Patent classifications
D06M15/6436
Treatment agent for carbon fiber precursor, aqueous solution of treatment agent for carbon fiber precursor, carbon fiber precursor, and method for producing carbon fibers
The present invention addresses the problem of suitably improving a treatment agent for a carbon fiber precursor in terms of the heat resistance and the effect of suppressing fusion between fibers during the step of flame-resisting treatment. This treatment agent for a carbon fiber precursor is characterized by containing a lubricant, the lubricant comprising a specific sulfur-containing diester compound and a specific sulfur-containing monoester compound.
COMPOSITION, FIBER TREATMENT AGENT, FIBER TREATMENT METHOD, AND TREATED FIBER
Provided is a composition that imparts an excellent flexibility to post-treatment fibers and textiles, provides a water-absorptive fiber surface and provides an excellent durability, and can maintain the water absorbency of the fiber surface even after a laundry treatment. Also provided is a fiber treatment agent that contains said composition as an effective component. The composition contains the following component (A) and component (B) wherein the content ratio on a mass basis represented by component (A)/[component (A)+component (B)] is 0.01-1. Component (A) is an organopolysiloxane represented by general formula (1) or a silane represented by general formula (2), and component (B) is water.
FIBERS TO WHICH SILICONE HAS BEEN FIXED, AND PRODUCTION METHOD THEREOF
In one embodiment, the present invention relates to silicone-fixed fibers including fibers and silicone fixed to the fibers. The silicone includes an acrylic-modified organopolysiloxane (A) having two or more acrylic groups per molecule. A rate of decrease in the amount of Si after the silicone-fixed fibers are washed 10 times is less than 50%. The present invention relates to a method for producing silicone-fixed fibers. The method includes coating or impregnating the fibers with a fiber treatment agent containing silicone, and irradiating the fibers coated or impregnated with the fiber treatment agent with an electron beam so that the silicone is fixed to the fibers. The silicone includes an acrylic-modified organopolysiloxane (A) having two or more acrylic groups per molecule. Thus, the present invention provides silicone-fixed fibers that include fibers to which silicone is fixed by electron beam irradiation and have a good texture even after washing, and a method for producing the silicone-fixed fibers.
FIBER TREATMENT AGENT FOR ELECTRON BEAM FIXING
The present invention relates to a fiber treatment agent for electron beam fixing that contains an acrylic-modified organopolysiloxane (A) having two or more acrylic groups per molecule, as represented by the following general formula (I).
M.sub.aM.sup.A.sub.bD.sub.cD.sup.A.sub.dT.sub.e(I) (in the general formula (I), M=R.sup.1R.sup.2R.sup.3SiO.sub.1/2, M.sup.A=R.sup.4R.sup.5R.sup.6SiO.sub.1/2, D=R.sup.7R.sup.8SiO.sub.2/2, D.sup.A=R.sup.9R.sup.10SiO.sub.2/2, T=R.sup.11SiO.sub.3/2, R.sup.1 to R.sup.11 each independently represent a hydrogen atom, an alkyl group having 1 to 4 carbon atoms, or a phenyl group, R.sup.4 and R.sup.9 each independently represent a monovalent hydrocarbon group represented by the following general formula (II), a, to d each independently are 0 or a positive integer, e is an integer of 0 to 3, c+d is an integer of 10 to 1000, b+d is an integer of at least 2, and a+b is an integer equal to e+2.)
##STR00001## (in the general formula (II), n is an integer of 1 to 3.)
Oil agent for carbon-fiber-precursor acrylic fiber, oil agent composition for carbon-fiber-precursor acrylic fiber, oil-treatment-liquid for carbon-fiber-precursor acrylic fiber, and carbon-fiber-precursor acrylic fiber bundle
An oil for a carbon fiber precursor acrylic fiber including: a hydroxybenzoate ester (A) indicated by formula (1a); an amino-modified silicone (H) indicated by formula (3e); and an organic compound (X) which is compatible with the hydroxybenzoate ester (A), in which a residual mass rate R1 at 300 C. in thermal mass analysis in an air atmosphere is 70-100 mass % inclusive, and which is a liquid at 100 C., and a carbon fiber precursor acrylic fiber bundle to which the oil for a carbon fiber precursor acrylic fiber is adhered. ##STR00001##
METHOD FOR TREATING TEXTILE PRODUCT
The present invention is a method for washing a textile product, including the following step 1 and step 2: step 1: a step of treating the textile product by contacting the textile product with treating liquid 1 obtained by mixing water and (A) an internal olefin sulfonate having 17 or more and 24 or less carbons [hereinafter, referred to as component (A)]; and step 2: a step of treating the textile product treated in step 1 by contacting the textile product with treating liquid 2 obtained by mixing water and a finishing agent composition for textile products.
FINISH COMPOSITION
Provided is a composition for the treatment of fibers, such as PAN precursor fibers. The finish composition includes a polysiloxane; an emulsifier; water; and a dicarboxylic acid having a pK.sub.a from 1 to 4, and boiling point from 200 to 400 C. The dicarboxylic acid may have the following formula:
##STR00001##
where R.sub.1 is absent or a saturated or unsaturated, linear or branched, aromatic substituted or unsubstituted, hydrocarbon group; Y.sub.1 and Y.sub.2 are independently hydrogen, nitrogen, oxygen, sulfur, phosphorus, C.sub.1-C.sub.6 alkyl group, or an alkoxy group; and X.sub.1 and X.sub.2 are independently one or more hydrogen atoms, a metal, a quaternary amine, or a hydrocarbon group having up to 6 carbon atoms, the hydrocarbon group being an alkyl group, an alkylene group, or an aromatic group, which may be branched or linear, and may optionally have one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur and phosphorus.
POLYSILOXANE-BASED WATER REPELLANTS FOR TEXTILES
An aqueous emulsion including a discontinuous oil phase comprising: a) a polyorganohydrogensiloxane, b) an amino-modified polyorganosiloxane comprising at least one amino group located at a terminal position and c) a blocked isocyanate.
FILTRATION MEDIA AND FILTERS
Filter media and filters, such as air filters, residential air filters, commercial air filters, face masks, gas turbine and compressor air intake filters, panel filters, and the like, are provided that comprise a plurality of fibers with a silicone-based coating. The silicone-based coating comprises a silicone compound at least about two percent by weight of the coating. The silicone-based coating may include a reactive silicone macroemulsion and a surfactant. The silicone-based coating increases the efficiency of the filter at capturing contaminants, particularly contaminants in the E2 and E3 particle group range, without compromising other important characteristics of the filters, such as cost, longevity, dust holding capacity, and the pressure drop or air permeability of the filter.
Elastic fiber treating agent and elastic fiber
Disclosed is an elastic fiber treatment agent that contains at least one smoothing agent selected from the group consisting of mineral oils, silicone oils, and ester oils and at least one naturally derived ingredient selected from the group consisting of terpene resins and terpene resin derivatives. Also disclosed is an elastic fiber treatment agent that contains at least one smoothing agent selected from the group consisting of mineral oils, silicone oils, and ester oils and at least one naturally derived ingredient selected from the group consisting of rosins and rosin derivatives. In one aspect, the smoothing agent includes a mineral oil and the mineral oil content of the smoothing agent (A) is 59.5% to 95% by mass.