A coating structure for a sheet-like substrate, which includes lignocellulosic fibres is disclosed. The structure includes at least one pre-coat layer including at least 70 weight-% of a first styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser, having a glass transition temperature Tg ≤20° C. preferably ≤10° C., ≤30 weight-% of inorganic platy mineral particles and 0.01-2 weight-% of at least one first thickener. The coating structure further includes a top coat layer including at least 50 weight-% of a second styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser having a glass transition temperature Tg ≤20° C. preferably ≤10° C., ≤30 weight-% of inorganic mineral particles, 0.01-5 weight-% of at least one second thickener and 0.5-30 weight-% of an antiblocking agent. Further disclosed is a sheet-like product coated with the coating structure.

A coating structure for a sheet-like substrate, which includes lignocellulosic fibres is disclosed. The structure includes at least one pre-coat layer including at least 70 weight-% of a first styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser, having a glass transition temperature Tg ≤20° C. preferably ≤10° C., ≤30 weight-% of inorganic platy mineral particles and 0.01-2 weight-% of at least one first thickener. The coating structure further includes a top coat layer including at least 50 weight-% of a second styrene (meth)acrylate copolymer polymerised in the presence of a stabiliser having a glass transition temperature Tg ≤20° C. preferably ≤10° C., ≤30 weight-% of inorganic mineral particles, 0.01-5 weight-% of at least one second thickener and 0.5-30 weight-% of an antiblocking agent. Further disclosed is a sheet-like product coated with the coating structure.

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium,

(a) 40 to 75 parts by weight of at least one vinylaromatic compound and
(b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene
(c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and
(d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer,
the amounts of the monomers (a) to (d) adding up to 100 parts by weight,
in a monomer feed process in the presence of at least one inorganic peroxide and at least one organic peroxide, with the proviso that the continuous metering of the inorganic peroxide starts at the same time as the continuous metering of the vinylaromatic compound, the metering of the organic peroxide is started at a time at which at least 5% and not more than 20% of the vinylaromatic compound has already been metered in in a continuous mass flow under polymerization conditions and optionally a portion of the inorganic peroxide is initially charged,
and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

The present invention relates to a process for producing an aqueous polymer dispersion by free-radically initiated aqueous emulsion polymerization, by polymerizing, in an aqueous medium,

(a) 40 to 75 parts by weight of at least one vinylaromatic compound and
(b) 24.9 to 59.9 parts by weight of at least one conjugated aliphatic diene
(c) 0.1 to 10 parts by weight of at least one monomer comprising acid groups and
(d) 0 to 20 parts by weight of at least one other monoethylenically unsaturated monomer,
the amounts of the monomers (a) to (d) adding up to 100 parts by weight,
in a monomer feed process in the presence of at least one inorganic peroxide and at least one organic peroxide, with the proviso that the continuous metering of the inorganic peroxide starts at the same time as the continuous metering of the vinylaromatic compound, the metering of the organic peroxide is started at a time at which at least 5% and not more than 20% of the vinylaromatic compound has already been metered in in a continuous mass flow under polymerization conditions and optionally a portion of the inorganic peroxide is initially charged,
and also to the aqueous polymer dispersions produced by the process and to the use of these as a binder, adhesive, sizing agent for fibers, for the production of coatings or for the production of a paper coating slip.

A printed substrate, wherein a printed polymer layer is present on a surface of the substrate, is disclosed. The printed polymer layer comprises a polymer chosen from one or more of polyvinyl chloride, a copolymer of vinyl chloride and vinyl acetate, and a terpolymer of vinyl chloride, vinyl acetate and ethylene; a plasticizer; a colorant; and calcium carbonate.

A coated paperboard container includes an inner paperboard substrate, an outer paperboard substrate, a first aqueous barrier coating located on the inner paperboard substrate, and a second aqueous barrier coating located on the outer paperboard substrate. The inner paperboard substrate and the outer paperboard substrate are coupled with an adhesive. The first aqueous barrier coating and the second aqueous barrier coating include a pigment and a binder and the first aqueous barrier coating is heat sealable.

A method for manufacturing a paperboard structure includes passing a paperboard substrate through a hot-hard calender to yield a calendered paperboard substrate, the hot-hard calender including a nip defined by a thermo-roller and a counter roller, wherein a contact surface of the thermo-roller is heated to an elevated temperature. The method then includes applying a basecoat to the calendered paperboard substrate to yield a basecoated paperboard substrate, the basecoat includes a basecoat binder and a basecoat pigment blend. The method further includes applying a topcoat to the basecoated paperboard substrate.

A method for manufacturing a paperboard structure includes passing a paperboard substrate through a hot-hard calender to yield a calendered paperboard substrate, the hot-hard calender including a nip defined by a thermo-roller and a counter roller, wherein a contact surface of the thermo-roller is heated to an elevated temperature. The method then includes applying a basecoat to the calendered paperboard substrate to yield a basecoated paperboard substrate, the basecoat includes a basecoat binder and a basecoat pigment blend. The method further includes applying a topcoat to the basecoated paperboard substrate.

A wall covering comprising a planar substrate having a front and a back facing opposite the front and an adhesive layer that covers the back of the substrate. The adhesive layer includes a separate polymer layer, formed by a polyvinyl alcohol polymer. Wall covering for example in the form of a pre-pasted paper is readily reactivated when wet, and exhibits no blocking, while having properties of sliding, adhesion, and stripability.

A coated paperboard is disclosed which includes a base coat and top coat containing substantially no fluorochemical or wax, exhibiting good resistance to oil and grease, no tendency toward blocking, and being fully repulpable. Improved moisture resistance is also exhibited.