The present invention is directed to a method of making a cord-reinforced rubber article, comprising the steps of A) mixing a carrier gas, sulfur and an alkyne, to form a gas mixture; B) generating an atmospheric pressure plasma from the gas mixture; C) exposing a steel reinforcement cord to the atmospheric pressure plasma to produce a treated reinforcement cord; and D) contacting the treated steel reinforcement cord with a rubber composition comprising a diene based elastomer.

Provided are: a tire including: a tire frame; and a reinforcing metal cord member that is wound at least on the outer circumference of the tire frame, wherein at least a portion of the reinforcing metal cord member is coated with a coating composition via an adhesion layer that contains a polyamide-based adhesive and has a melting point of from 160 C. to 200 C., the coating composition containing at least one thermoplastic material selected from polyamide-based thermoplastic resins having a melting point of from 160 C. to 240 C. and polyamide-based thermoplastic elastomers having a melting point of from 160 C. to 240 C.; and a method of producing the same.

The present invention relates to a steel cord for rubber reinforcement. In the steel cord of the present invention, cobalt is contained by 0.001 ppm to 0.1 ppm within a 4 nm top-surface of the brass-plated steel wire. A method of manufacturing the steel cord includes: providing a brass-plated steel wire; mixing a cobalt compound in a wet lubricant filled in a wet drawing bath provided with a plurality of drawing dies between one pair of multi-stage drawing cones such that the concentration of the cobalt compound becomes 0.1 ppm to 100 ppm; and causing the cobalt to be contained by 0.001 ppm to 0.1 ppm within a 4 nm top-surface of the brass-plated steel wire after the brass-plated steel wire passes through a final die by causing the cobalt to be attached to a surface of the brass-plated steel wire and alloyed with a brass layer while the brass-plated steel wire is passing through the drawing cones and the drawing dies to be subjected to multi-stage drawing.

The present disclosure relates to a cable bead for a pneumatic tire which constitutes a bead part of a pneumatic tire, improves rubber permeability by restricting a ratio between a diameter of a cable and a pitch of an outer wire, and improves durability of a pneumatic tire by improving rubber adhesive properties through cobalt coating on a surface of the outer wire, and a pneumatic tire having the same, and the cable bead for a pneumatic tire is characterized in that the diameter D of the cable and a pitch P of the outer wire 20 satisfy a relationship formula, P/D=25 to 45, and further characterized in that the surface of the outer wire 20 is coated with cobalt after wire drawing.

A steel cord with two or more filaments possibly including a wrapping filament, at least one but not all of the two or more filaments including the possible wrapping filament is coated with a ternary or quaternary alloy coating of copper-M-zinc. The steel cord with lower cost and good adhesion performance is for reinforcing rubber product.

A cobalt-free steel cord-rubber composite article includes, in sequence, a steel cord core, a steel cord coating, and a rubber layer. The steel cord coating contains from about 61 wt % to about 66 wt % copper, from about 3.5 wt % to about 6.5 wt % iron, and a balance of zinc and unavoidable impurities. The rubber layer is formed from a rubber compound including 100 phr of at least one elastomer; sulfur; about 20 phr to about 100 phr of at least one filler; about 2 phr to about 15 phr of zinc oxide; and about 0.5 phr to about 3.0 phr of at least one accelerator, containing no cobalt and no resin.

A pneumatic commercial vehicle tire of radial design includes at least a three-ply belt, of which two belt plies are working plies and one radially outermost belt ply is a cover ply. Each of these belt plies includes reinforcements which are made of steel cord and which are embedded in elastomer. The steel cords of each of the three belt plies are coated with brass so as to provide for good elastomer adhesion. The brass coating of the reinforcement supports of the two working plies has a copper proportion of 60 wt. % to 65 wt. % and the brass coating of the reinforcement supports of the cover ply has a copper proportion of 66 wt. % to 70 wt. %.

A ready-for-use metal reinforcer, for example, of the wire or cord type, made of brass-coated carbon steel, is capable of adhering directly by vulcanization to a matrix of unsaturated rubber such as natural rubber. The surface of the reinforcer is provided with nanoparticles of at least one sulfide of a metal chosen from cobalt, copper, iron, zinc and the alloys comprising at least one of these elements. Such a reinforcer can be used as the reinforcing element of a finished article made of rubber, such as a tire.

A cable bead comprising an annular core and a side wire spirally wrapped up around the annular core, wherein the annular core is made up of a round steel wire made to circle once or made, without being stranded, to circle 2 to 10 times side by side, and wherein the side wire is a round steel wire consecutive from the annular core. This provides a high-strength cable bead that can press a tire main body against a wheel without fail even if a tire is charged with a high load.

A threadlike metallic or metallized reinforcer, for example a thread, film, tape or cord made of carbon steel, at the periphery of which is positioned a layer of metal referred to as surface metal chosen from copper, nickel and copper/nickel alloys, is characterized in that this surface metal layer is itself coated, at least in part, with at least one layer of graphene; preferably, there is grafted, to this graphene, at least one functional group which can crosslink to a polymer matrix. This reinforcer of the invention is effectively protected from corrosion by virtue of the graphene present at the surface; advantageously, it can be adhesively bonded directly, without adhesion primer or addition of metal salt, to an unsaturated rubber matrix, such as natural rubber, by virtue of the possible functionalization of this graphene.