Certain example embodiments of this invention relate to vacuum insulating glass (VIG) units having improved seals made using two different frit-based edge seal materials, and/or methods of making the same. In certain example embodiments, a first frit material is applied around peripheral edges of first and second glass substrates. The first frit material, which may be bismuth-based in certain example embodiments, is fired with a heat treatment (e.g., thermal tempering) process. A second frit material, which may be VBZ-based in certain example embodiments, is applied and at least partially overlaps with the fired first frit material. The first frit material acts as a primer, and the second frit material helps seal together the VIG unit. The second frit material is fired at a significantly lower temperature that enables the glass to retain the temper or other strength imparted by the heat treatment.

Certain example embodiments relate to seals for glass articles. Certain example embodiments relate to a composition used for sealing an insulted glass unit. In certain example embodiments the composition includes vanadium oxide, barium oxide, zinc oxide, and at least one additional additive. For instance, another additive that is a different metal oxide or different metal chloride may be provided. In certain example embodiments, a composition may be combined with a binder solution that substantially or completely burns out by the time the composition is melted. In certain example embodiments, a CTE filler is included with a frit material. In certain example embodiments, a vacuum insulated glass unit includes first and second glass substrates that are sealed together with a seal that includes the above-described composition.

The disclosure describes a tempered vacuum glass, which comprises: at least two glass sheets arranged parallel to each other; surrounding edges of adjacent glass sheets being sealed using an edge sealing structure; and support members placed in an array between the adjacent glass sheets to form a vacuum space. The edge sealing structure is a metallic edge-sealing structure. The structure comprises a first transition layer, a first metallized layer, a first intermetallic compound layer, a solder layer, a second intermetallic compound layer, a second metallized layer, and a second transition layer stacked in that order. The first and second metallized layers are in a spongy skeleton structure formed by sintering a metal paste. The first and second transition layers are formed by sintering the metal paste on the adjacent glass sheets, and contain a glass phase layer including metallic particles and a metal oxide layer with a net structure.

A compressible pillar is disclosed for the preparation of a vacuum insulated glazing (VIG) unit, having a longitudinal extent in a longitudinal direction when in an uncompressed state, and comprising:

a deformable part comprising an open structure, wherein the open structure at least partially collapses under a compression force acting in the longitudinal direction of the compressible pillar, the compression force being of at least one value selected within the range of 60 N to 320 N such as a value of the compression force being selected from the range of 60 N to 140 N, from the range of 140 N to 230 N, or from the range of 230 N to 320 N, wherein the longitudinal extent of the compressible pillar decreases to a compressed longitudinal extent when the compressible pillar is subjected to the compression force, and

wherein the compressed longitudinal extent of the compressible pillar increases to an expanded longitudinal extent when the compression force is released, wherein the increase in the longitudinal extent is less than the decrease in the longitudinal extent. Furthermore is disclosed a process of manufacturing a compressible pillar, a method of producing a vacuum insulated glazing unit by the use of such pillars and a vacuum insulated glazing unit comprising such pillars.

When producing insulating glass including at least two panes of glass (1) and at least one spacer of thermoplastic material arranged between the panes of glass, to seal the beginning (4) and the end (5) of the strand (2) of thermoplastic material the thermoplastic material is compressed with the aid of jaws placed against the side faces of the strand. In the region of the joint thus formed between the beginning and the end of the strand forming the spacer, the width of the strand is reduced with the aid of a compression die with a convexly curved active face such that a depression is created. This depression has the effect that, after the assembly of an insulating glass blank, placing a second pane of glass onto the free edges of the strand produces an opening that allows a pressure equalization during the subsequent compression of the insulating glass blank.

A vacuum insulating panel includes first and second substrates (e.g., glass substrates), a hermetic edge seal, a pump-out port, and spacers sandwiched between at least the two substrates. The gap between the substrates may be at a pressure less than atmospheric pressure to provide insulating properties. The panel may include a getter. The getter may be laser activated in a manner which causes the getter to transform and realize a TiAlV phase (e.g., Al.sub.3V.sub.0.333Ti.sub.0.667) of crystallite material. The getter may be a thin film getter and/or may be elongated in shape.

A method of making a vacuum insulating panel including a first substrate, a second substrate, a plurality of spacers provided in a gap between at least the first and second substrates, and a seal provided between at least the first and second substrates, the seal comprising a first seal layer, and optionally second and/or third primer layer(s). The method may include at least one of: (i) laser heating, using a laser beam from a laser, the first seal material for firing and/or sintering the first seal material to form the first seal layer, in a manner that causes TeO.sub.4>TeO.sub.3 in the first seal material to transform into TeO.sub.3>TeO.sub.4 due to said laser heating, whereby an amount of TeO.sub.4 decreases and an amount of TeO.sub.3 increases due to said laser heating, and/or (ii) laser heating in a manner that causes V.sub.2O.sub.5>VO.sub.2 in the first seal material to transform into VO.sub.2>V.sub.2O.sub.5 due to said laser heating whereby an amount of VO.sub.2 increases and an amount of V.sub.2O.sub.5 decreases due to said laser heating, so that after said laser heating the first seal layer comprises more VO.sub.2 than V.sub.2O.sub.5 by wt. %.

A method of making a vacuum insulating panel, the vacuum insulating panel comprising a first glass substrate, a second glass substrate, a plurality of spacers provided in a gap between at least the first and second glass substrates, and a seal provided between at least the first and second glass substrates, the seal comprising a first seal layer and/or a second seal layer. The method may include laser heating, using a laser beam from a continuous wave near-IR laser, seal material in order to form the first seal layer; wherein the laser heating may include causing the laser beam to move at a lateral speed of from about 5-70 mm/second relative to the substrates and the first seal material so that the laser beam at least partially passes through at least one of the glass substrates and impinges upon at least the second seal layer in order to heat the second seal layer and fire and/or sinter the first seal material thereby forming the first seal layer.

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at a pressure less than atmospheric pressure; a seal provided between at least the first substrate and the second substrate, the seal comprising a first seal layer; wherein the first seal layer comprises tellurium oxide and vanadium oxide; wherein the first seal layer comprises, on a wt. %, more tellurium oxide than vanadium oxide, and has a density of from about 2.8-4.0 g/cm.sup.3.

A vacuum insulating panel may include: a first substrate; a second substrate; a plurality of spacers provided in a gap between at least the first and second substrates, wherein the gap is at pressure less than atmospheric pressure; a pump-out/evacuation tube extending at least partly into an aperture in one of the substrates; and a pump-out/evacuation tube seal. The pump-out/evacuation tube seal may include at least one of: (a) from about 20-80 wt. % tellurium oxide, the tellurium oxide comprising TeO.sub.4 and TeO.sub.3, wherein the pump-out tube seal comprises more TeO.sub.3 than TeO.sub.4 by wt. %; and/or (b) tellurium oxide and from about 10-50 wt. % vanadium oxide, wherein the pump-out tube seal by wt. % comprises more tellurium oxide than vanadium oxide, and wherein the vanadium oxide comprises VO.sub.2 and V.sub.2O.sub.5, and wherein more V in the pump-out tube seal is in a form of VO.sub.2 than V.sub.2O.sub.5. A substantially donut-shaped laser beam may be used to heat pump-out tube material in order to form a pump-out tube seal.