The present disclosure describes a treated cellulosic material comprising: a cellulosic material having a porous structure defining a plurality of pores, at least a portion of the pores containing a treating agent comprising: a polymer comprising an olefin-carboxylic acid copolymer; and a modifying agent comprising a quat.

A sheet having dead-fold properties, wherein said sheet comprises cellulose fibers whereof at least 75%, preferably at least 90%, or more preferably at least 95% of said cellulose fibers have a fiber length of less than 1 mm, and wherein the tensile strength ratio (MD/CD) of the film is above 1.4, preferably higher than 1.6 and most preferably higher than 1.8.

A sheet having dead-fold properties, wherein said sheet comprises cellulose fibers whereof at least 75%, preferably at least 90%, or more preferably at least 95% of said cellulose fibers have a fiber length of less than 1 mm, and wherein the tensile strength ratio (MD/CD) of the film is above 1.4, preferably higher than 1.6 and most preferably higher than 1.8.

The present disclosure describes a treated cellulosic material comprising: a cellulosic material having a porous structure defining a plurality of pores, at least a portion of the pores containing a treating agent comprising: a polymer comprising an olefin-carboxylic acid copolymer; a modifying agent comprising a bivalent, trivalent, or tetravalent metal ion.

The present disclosure describes a treated cellulosic material comprising: a cellulosic material having a porous structure defining a plurality of pores, at least a portion of the pores containing a treating agent comprising: a polymer comprising an olefin-carboxylic acid copolymer; a modifying agent comprising a bivalent, trivalent, or tetravalent metal ion.

Finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in an aqueous liquid containing a cationic prepolymer as a dispersant, wherein the cationic prepolymer is prepared in the presence of at least one polymerisation initiator by polymerisation of (a) from 15 to 45% by weight of at least one ethylenically unsaturated monomer comprising at least one quaternary ammonium group; (b) from 5 to 80% by weight of at least one optionally substituted styrene; (c) from 0 to 50% by weight of at least one C 1-12 alkyl (meth) acrylate; (d) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an acid group; (e) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising an amine group; and (f) from 0 to 20% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (b), (c) and (e), the sum of (a)+(b)+(c)+(d)+(e)+(f) being 100% by weight, in a first emulsion polymerisation in the presence of at least one non-ionic emulsifier, and thereafter, in the aqueous liquid containing the cationic prepolymer a second emulsion polymerisation is carried out, in the presence of at least one polymerisation initiator, of a monomer mixture comprising (i) from 10 to 70% by weight of at least one of an optionally substituted styrene or (meth) acrylonitrile; (ii) from 30 to 90% by weight of at least one CMS alkyl (meth) acrylate; (iii) from 0 to 30% by weight of at least one vinyl ester of linear or branched C.sub.1-30 carboxylic acids; and (iv) from 0 to 30% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (i), (ii) and (iii), the sum of (i)+(ii)+(iii)+(iv) being 100% by weight, and the first emulsion polymerisation and/or the second emulsion polymerisation is optionally carried out in the presence of from 0 to 10% by weight of at least one polymerisation regulator. The polymer dispersions according to the present invention are suitable for use as sizing agents for paper, board and card board.

A method includes: forming core polymer particles by copolymerizing a monomer mixture (a); forming a first shell layer substantially surrounding the particles and not swollen by a base by copolymerizing a monomer mixture (b) in the presence of the particles; swelling the particles with a base to an aqueous dispersion containing the particles on which the layer has been formed in an amount of 0.1-30 parts by weight; and swelling the layer with a monomer mixture (c) to an aqueous dispersion containing the particles on which the layer has been formed in an amount of 0.1-45 parts by weight, in which a difference in water contents represented by (a water content in the particles on which the layer has been formed after swelling the shell)(a water content in the particles on which the layer has been formed before swelling the shell) is 1 to 45%.

A method includes: forming core polymer particles by copolymerizing a monomer mixture (a); forming a first shell layer substantially surrounding the particles and not swollen by a base by copolymerizing a monomer mixture (b) in the presence of the particles; swelling the particles with a base to an aqueous dispersion containing the particles on which the layer has been formed in an amount of 0.1-30 parts by weight; and swelling the layer with a monomer mixture (c) to an aqueous dispersion containing the particles on which the layer has been formed in an amount of 0.1-45 parts by weight, in which a difference in water contents represented by (a water content in the particles on which the layer has been formed after swelling the shell)(a water content in the particles on which the layer has been formed before swelling the shell) is 1 to 45%.

The present disclosure relates to weatherproof or moisture-resistant writable or printable paper or paper-containing substrates, which includes recyclable cellulosic sheets coated with a coating layer. Sheets are suitable for writing and printing and are prepared by impregnantly coating a cellulosic substrate. In addition, a composition used for coating paper sheets and related substrates to obtain general-purpose weatherproof sheets comprising a substrate, a polymer, a cross-linking agent and methods for producing and using the same are disclosed. The sheets resist degradation, remain legible, can be written upon when wet, and are recyclable.

The present disclosure describes a treated cellulosic material comprising: a cellulosic material having a porous structure defining a plurality of pores, at least a portion of the pores containing a treating agent comprising: a polymer comprising an olefin-carboxylic acid copolymer; and a modifying agent comprising a hydrophobic amine.