The present disclosure generally relates to glyoxalated polyacrylamide (GPAM) compositions, methods of preparation and methods of use thereof, particularly in the paper industry. Moreover, the present disclosure generally pertains to cationic GPAM compositions, methods of preparation and methods of use thereof in papermaking applications and in products such as paper-based products, wherein the cationic GPAM compositions may provide increased wet and/or dry strength to the paper-based products, and wherein such cationic GPAM compositions optionally require a reduced volume of an aqueous carrier for storage or transport compared to a volume of an aqueous carrier needed for conventional GPAMs used in papermaking.

The present invention concerns a process for preparing self-binding pigment particles from an aqueous suspension of calcium carbonate containing material, wherein an anionic binder and at least one cationic polymer are mixed with the suspension.

The present invention concerns a process for preparing self-binding pigment particles from an aqueous suspension of calcium carbonate containing material, wherein an anionic binder and at least one cationic polymer are mixed with the suspension.

Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and the use thereof The present invention relates to a finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in a continuous phase containing an aqueous liquid in which the emulsion polymerisation is carried out, in the presence of polymerisation initiators, of a combination of monomers comprising (a) from 0 to less than 60% by weight of at least one optionally substituted styrene, (b) from greater than 0 to 80% of at least one C.sub.1-C.sub.12-alkyl acrylate and/or at least one C.sub.1-C.sub.12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising at least one acid group, (d) from 5 to 20% by weight of at least one ethylenically unsaturated monomer comprising a cationic group, and (e) from 0 to 50% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (a), (b), (c), and (d), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, and the aqueous liquid contains from 0 to 4% by weight based on the weight of the combination of monomers of at least one emulsifier, in which the emulsion polymerisation is carried out optionally in the presence of at least one terpene containing compound. Also claimed is a process or preparing the finely divided, cationic, aqueous polymer dispersion and the use of the finely divided, cationic, aqueous polymer dispersion for sizing paper, board and cardboard.

Finely divided, cationic, aqueous polymer dispersions, method for the production thereof, and the use thereof The present invention relates to a finely divided, cationic, aqueous polymer dispersion which is obtainable by emulsion polymerisation of ethylenically unsaturated monomers in a continuous phase containing an aqueous liquid in which the emulsion polymerisation is carried out, in the presence of polymerisation initiators, of a combination of monomers comprising (a) from 0 to less than 60% by weight of at least one optionally substituted styrene, (b) from greater than 0 to 80% of at least one C.sub.1-C.sub.12-alkyl acrylate and/or at least one C.sub.1-C.sub.12-alkyl methacrylate, (c) from 0 to 10% by weight of at least one ethylenically unsaturated monomer comprising at least one acid group, (d) from 5 to 20% by weight of at least one ethylenically unsaturated monomer comprising a cationic group, and (e) from 0 to 50% by weight of at least one non-ionic ethylenically unsaturated monomer differing from (a), (b), (c), and (d), the sum of (a)+(b)+(c)+(d)+(e) being 100% by weight, and the aqueous liquid contains from 0 to 4% by weight based on the weight of the combination of monomers of at least one emulsifier, in which the emulsion polymerisation is carried out optionally in the presence of at least one terpene containing compound. Also claimed is a process or preparing the finely divided, cationic, aqueous polymer dispersion and the use of the finely divided, cationic, aqueous polymer dispersion for sizing paper, board and cardboard.

A papermaking agent exhibiting an excellent freeness and paper strength effect with little increase in viscosity after long-term storage. A papermaking agent including a (meth)acrylamide polymer containing two or more starches (a1) selected from the group consisting of unmodified starch, oxidized starch, esterified starch, etherified starch, amidated starch, cationic starch, amphoteric starch and crosslinked starch, a (meth)acrylamide (a2), a polymerizable monomer having an amino group (a3), a polymerizable monomer having a carboxy group (a4) and a polymerizable monomer having a sulfonate group (a5) as essential constituent components.

A papermaking agent exhibiting an excellent freeness and paper strength effect with little increase in viscosity after long-term storage. A papermaking agent including a (meth)acrylamide polymer containing two or more starches (a1) selected from the group consisting of unmodified starch, oxidized starch, esterified starch, etherified starch, amidated starch, cationic starch, amphoteric starch and crosslinked starch, a (meth)acrylamide (a2), a polymerizable monomer having an amino group (a3), a polymerizable monomer having a carboxy group (a4) and a polymerizable monomer having a sulfonate group (a5) as essential constituent components.

A process for producing paper or board, which process comprises ad-mixing (I) an aqueous composition of pH ≦6 and (II) at least one water-soluble polymeric anionic compound to a paper stock having a pH in the range from 6 to 8 and then dewatering the paper stock by sheet formation and drying, wherein the aqueous composition comprises (a) polymers having primary amino groups and/or amidine groups to a combined content for these groups of ≧1.5 meq/g of polymer, and (b) 0.01 to 50 mol % of 1,4-cyclohexanedione (b) based on the combined amount of primary amino groups and/or amidine groups of the polymers, and also to the paper or board thus obtained.

A process for producing paper or board, which process comprises ad-mixing (I) an aqueous composition of pH ≦6 and (II) at least one water-soluble polymeric anionic compound to a paper stock having a pH in the range from 6 to 8 and then dewatering the paper stock by sheet formation and drying, wherein the aqueous composition comprises (a) polymers having primary amino groups and/or amidine groups to a combined content for these groups of ≧1.5 meq/g of polymer, and (b) 0.01 to 50 mol % of 1,4-cyclohexanedione (b) based on the combined amount of primary amino groups and/or amidine groups of the polymers, and also to the paper or board thus obtained.

The present invention provides aqueous compositions for treating fluff pulp comprising (i) one or more acrylic acid polymers containing phosphinate groups and having a weight average molecular weight of from 1,000 to 6,000 and (ii) from 5 to 50 wt. %, based on the total solids weight of the aqueous compositions, of one or more polyethylene glycols, having a formula weight of from 150 to 7,000, or, preferably, from 200 to 600. The present invention also provides individualized, intrafiber crosslinked cellulosic fibers comprising the cellulosic fiber and, in cured form, the aqueous compositions, as well as methods of making the individualized, intrafiber crosslinked cellulosic fibers.