 mmol/g or less.

A curable composition including: a component (a): a polycarbonate polyol having a hydroxyl value of 40 to 75 mgKOH/g; a component (b): a polycarbonate polyol having a hydroxyl value of 100 to 280 mgKOH/g; and a component (c): a polyisocyanate having an average number of functional groups per molecule, of 2 to 6.

An interior material of a vehicle includes: a fabric layer made of a tricoat fabric, a foam layer disposed on a lower surface of the fabric layer, and an antifouling layer disposed at least between an upper surface of the fabric layer or the fabric layer and the foam layer. The tricoat fabric includes a combination of at least one of a polyurethane yarn, a high-elongation polyester yarn, or a polyester yarn.

Disclosed is a grain-finished leather-like sheet including: a fiber base material; a polyurethane intermediate layer stacked on the fiber base material; and a polyurethane skin film stacked directly on the polyurethane intermediate layer or via another polyurethane layer, wherein the polyurethane skin film contains a silicone-modified polyurethane, and the grain-finished leather-like sheet has an uneven surface whose skewness (Ssk), kurtosis (Sku), and maximum height (Sz) of surface roughness in accordance with ISO 25178 respectively satisfy −0.4≤Ssk≤−0.2, 3≤Sku≤4, 60 μm≤Sz≤150 μm.

A skin material includes a loop pile fabric including fibers including polyester fibers, and an adhesive layer and a skin layer, which are disposed, in this order, on a surface of the loop pile fabric at a side at which pile yarns are provided, in which at least top parts of the pile yarns are located in the adhesive layer, and a gap is formed between a ground structure of the loop pile fabric and the adhesive layer.

A process for coating a fabric web on upper and lower sides in one pass containing unwinding a fabric web, coating the upper side of the fabric web with a upper coating composition using a first coater, coating the lower side of the fabric web with a lower coating composition using a second coater, drying the coated fabric web in a horizontal dryer, and winding up the coated fabric web.

The upper and lower coatings are each in an add-on amount of between about 10 and 75 GSM. The second coater comprises an entry edge and a beveled exit edge, where the entry edge is located closer to the first coater than the beveled exit edge, the entry edge of the second coater is in contact with the lower side of the fabric web, and the beveled exit edge of the second coater is not in contact with the web.

A composite skin material for a vehicle wherein a synthetic leather includes a surface resin layer having a plurality of openings, an adhesion layer present on the rear surface of the surface resin layer, and a fibrous base material present on the rear surface of the surface resin layer across the adhesion layer, and the adhesion layer is present only at the adherend part, except for the plurality of openings, in the rear surface of the surface resin layer, and the base material surface of the fibrous base material is bonded to the surface resin layer.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight.

Disclosed are a soft solvent-free flame-retardant polyurethane synthetic leather and a preparation method therefor. The soft solvent-free flame-retardant polyurethane synthetic leather comprises an antifouling layer, a surface layer, an intermediate layer, a bonding layer and a base cloth in sequence from top to bottom, wherein the bonding layer is prepared from component A and an isocyanate; the molar ratio of —NCO in the isocyanate to —OH in the component A is 0.85-0.93; and the component A is composed of a polyhydric alcohol, an inhibition-type catalyst, a flame retardant, a filler and a viscosity modifier in parts by weight. The polyurethane synthetic leather prepared by the present invention has daily life antifouling properties, a good durability, is soft to the touch, is strongly skin-friendly, and has a very superior flame-retardant performance, and also has excellent antifouling, scratch resistance and flexure resistance properties; the production process is simple, efficient and environmentally friendly and same can satisfy market demands.

The invention relates to a method for producing a surface-structured layered material which has a backing layer (I) and a polyurethane layer (2) connected thereto, the backing layer (I) used, in particular in pieces, being a leather, preferably a smoothed full-grain leather or a split cowskin, a textile material, preferably a woven fabric or a knitted fabric, a cellulose fibre material, a split foam, a leather fibre material or a microfibre fleece and being connected to the layer (2), and the layer (2) applied to the backing layer (I) being at least one, preferably a single layer formed of a PU foam, in particular containing gas pockets, preferably a whipped PU foam optionally containing hollow microspheres and/or a PU foam containing hollow microspheres. According to the invention: —the PU foam, in particular containing gas pockets, is created with a PU dispersion mixture, wherein the individual PU dispersions used to create the PU dispersion mixture exhibit different softening points in the dry state; —to create the PU dispersion mixture, one or more PU dispersions having heat—preferably melting and contact adhesive properties and a softening point in the dry state greater than 40° C., preferably greater than 45° C., in an amount of 18 to 52 wt ¾ of the finished PU dispersion mixture is/are mixed with one or more PU dispersions without melting and contact adhesive properties and with a softening point greater than 95° C., preferably greater than 125° C., in an amount of 39 to 73 wt ¾ of the finished PU dispersion mixture; —the PU dispersion mixture for the layer (2) is applied to the backing layer (I) with a thickness such that the layer has a thickness in the dried state of 0.075 to 0.450 mm, preferably 0.150 to 0.280 mm; —before or during structuring of the PU foam, a further layer (3) of a non-foamed PU dispersion which is a mixture of multiple PU dispersions is applied to the layer (2); —the backing layer (I) is optionally cut or punched into banks or pattern parts before or after the application of the PU foam, in particular after the drying thereof, and the coated blanks or pattern parts are subjected to stamping or structuring under pressure and temperature; and —the backing layer (1), the further layer (3) and the layer (2) are compressed and joined to one another and structured with a die (4) under application of a contact pressure of 4 to 48 kg/cm2, preferably 4 to 48 kg/cm2, in particular 18 to 25 kg/cm2.