Provided is a method and composition for the in-situ generation of synthetic sweet spots in tight-gas formations. The composition can include nitrogen generating compounds, which upon activation, react to generate heat and nitrogen gas. The method of using the composition includes injecting the composition into a tight-gas formation such that upon activation, heat and nitrogen gas are generated. Upon the generation of nitrogen gas and heat within the formation, microfractures are produced within the formation and the hydrostatic pressure within the reservoir is reduced to less than the reservoir fluid pressure, such that the rate of production of hydrocarbons from the formation is increased.

A chemical reaction heat source for use in heaters used in down-hole application. The heat source has a fuel composition that comprises thermite and a damping agent. The use of the thermite mix enables the heaters of the present invention to generate hotter temperature down wells. This in turn allows the use of Bismuth/Germanium alloys, which have higher melting points, to enable the production of plugs for the abandonment of deeper wells where subterranean temperatures are higher.

A downhole tool for use in a gas or oil well is provided. The tool comprising a length of tubing having at least one annular sealing means mounted on the outer surface thereof. The annular sealing means, which are formed from a eutectic/bismuth based alloy, serve to secure the downhole tool in position within an oil or gas well during so that the tool can carry out its function.

Terpene-based spotting fluid compositions and processes for freeing differentially stuck pipe are provided. A spotting fluid composition includes a terpene and an acid, such that the acid initiates an exothermic polymerization reaction of the terpene. Another spotting fluid composition includes an invert emulsion having a terpene external phase and a non-miscible organic hygroscopic fluid internal phase. The terpene emulsion spotting fluid composition may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the spotting fluid composition contacts a filter cake surrounding the portion of the differentially stuck pipe. An acid may be introduced downhole in the vicinity of a portion of a differentially stuck pipe such that the acid initiates an exothermic polymerization reaction of the terpene of the terpene emulsion spotting fluid composition.

A system and method for delivering heat to a fluid in a fluid production pipeline. Particles are injected into a line adjacent the fluid production pipeline. The particles include a microencapsulated liquid exothermic phase change material configured to undergo a phase change by solidification and release heat at a selected temperature. The released heat is transferred to the fluid production pipeline.

An oil or gas well fishing tool is provided. The downhole fishing tool has a receptacle that is open at one end. The tool also has deployment tool engaging means, located on the opposite end of the receptacle to the one end. The tool further has a layer of an alloy provided on the interior surface of the receptacle. The alloy is a eutectic alloy and/or a bismuth alloy. The tool further comprises heating means to heat the alloy so that it melts and can flow over any object received within the receptacle.

Methods, systems, and compositions for increasing hydrocarbon production from a wellbore where the wellbore or a nearby hydrocarbon reservoir is suffering from water blockage, one method including identifying water blockage in a rock sample of a formation via increased capillary pressure in the rock sample; formulating an exothermic reaction component to remove water blockage from a reservoir rock in situ via heat and pressure release, the reservoir rock type the same as the rock sample; injecting the exothermic reaction component into the wellbore; and allowing the exothermic reaction component to react to remove water blockage in situ to decrease capillary pressure of the reservoir rock without substantially changing porosity of the reservoir rock.

A downhole method comprises expanding a patch member. The patch member may be employed in a method of sealing a wall of a bore. The sealing method may comprise: providing the patch member with a sealing material on an exterior surface; running the patch member into the bore in a smaller diameter first configuration; heating the sealing material to render the sealing material flowable; reconfiguring the patch member to a larger diameter second configuration; and hardening the sealing material to provide a seal between the exterior surface of the patch member and an inner surface of the bore.

Methods including generating heat and/or gas in subterranean operations, pipelines, and other related applications. In some embodiments, the methods include providing treatment composition including a carrier fluid, a catalyst, a first reactant, a second reactant, a solvent, an emulsifier, and a foaming agent, wherein the first and second reactants are capable of reacting in an exothermic chemical reaction; and introducing the treatment composition into at least a portion of a conduit or container having a temperature of less than 30° C.

A sand screen assembly for a subterranean wellbore includes a base pipe having a central axis and including a flow port extending radially therethrough. The sand screen assembly also includes a screen element disposed about the base pipe and radially spaced from the base pipe to define an annulus radially positioned between the screen element and the base pipe. In addition, the sand screen assembly includes a manifold formed about the based pipe. The flow port is in fluid communication with the manifold and axially overlaps with the manifold. Further, the sand screen assembly includes a phase change material disposed within the manifold. The phase change material is configured to melt at a temperature below a melting temperature of the base pipe and flow into the flow port.