Lithium ion batteries, electrodes, nanofibers, and methods for producing same are disclosed herein. Provided herein are batteries having (a) increased energy density; (b) decreased pulverization (structural disruption due to volume expansion during lithiation/de-lithiation processes); and/or (c) increased lifetime. In some embodiments described herein, using high throughput, water-based electrospinning process produces nanofibers of high energy capacity materials (e.g., ceramic) with nanostructures such as discrete crystal domains, mesopores, hollow cores, and the like; and such nanofibers providing reduced pulverization and increased charging rates when they are used in anodic or cathodic materials.

The invention is directed to carbon fibers having high tensile strength. The invention also provides a method and apparatus for making the carbon fibers. The method comprises advancing a precursor fiber through a plurality of passes through an oxidation oven, where stretching during the initial passes is minimized or eliminated entirely, or made negative, followed by controlled stretching over a series of passes, using rollers of increasing speed.

The invention is directed to carbon fibers having high tensile strength. The invention also provides a method and apparatus for making the carbon fibers. The method comprises advancing a precursor fiber through a plurality of passes through an oxidation oven, where stretching during the initial passes is minimized or eliminated entirely, or made negative, followed by controlled stretching over a series of passes, using rollers of increasing speed.

Cord-yarn supercapacitors are disclosed herein. The cord-yarn supercapacitor can include two or more ply yarns twisted together and an electrolyte. The ply yarns can comprise an activated carbon fiber yarn and a non-activated carbon fiber yarn. The activated carbon fiber yarn can be derived from a staple yarn which has been carbonized and activated. The non-activated carbon fiber yarn can be derived from a multi filament yarn. The electrolyte can include a polymer gel. The cord-yarn supercapacitors disclosed herein provide a rope-format linear structure with great flexibility. This unique linear structure allows the supercapacitor to find use in applications such as apparel products, outdoor activity products, sports wears, and other industrial end uses. Methods of making cord-yarn supercapacitors are also disclosed.

Cord-yarn supercapacitors are disclosed herein. The cord-yarn supercapacitor can include two or more ply yarns twisted together and an electrolyte. The ply yarns can comprise an activated carbon fiber yarn and a non-activated carbon fiber yarn. The activated carbon fiber yarn can be derived from a staple yarn which has been carbonized and activated. The non-activated carbon fiber yarn can be derived from a multi filament yarn. The electrolyte can include a polymer gel. The cord-yarn supercapacitors disclosed herein provide a rope-format linear structure with great flexibility. This unique linear structure allows the supercapacitor to find use in applications such as apparel products, outdoor activity products, sports wears, and other industrial end uses. Methods of making cord-yarn supercapacitors are also disclosed.

Poly-(caffeyl alcohol) (PCFA), also known as C-lignin, is a promising new source of both carbon fibers and pure carbon. PCFA can be used to produce carbon fibers by direct electrospinning, without blending with another polymer to reduce breakage. Analyses have shown that the carbon obtained from PCFA is superior to that obtained from other lignins. The fibers formed from PCFA are smoother, have a narrower diameter distribution, and show very low defects. The PCFA can be obtained by extraction from plant seed coats. Examples of these plants include the vanilla orchid, Vanilla planifolia, and Jatropha curcas. The fibers may be formed through electrospinning, although other methods for forming the fibers, such as extrusion with a carrier polymer, could be used. The fibers may then be carbonized to increase the carbon yield.

A preparation method for a large crystal region high crystallinity carbonaceous fiber, where a wet spinning method is mainly used to assemble graphene oxide and other polymer materials in liquid phase, a two-dimensional graphene oxide sheet performs a template orienting effect on polymer molecules, making the directional crystallization of polymer molecules, resulting in fiber with high orientation and crystallinity. Graphene sheet catalyzes pyrolyzed molecules through a graphitization inducing effect to directionally generate graphene-like carbon layers after following high temperature treatment, thereby promoting stacking behavior of graphene sheets, and a composite carbonaceous fiber with an optimal crystallinity is prepared. The graphene fiber material prepared by the present method has characteristics of low cost, high crystallinity and high performance, and can be applied to a field of lightweight structural materials. The present invention is a high crystallinity graphene fiber material with two-dimensional induction effect and a preparation method for the same.

A preparation method for a large crystal region high crystallinity carbonaceous fiber, where a wet spinning method is mainly used to assemble graphene oxide and other polymer materials in liquid phase, a two-dimensional graphene oxide sheet performs a template orienting effect on polymer molecules, making the directional crystallization of polymer molecules, resulting in fiber with high orientation and crystallinity. Graphene sheet catalyzes pyrolyzed molecules through a graphitization inducing effect to directionally generate graphene-like carbon layers after following high temperature treatment, thereby promoting stacking behavior of graphene sheets, and a composite carbonaceous fiber with an optimal crystallinity is prepared. The graphene fiber material prepared by the present method has characteristics of low cost, high crystallinity and high performance, and can be applied to a field of lightweight structural materials. The present invention is a high crystallinity graphene fiber material with two-dimensional induction effect and a preparation method for the same.

Provided herein are nanofibers comprising carbon precursors, nanofibers comprising carbon matrices, and processes for preparing the same. In specific examples, provided herein are high performance lithium ion battery anodic nanofibers comprising non-aggregated silicon domains in a continuous carbon matrix.