A resin-metal composite member for a tire includes a metal member (27), an adhesion layer (25), and a covering resin layer (28) in this order. The adhesion layer (25) includes a polyester-based thermoplastic elastomer having a polar functional group, and at least one additive selected from the group consisting of an amorphous resin including an ester bond, a polyester-based thermoplastic resin, and a filler, and the content ratio of the polyester-based thermoplastic elastomer having a polar functional group is 50% by mass or more with respect to the entire adhesion layer (25).

Provided are: an elastomer-metal cord composite capable of improving the performance of a tire, in which composite a metal cord composed of a bundle of metal filaments that are parallelly aligned without being twisted together is coated with an elastomer; and a tire including the same. An elastomer-metal cord composite (10) is obtained by coating, with an elastomer (3), a metal cord (2) composed of a bundle of two to ten metal filaments (1) that are parallelly aligned in a single row without being twisted together, and the metal cord (2) includes at least one pair of adjacent metal filaments (1) being different from each other in at least either of patterning amount and patterning pitch in a direction perpendicular to an extending direction of the metal filaments (1).

A compact steel cord is provided. The cord includes a core-filament I steel wire with a diameter of d0, and four middle-layer M steel wires with a diameter of d1 and eight outer-layer O steel wires with a diameter of d2 that are twisted around the core-filament I steel wire in the same lay direction and the same lay length. Gaps L are reserved between the outer-layer O steel wires, an average width of the gaps L is not smaller than 0.02 mm, and the total size of the gaps L is larger than d0 and smaller than d1. The steel cord of a stable structure can be obtained by controlling the proportion of the sizes of all layers of monofilaments, the rubber coating performance of a tire cord can also be improved, the corrosion resistance, fatigue resistance, impact resistance and adhesion retention of a tire are improved.

A steel cord that is suitable for reinforcing rubber articles such as tires. The inventive steel cord enables to completely eliminate the presence of cobalt in a tire when combined with the proper cobalt free compound. Advantageously the steel cord adheres equally well to rubbers containing organic cobalt salts. The inventive wire is different from prior art steel cords in that the brass coating now comprises iron particles. The iron particles have a size between 10 nm and 10 000 nm. The presence of iron mitigates the adhesion retention loss of the rubber to steel cord bond in a hot and humid environment. It is a further advantage that the inventive steel cord does not contain any intentionally added cobalt thereby contributing to the elimination of harmful substances in the production area as well as the environment.

Disclosed are a metal wire, a manufacturing method therefor, and a tire. The metal wire is made by twisting a filament; an outer peripheral surface of the filament is covered with a CuMZn alloy coating; the outer peripheral surface of the filament is also covered with a CuZn alloy coating; the metal wire is made of at least one filament; an area covered by the CuMZn alloy coating is 10%-90% of an area of the outer peripheral surface of the filament, and the rest is the CuZn alloy coating; M in the CuMZn alloy coating is selected from one or two of Co, Ni, Mn, or Mo; the mass fraction of Cu in the CuMZn alloy coating is 58%-72%, the mass fraction of M in the CuMZn alloy coating is 0.5%-5%, and the balance in the CuMZn alloy coating is Zn and inevitable impurities.

A process for depositing, with forward progression, graphene on the surface of a metallic or metallized continuous reinforcer, at the periphery of which is positioned a layer of surface metal chosen from copper, nickel and copper/nickel alloys, comprises at least one stage of flame spray pyrolysis (FSP), under a reducing atmosphere, of a carbon precursor which generates, in the flame, at least one carbon-based gas such as carbon monoxide which is sprayed onto the surface of the reinforcer in forward progression, and is decomposed thereon to form one or more graphene layers at the surface of the surface metal; an additional stage of graphene functionalization makes it possible to adhere the reinforcer to a polymer matrix such as rubber.

This invention reveals a pneumatic tire comprising a generally toroidal-shaped carcass with an outer circumferential tread, two spaced beads, at least one ply extending from bead to bead and sidewalls extending radially from and connecting said tread to said beads, and an innerliner which covers the inner surface and which is comprised of a halobutyl rubber, a filler and lignin. The incorporation of lignin into the innerliner prevents migration of moisture into the tire carcass which can lead to corrosion and consequential delamination of steel cords within the tire. Normally the lignin will be included in such innerliner formulations in an amount which is within the range of 1 phr to 20 phr. Lignin can also be used to protect the steel belts by incorporating it into other tire components located between the innerliner and the belts.

A reinforcement means for molded and extruded articles such as tires has a metal structure with a layer of silica gel bonded thereto. The silica gel bonds the reinforcement means to the rubber compound during the molding/vulcanization of the rubber compound without the need for a slow curing stage. The silica gel may be applied to the metal structure by a sol-gel process with the gel formed by drying the sol at a temperature up to 150 C. The reinforcement means is preferably a cable formed from steel wires coated with the silica gel. To further improve bonding of the silica gel to the rubber compound, an organosilane bonding agent may be included in the rubber compound or the reinforcing means provided with a second layer comprising an organosilane as a bonding agent. The reinforcement means are particularly useful for strengthening and providing geometric stability to tires.

A cable bead comprising an annular core and a side wire spirally wrapped up around the annular core, wherein the annular core is made up of a round steel wire made to circle once or made, without being stranded, to circle 2 to 10 times side by side, and wherein the side wire is a round steel wire consecutive from the annular core. This provides a high-strength cable bead that can press a tire main body against a wheel without fail even if a tire is charged with a high load.

A steel cord that is suitable for reinforcing rubber articles such as tires. The inventive steel cord enables to completely eliminate the presence of cobalt in a tire when combined with the proper cobalt free compound. Advantageously the steel cord adheres equally well to rubbers containing organic cobalt salts. The inventive wire is different from prior art steel cords in that the brass coating now comprises iron particles. The iron particles have a size between 10 nm and 10 000 nm. The presence of iron mitigates the adhesion retention loss of the rubber to steel cord bond in a hot and humid environment. It is a further advantage that the inventive steel cord does not contain any intentionally added cobalt thereby contributing to the elimination of harmful substances in the production area as well as the environment.