A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

A fluorine-free composition includes at least one polycarbodiimide compound derived from a carbodiimidization reaction of a carbodiimidization reaction mixture comprising at least one oligomer, wherein the oligomer comprises at least one isocyanate end group and at least two repeating units, wherein each of the at least two repeating units comprises at least one hydrocarbon group having at least 16 carbon atoms. The composition may also include at least one paraffin wax. Such compositions are useful for treating fibrous substrates to enhance their water-repellency.

A reinforced paper includes a nonwoven fibrous mat impregnated with a polyetherimide composition. The nonwoven fibrous mat includes a reinforcing fiber, a high strength toughening fiber, or a combination thereof. The polyetherimide composition includes a polyetherimide having repeating units as defined herein. A method of making a reinforced paper is also disclosed. The method includes contacting at least a portion of a nonwoven fibrous mat with a composition to form a pre-preg, and heating under conditions effective to provide the reinforced paper. Articles including the reinforced paper are also described.

A reinforced paper includes a nonwoven fibrous mat impregnated with a polyetherimide composition. The nonwoven fibrous mat includes a reinforcing fiber, a high strength toughening fiber, or a combination thereof. The polyetherimide composition includes a polyetherimide having repeating units as defined herein. A method of making a reinforced paper is also disclosed. The method includes contacting at least a portion of a nonwoven fibrous mat with a composition to form a pre-preg, and heating under conditions effective to provide the reinforced paper. Articles including the reinforced paper are also described.

The present invention relates to an interpenetrating polymer network (IPN) material comprising a copolymer of vinylamine-vinylformamide, and a homo-polymer or a copolymer of at least one monomer selected from acrylamide or derivatives thereof, acrylic acid or derivatives thereof, or a mixture thereof forming the IPN material together with the copolymer of vinylamine-vinyl-formamide. The present invention further relates to a process for producing the IPN material, and to use of the IPN material in paper industry.

The present invention relates to an interpenetrating polymer network (IPN) material comprising a copolymer of vinylamine-vinylformamide, and a homo-polymer or a copolymer of at least one monomer selected from acrylamide or derivatives thereof, acrylic acid or derivatives thereof, or a mixture thereof forming the IPN material together with the copolymer of vinylamine-vinyl-formamide. The present invention further relates to a process for producing the IPN material, and to use of the IPN material in paper industry.

The invention relates to fibrous structures having desirable physical properties, such as good tensile strength, low stiffness and high bulk, manufactured using a fiber furnish comprising cellulosic fibers having a pH of 5.0 or less and at least one strength resin. Not only do structures prepared with acidic fibers have desirable physical properties, they may also be manufactured in an energy efficient manner. To achieve the greatest energy savings it is generally desirable that acidic fibers not be subjected to mechanical treatment, such as by refining, prior to forming the fiber into a fibrous structure. Further, it may be desirable to subject the remainder of the fiber furnish to a minimal degree of mechanical treatment, such as by refining, so as to produce a furnish having a freeness greater than about 550 mL.

The present disclosure provides cellulose reactive glyoxalated vinylamide polymers which impart improved wet strength decay properties, as well as high efficiency of wet strength build in paper products. A method of preparing a cellulose reactive glyoxalated vinylamide polymer composition, and methods of its use in maunfacturing paper products, as well as the resulting paper products, are also provided.

The present invention relates to a process for producing a paper or a board product having increased dimension stability including providing a fibre slurry including never-dried fibres, treating the fibre slurry with a strength composition, and forming a paper or a board product from the treated fibre slurry, where the strength composition includes a permanent wet strength resin component and a sizing agent. The present invention further relates to a use of a strength composition for increasing dimensional stability of a paper and a board, and to a paper or a board product having improved dimensional stability.

The present invention provides a novel method and composition for enhancing the efficiency of starch adsorption (i.e., starch trapping) from starch-containing furnishes comprising high content of recycled fibers for use in paper making processes such as pulp, paper, or board production. A novel polymer coagulation system is disclosed in which two quick inversion cationic emulsion polymers (starch trapping polymers A and B) are co-mixed at optimal blend ratios to meet specific recycled fiber and process water requirements for different recycled fiber plants and added to furnishes prior to formation of paper or board in a paper machine. Co-mixed solutions of starch trapping polymers A and B provide synergistic enhancements in (i) starch trapping efficiency and (ii) starch retention in the produced paper or board over equivalent dosage levels of singly administered polymer A, polymer B, or conventional starch trapping products, without over-flocculation or formation of stickies.