The present invention relates to polymer latex composition for fibre binding comprising: a) 50 to 98 wt.-% based on the total weight of latex particles in the composition of first latex particles having a volume average particle size of 80 to 1000 nm, wherein the first latex particles optionally bear functional groups and if functional groups are present they are selected from functional groups consisting of acid functional groups and salts, amides or anhydrides thereof, silane functional groups, and combinations thereof; b) 2 to 50 wt.-% based on the total weight of latex particles in the composition of second latex particles having a volume average particle size of 5 to 70 nm bearing epoxy functional groups, to the use of that composition for fibre binding, to a fibre structure comprising the dried residue of that composition and to a method for increasing the strength of a fibre structure.

The present invention relates to polymer latex composition for fibre binding comprising: a) 50 to 98 wt.-% based on the total weight of latex particles in the composition of first latex particles having a volume average particle size of 80 to 1000 nm, wherein the first latex particles optionally bear functional groups and if functional groups are present they are selected from functional groups consisting of acid functional groups and salts, amides or anhydrides thereof, silane functional groups, and combinations thereof; b) 2 to 50 wt.-% based on the total weight of latex particles in the composition of second latex particles having a volume average particle size of 5 to 70 nm bearing epoxy functional groups, to the use of that composition for fibre binding, to a fibre structure comprising the dried residue of that composition and to a method for increasing the strength of a fibre structure.

An emulsion formulation includes a silicone-(meth)acrylate copolymer and a silicone additive. The emulsion formulation can be coated on textiles and dried to impart both durable water repellency and softness to the textiles.

The present invention relates to a continuous carbon fiber bundle that is easily divided by cutting to a length of 25.4 mm, a sheet molding compound (SMC), and a fiber-reinforced composite material to be molded using the same. The SMC includes carbon fiber bundles including carbon fibers with a single fiber fineness of 1.0 dtex or more and 2.4 dtex or less and a matrix resin composition. In the SMC, a mode value in a mass distribution of carbon fiber bundles with respect to a mass of individual carbon fibers bundle is 50% or less of the mass of the carbon fiber bundle with the largest mass, and additionally, a fiber-reinforced composite material molded using the same is used to address problems.

A polymer composition with (A) a first poly(meth)acrylate polymer or urethane polymer; and (B) a second poly(meth)acrylate polymer or urethane polymer which has a residue X incorporated therein, where X is the residue of a cyclic or acyclic sugar alcohol which is substituted with at least one R.sup.1; C(O)R.sup.1; (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mR.sup.2; (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mC(O)R.sup.1; or mixtures thereof; where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R.sup.1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; and each R.sup.2 is independently H, a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof.

A polymer composition with (A) a first poly(meth)acrylate polymer or urethane polymer; and (B) a second poly(meth)acrylate polymer or urethane polymer which has a residue X incorporated therein, where X is the residue of a cyclic or acyclic sugar alcohol which is substituted with at least one R.sup.1; C(O)R.sup.1; (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mR.sup.2; (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mC(O)R.sup.1; or mixtures thereof; where the cyclic or acyclic sugar alcohol is selected from a saccharide, reduced sugar, aminosaccharide, aldonic acid, or aldonic acid lactone; wherein each n is independently 0 to 20; each m is independently 0 to 20; m+n is greater than 0; each R.sup.1 is independently a linear or branched alkyl group having 5 to 29 carbons optionally comprising at least 1 unsaturated bond; and each R.sup.2 is independently H, a linear or branched alkyl group having 6 to 30 carbons optionally comprising at least 1 unsaturated bond, or mixtures thereof.

Polymers are described having repeat units of Formula (I): ##STR00001##
wherein R.sup.3 is H or alkyl group; x and t are positive integers; Q is C(O)O, C(O)NH, or direct bond; D is alkylene, arylene, or (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.m; E is O, S, NR.sup.5, or direct bond; R.sup.5 is H or alkyl; G is the residue of a polyisocyanate; V is a urethane, urea, or thiourea that bonds to other parts of the polymer compound or to a monovalent blocking group; s is 1 to 5; Y is O or a substituted or unsubstituted arylene group; A is an alkylene group; w, v, and y are 0 or 1; X is the residue of a cyclic or acyclic sugar alcohol which is substituted with R.sup.1, C(O)R.sup.1, (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mR.sup.2, (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mC(O)R.sup.1, or mixtures thereof; n and m are independently 0 to 20; R.sup.1 is independently an alkyl group; and R.sup.2 is independently H or alkyl group.

Polymers are described having repeat units of Formula (I): ##STR00001##
wherein R.sup.3 is H or alkyl group; x and t are positive integers; Q is C(O)O, C(O)NH, or direct bond; D is alkylene, arylene, or (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.m; E is O, S, NR.sup.5, or direct bond; R.sup.5 is H or alkyl; G is the residue of a polyisocyanate; V is a urethane, urea, or thiourea that bonds to other parts of the polymer compound or to a monovalent blocking group; s is 1 to 5; Y is O or a substituted or unsubstituted arylene group; A is an alkylene group; w, v, and y are 0 or 1; X is the residue of a cyclic or acyclic sugar alcohol which is substituted with R.sup.1, C(O)R.sup.1, (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mR.sup.2, (CH.sub.2CH.sub.2O).sub.n(CH(CH.sub.3)CH.sub.2O).sub.mC(O)R.sup.1, or mixtures thereof; n and m are independently 0 to 20; R.sup.1 is independently an alkyl group; and R.sup.2 is independently H or alkyl group.

The invention relates to the use of binder compositions containing one or more polymers based on ethylenically unsaturated monomers for producing textile sheet products, characterized in that the polymers are based on a) from 0.1 to 10% by weight of one or more ethylenically unsaturated monomers containing epoxy groups, b) from 0.1 to 10% by weight of one or more ethylenically unsaturated monomers containing silane groups and c) one or more other ethylenically unsaturated monomers differing from the monomers a) and b), where the % by weight data are always based on the total weight of the polymers.

The invention relates to the use of binder compositions containing one or more polymers based on ethylenically unsaturated monomers for producing textile sheet products, characterized in that the polymers are based on a) from 0.1 to 10% by weight of one or more ethylenically unsaturated monomers containing epoxy groups, b) from 0.1 to 10% by weight of one or more ethylenically unsaturated monomers containing silane groups and c) one or more other ethylenically unsaturated monomers differing from the monomers a) and b), where the % by weight data are always based on the total weight of the polymers.