Methods and systems for improving NOx conversion efficiency of a selective catalytic reduction catalyst are described. In one example, an amount of NH.sub.3 stored in a SCR is adjusted after stopping an engine so that a desired amount of NH.sub.3 may be stored within the SCR when the engine is restarted.

An exhaust gas purification catalyst including an alkaline-earth metal carried on a porous carrier in a highly dispersed state. The catalyst layer of the exhaust gas purification catalyst has an alkaline-earth metal carrying region including a porous carrier, Pt, and a sulfuric acid salt of at least one alkaline-earth metal carried on the porous carrier, wherein a value of R.sub.Ae/Pt is 0.5 or more, where R.sub.Ae/Pt represents the Pearson's correlation coefficient calculated using α and β in each pixel obtained by, for a cross section of the region, performing the area analysis by FE-EPMA under the conditions of: pixel size 0.34 μm×0.34 μm; and number of measured pixels 256×256; and measuring an intensity (α: cps) of a characteristic X ray of an element (Ae) of the alkaline-earth metal and an intensity (β: cps) of a characteristic X ray of Pt for each pixel.

A control system for a vehicle, the control system comprising one or more controllers, the control system being arranged to: determine a prediction of an end of a current driving cycle of the vehicle, determine a likelihood of slippage from an emissions trap of the vehicle in a next driving cycle of the vehicle in dependence on the prediction of the end of the current driving cycle, and control purging of the emissions trap prior to the prediction of the end of the current driving cycle in dependence on the likelihood of slippage.

An exhaust aftertreatment system includes a cross-flow selective catalytic reduction catalyst. The cross-flow selective catalytic reduction catalyst includes a housing and a substrate assembly. The substrate assembly includes a plurality of first substrate layers defining a plurality of first flow channels and a plurality of second substrate layers defining a plurality of second flow channels. The exhaust aftertreatment system includes a passive NO.sub.x adsorber. The passive NO.sub.x adsorber includes a housing. The housing includes an inlet in exhaust gas receiving communication with the plurality of first flow channels of the cross-flow selective catalytic reduction catalyst. The housing includes an outlet in exhaust gas providing communication with the plurality of second flow channels of the cross-flow selective catalytic reduction catalyst. The passive NO.sub.x adsorber includes a substrate positioned in the housing. The substrate includes a passive NO.sub.x adsorber washcoat.

An exhaust system comprising: a NOx storage catalyst; an electric heating element; and a NOx reduction catalyst wherein the heating element is located downstream of the NOx storage catalyst.

An internal combustion engine (1), with an engine regulating device (3) and an exhaust gas aftertreatment device (16) with an SCR catalytic converter (4) for the reduction of at least one NO.sub.x component, and with a catalytic converter regulating device (6), wherein the engine regulating device (3) is prescribed a target value for an NO.sub.x mean value of the NO.sub.x component of the exhaust gases, which mean value results at an outlet point (7) of the exhaust gas aftertreatment device (16) in relation to a predefinable time period, and the engine regulating device (3) is configured at least in one operating mode to continuously calculate an NO.sub.x reference value for the catalytic converter regulating device (6) with consideration of No.sub.x components which have already been emitted and the predefined target value, which reference value is selected in such a way that the predefined target value results at the outlet point of the exhaust gas aftertreatment device (16) at the end of the predefinable time period when the calculated NO.sub.x reference value of the catalytic converter regulating device (6) is fed as NO.sub.x setpoint value to the regulating means.

A process of reducing the content of nitrogen oxides in a gas, comprising passing the gas over a catalyst suitable for selective catalytic reduction of nitrogen oxides and in the presence of a reducing agent, wherein the catalyst is a FER-zeolite obtainable with a process which does not include a step of iron loading and does not include a step of loading with any transition metal so that said FER-zeolite does not contain ion-exchanged iron and is not loaded with iron or any transition metal.

A device for the aftertreatment of exhaust gases from an exhaust-gas source, having a spatially delimited flow path through which flow may pass proceeding from the exhaust-gas source, having a heating catalytic converter which is arranged in the flow path and which, as viewed in a flow direction, firstly has a catalytically active catalytic converter through which flow may pass and, following this in the flow direction, has an electrically heatable heating disk, wherein at least one outlet of a secondary air supply is arranged in the region of the heating catalytic converter such that a gas flow referred to as secondary air is fed into the flow path in the region of the heating catalytic converter.

A system for treatment of an exhaust gas stream from an engine is provided, containing an upstream selective catalytic reduction (SCR) catalyst, which receives the exhaust gas stream without any intervening catalyst, a diesel oxidation catalyst (DOC) positioned downstream thereof; a catalyzed soot filter (CSF) downstream of the diesel oxidation catalyst; a second SCR catalyst positioned downstream of the catalyzed soot filter; and an ammonia oxidation (AMOx) catalyst. The application also describes use of such systems to reduce nitrogen oxides (NOx) and hydrocarbons (HC) in an exhaust gas stream.

The invention provides a method of synthesizing a zeolite having the CHA crystalline framework, the method including forming a reaction mixture comprising an alumina source comprising a zeolite having an FAU crystalline framework, a silica source, and an organic structure directing agent, the reaction mixture—having a combined molar ratio of M/Si+R/Si higher than the molar ratio OH/Si, wherein M is moles of alkali metal and R is moles of organic structure directing agent; and crystallizing the reaction mixture to form a product zeolite having the CHA crystalline framework, wherein the product zeolite has a mesopore surface area (MSA) of less than about 25 m.sup.2/g. The invention also includes catalyst articles made using the product zeolite, exhaust gas treatment systems including the catalyst articles, and methods of treating exhaust gas using the catalyst articles.