An exhaust treatment catalyst (5) is arranged in the engine exhaust passage, and hydrogen generated in the reformer (6) is supplied through the hydrogen supply pipe (13) to the inside of the engine exhaust passage upstream of the exhaust treatment catalyst (5). Heat exchange fins (15) for heat exchange with exhaust gas flowing through the inside of the engine exhaust passage are formed on the outer circumferential surface of the hydrogen supply pipe (13) inserted inside the engine exhaust passage.

An internal combustion engine assembly comprising a fuel reformer, a combustion chamber and a controller. The fuel reformer comprises a first channel and a second channel, a portion of the second channel being adjacent to a portion of the first channel to facilitate heat exchange between the first and second channels. The first channel comprises a catalyst selected to reform ammonia to hydrogen and nitrogen. The first channel is configured to receive ammonia, pass the ammonia over the catalyst and output a first mixture comprising ammonia, hydrogen and nitrogen. The composition of the first mixture depends on a first reformer temperature of the first channel. The combustion chamber is configured to receive the first mixture from the fuel reformer; to receive an oxidant; to combust the first mixture in the oxidant to produce heat and a first product; and to output the first product. The second channel of the fuel reformer is configured to receive the first product.

Disclosed herein are emission treatment systems, articles, and methods for selectively reducing NOx compounds. The systems include a hydrogen generator, a hydrogen selective catalytic reduction (H.sub.2-SCR) article, and one or more of a diesel oxidation catalyst (DOC) and/or a lean NOx trap (LNT) and/or a low temperature NOx adsorber (LTNA). Certain articles may comprise a zone coated substrate and/or a layered coated substrate and/or an intermingled coated substrate of one or more of the H.sub.2-SCR and/or DOC and/or LNT and/or LTNA catalytic compositions.

A fuel reforming system includes an engine combusting reformed gas to generate mechanical power; an intake line connected with the engine to supply the reformed gas and air to the engine; an exhaust line connected with the engine to circulate exhaust gas exhausted from the engine; a fuel reformer provided at an exhaust gas recirculation (EGR) line diverging from the exhaust line, mixing the exhaust gas passing through the EGR line with fuel and reforming the fuel mixed with the exhaust gas; a water temperature controller (WTC) provided at the engine to control coolant cooling the engine; a radiator for radiating a portion of heat generated from the engine to atmosphere through the coolant; a temperature sensor provided at the EGR line at a front end of the fuel reformer and measuring temperature of the exhaust gas at the front end of the fuel reformer; a coolant passage provided to connect an exit of the engine, the fuel reformer, the radiator, and an entrance of the engine in series; and a coolant supply control valve for supplying the coolant into an inside of the fuel reformer according to engine driving condition and temperature of the exhaust gas.

An exhaust purification system of an internal combustion engine comprising at least two exhaust treatment catalysts arranged in an engine exhaust passage, a hydrogen feed source, and a plurality of hydrogen feed passages for feeding hydrogen from the hydrogen feed source to the exhaust treatment catalysts. When warming up the exhaust treatment catalysts, hydrogen is fed from the hydrogen feed source through the corresponding hydrogen feed passage to the exhaust treatment catalyst with the larger rise of the exhaust removal rate when hydrogen is fed among the exhaust treatment catalysts.

A hydrogen producing device is mounted at an exhaust gas port of a vehicle to receive exhaust gas and waste heat as a heat source necessary for a reforming reaction with a catalyst member in a reaction chamber. The hydrogen producing device includes a heating chamber in which the reaction chamber is received, a fuel introducing tube disposed to introduce fuel to the reaction chamber, an air introducing tube disposed in the heating chamber to exchange heat with a reaction air thereinto and introducing the reaction air into the reaction chamber for the reforming reaction, and a product discharging tube disposed to discharge a hydrogen-rich synthesis gas generated in the reaction chamber.

A modular plasma treatment system has interchangeable and easily accessible inner and outer electrodes that concentrically nest within an outer housing of one or more plasma reformers. The inner and outer electrodes have self-centering features that allow for blind-fitting of the interchangeable inner and outer electrodes during electrode replacement and maintenance. A plurality of reformers that generate different types of plasmas are preferably arranged serially to allow for a mixture of separate plasmas within the same reaction area and to increase utilization of short-lived radicals.

An exhaust treatment catalyst (13) arranged in an engine exhaust passage and a heat and hydrogen generation device (50) are provided. The amount of fuel fed to the heat and hydrogen generation device (50), which is required for making the temperature of the exhaust treatment catalyst (13) rise by exactly a predetermined temperature rise by heat and hydrogen fed from the heat and hydrogen generation device (50) when the exhaust treatment catalyst (13) is not poisoned and does not thermally deteriorate, is calculated based on the amount of exhaust gas. When fuel of the reference feed fuel amount corresponding to the amount of exhaust gas is fed to the heat and hydrogen generation device (50) and the temperature rise of the exhaust treatment catalyst (13) fails to reach the predetermined temperature rise, the treatment for restoration from poisoning of the exhaust treatment catalyst (13) is performed.

A fuel reforming system is provided. The system includes an engine combusting reformed gas to generate mechanical power and an intake line connected with the engine to supply the reformed gas and air to the engine. An exhaust line is connected with the engine to circulate exhaust gas and a fuel reformer disposed at an exhaust gas recirculation (EGR) line diverging from the exhaust line mixes the exhaust gas passing through the EGR line with fuel and reforms the mixed fuel. An exhaust gas purifying catalyst disposed at the exhaust line purifies nitrogen oxide in the exhaust gas. A temperature sensor at the exhaust line of the exhaust gas purifying catalyst measures temperature of the exhaust gas purifying catalyst. A bypass controller then operates a bypass valve to supply or cut off the exhaust gas into the fuel reformer according to temperature of the exhaust gas purifying catalyst.

An exhaust purification system of an internal combustion engine comprising an exhaust treatment catalyst (13) arranged in an engine exhaust passage and a heat and hydrogen generation device (50) able to feed only heat or heat and hydrogen to the exhaust treatment catalyst (13). When the warm-up operation of the heat and hydrogen generation device (50) is completed and a reforming action by a reformer catalyst (54) becomes possible, if the temperature of the exhaust treatment catalyst (13) is a preset activation temperature or more, a partial oxidation reaction is performed at the heat and hydrogen generation device (50) and the generated heat and hydrogen are fed to the exhaust treatment catalyst (50). At this time, if the temperature of the exhaust treatment catalyst (13) is less than the preset activation temperature, a complete oxidation reaction by a lean air-fuel ratio is continued and a heat is fed to the exhaust treatment catalyst (13).