An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. In the after treatment method, a rich air/fuel ratio (AFR) is controlled in multiple phases in response to detecting that conversion to the rich AFR is desired.

A mixing device for an exhaust system of an internal combustion engine includes a mixing section (14) with a mixing section inlet area (20) to be positioned downstream in relation to a reactant introduction device (12). A mixing section outlet area (22) is positioned upstream in relation to a catalytic converter device (16). The mixing section (14) includes an inner wall (26) surrounding an inner volume (28), through which exhaust gas (A) or/and reactant (R) can flow, and an outer wall (24) surrounding the inner wall (26). An outer volume (30) surrounds the inner volume (28) in a ring-shape, formed between the inner wall and the outer wall (24). An electrically energizable heating device (34) is provided at the inner wall (26), or/and a heat transfer rib formation (54) is provided at the inner wall (26).

An automotive exhaust aftertreatment system includes an onboard ammonium carbamate reactor. The onboard ammonium carbamate reactor is coupled to a diesel emission fluid reservoir also included in the system and is configured to generate aqueous ammonium carbamate solution from diesel emission fluid. A doser configured to inject the generated aqueous ammonium carbamate solution has integrated heating.

A reductant generator includes a housing defining a chamber, an inlet to direct engine exhaust gas into the chamber, a moveable member that receives driving input from an engine and which is configured to compress engine exhaust gases within the chamber, and a supply to provide a fluid into the chamber to be transformed into reductant. The generator also includes an outlet from which the reductant is directed into an exhaust system.

An after treatment system is disclosed. The after treatment system may include a three-way catalyst (TWC), a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows. The CUC may include a zeolite in which Cu and Fe are ion-exchanged and CeO.sub.2 in which Pt is supported, wherein a weight ratio of the CeO.sub.2 to a total weight of the CUC is 30-70 wt % such that the CUC purifies NH.sub.3 at a lean air/fuel ratio and purifies NH.sub.3 during a delay time at a rich air/fuel ratio.

An after treatment system is disclosed. The after treatment system may include an exhaust pipe through which an exhaust gas flows; a three-way catalyst (TWC) mounted on the exhaust pipe and purifying HC, CO, and NOx contained in the exhaust gas, an ammonia production catalyst (APC) mounted on the exhaust pipe at a downstream of the TWC, storing NOx at a lean air/fuel ratio, and generating H.sub.2, releasing the stored NOx, and generating NH.sub.3 using the released NOx and the generated H.sub.2 at a rich air/fuel ratio, and a selective catalytic reduction (SCR) catalyst mounted on the exhaust pipe at a downstream of the APC, storing the NH.sub.3 generated in the TWC and the APC, and reducing the NOx contained in the exhaust gas using the stored NH.sub.3.

An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. In the after treatment method, a rich air/fuel ratio (AFR) is controlled in multiple phases in response to detecting that conversion to the rich AFR is desired.

An after treatment system for a lean-burn engine is disclosed. The after treatment system is sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction (SCR) catalyst, and a CO clean-up catalyst (CUC) on an exhaust pipe through which an exhaust gas flows and which is connected to a lean-burn engine. An exhaust flow changer is disposed between the ammonia production catalyst module and the SCR catalyst. The exhaust flow changer changes flow of an exhaust gas discharged from the ammonia production catalyst module according to a temperature of the SCR catalyst.

An after treatment method for a lean-burn engine is disclosed. The after treatment method is configured to control an after treatment system sequentially equipped with an ammonia production catalyst module, a selective catalytic reduction catalyst, and a CO clean-up catalyst on an exhaust pipe through which an exhaust gas flows. In the after treatment method, the engine is operated sequentially at a stoichiometric air/fuel ratio (AFR) and a lean AFR prior to entering a rich AFR.

An automotive exhaust aftertreatment system includes an onboard ammonium carbamate reactor. The onboard ammonium carbamate reactor is coupled to a diesel emission fluid reservoir also included in the system and is configured to generate aqueous ammonium carbamate solution from diesel emission fluid. A hybrid heating system for use with the ammonium carbamate reactor is provided in this disclosure.