The present invention relates to a new process for improving dewatering when manufacturing a film comprising high amounts of microfibrillated cellulose (MFC) without negatively impacting the film properties. According to the present invention a high amount of nanoparticles is used as an additive, optionally together with a polymer.

A composition for improving softness of tissue and/or towel products includes lignocellulosic fibers; water; and a hydrophobic softener that includes the reaction product of: (1) at least one di- and/or poly-amine, (2) at least one chain extender having at least two carboxyl groups; and (3) at least one hydrophobic end-capper. The reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product. In addition, a method of improving softness of tissue and/or towel products includes combining the lignocellulosic fibers, the water, and the hydrophobic softener; and creating the tissue and/or towel products.

A composition for improving softness of tissue and/or towel products includes lignocellulosic fibers; water; and a hydrophobic softener that includes the reaction product of: (1) at least one di- and/or poly-amine, (2) at least one chain extender having at least two carboxyl groups; and (3) at least one hydrophobic end-capper. The reaction product comprises a hydrophobic substitution of at least about 25 mole percent of the hydrophobic end-capper based on a total number of moles of active amine sites of the reaction product. In addition, a method of improving softness of tissue and/or towel products includes combining the lignocellulosic fibers, the water, and the hydrophobic softener; and creating the tissue and/or towel products.

The invention pertains to a cellulosic material provided with a coating comprising an oxidized carboxylated starch having a weight-average molecular weight of 0.3−10×10.sup.6 Da and a water-soluble starch extender present in a quantity of 0 to 25 wt. % based on the coating dry weight, selected from a crosslinked cationic polyalkylene amine and a zirconium carbonate, as well as to use thereof in improving the oil and grease resistance of paper. The invention furthermore pertains to a method to improve the oil and grease resistance of a cellulosic material, comprising providing a cellulosic material, coating said material on at least one side with a homogenous aqueous composition comprising an oxidized carboxylated starch having a weight-average molecular weight of 0.3−10×106 Da and 0-3 wt. % of a starch extender, selected from a crosslinked cationic polyalkylene amine and a zirconium carbonate, and drying the cellulosic material.

The invention relates to fibrous structures having desirable physical properties, such as good tensile strength, low stiffness and high bulk, manufactured using a fiber furnish comprising cellulosic fibers having a pH of 5.0 or less and at least one strength resin. Not only do structures prepared with acidic fibers have desirable physical properties, they may also be manufactured in an energy efficient manner. To achieve the greatest energy savings it is generally desirable that acidic fibers not be subjected to mechanical treatment, such as by refining, prior to forming the fiber into a fibrous structure. Further, it may be desirable to subject the remainder of the fiber furnish to a minimal degree of mechanical treatment, such as by refining, so as to produce a furnish having a freeness greater than about 550 mL.

The invention relates to fibrous structures having desirable physical properties, such as good tensile strength, low stiffness and high bulk, manufactured using a fiber furnish comprising cellulosic fibers having a pH of 5.0 or less and at least one strength resin. Not only do structures prepared with acidic fibers have desirable physical properties, they may also be manufactured in an energy efficient manner. To achieve the greatest energy savings it is generally desirable that acidic fibers not be subjected to mechanical treatment, such as by refining, prior to forming the fiber into a fibrous structure. Further, it may be desirable to subject the remainder of the fiber furnish to a minimal degree of mechanical treatment, such as by refining, so as to produce a furnish having a freeness greater than about 550 mL.

A method of making an absorbent structure including mixing ultra-high molecular weight (“UHMW”) glyoxalated polyvinylamide adducts (“GPVM”) and/or high molecular weight (“HMW”), glyoxalated polyacrylamide and/or high cationic charge glyoxalated polyacrylamide (“GPAM”) copolymers and high molecular weight (“HMW”) anionic polyacrylamide (“APAM”) with the furnish during stock preparation of a wet laid papermaking process.

A differential density paper product comprising at least one paper web is disclosed. The paper product has: (a) from about 20% to about 90% by weight of the dry fiber basis of the paper product of a refined soft wood pulp fiber mixture, (b) pulp fibers selected from the group consisting of hard wood fibers, non-wood fibers, recycled fibers, synthetic polymer fibers, bleached eucalyptus kraft fibers, and combinations thereof; and, (c) not more than about 10% by weight moisture.

A method for manufacturing a multi-layered fibrous web is disclosed, which includes at least two fibrous layers, where each layer is formed from one or more fibre stocks. The fibrous layers are combined prior to subjecting the multilayered fibrous web to wet-pressing and drying. At least one layer of the multi-layered fibrous web is formed from a fibre stock including at least 50 weight-% of a chemi-thermomechanical pulp (CTMP), a hardwood kraft pulp and/or a recycled fibre material calculated from a thick stock applied to a particular layer approach system. A first strength component and a second strength component are added to the fibre stock. The first strength component includes a cationic strength agent and the second strength component includes a synthetic amphoteric polymer composition having a net charge from −3 to +1 meq/g (dry), at a pH of 7.

A method for manufacturing a multi-layered fibrous web is disclosed, which includes at least two fibrous layers, where each layer is formed from one or more fibre stocks. The fibrous layers are combined prior to subjecting the multilayered fibrous web to wet-pressing and drying. At least one layer of the multi-layered fibrous web is formed from a fibre stock including at least 50 weight-% of a chemi-thermomechanical pulp (CTMP), a hardwood kraft pulp and/or a recycled fibre material calculated from a thick stock applied to a particular layer approach system. A first strength component and a second strength component are added to the fibre stock. The first strength component includes a cationic strength agent and the second strength component includes a synthetic amphoteric polymer composition having a net charge from −3 to +1 meq/g (dry), at a pH of 7.