The object of the present invention is to provide an exhaust gas purifying catalyst that can achieve high purification performance while suppressing H.sub.2S emissions. The object is solved by an exhaust gas purifying catalyst in which the top layer of a catalyst coating layer comprises a ceria-zirconia composite oxide having a pyrochlore-type ordered array structure, in which the ceria-zirconia composite oxide contains at least one additional element selected from the group consisting of praseodymium, lanthanum, and yttrium at 0.5 to 5.0 mol % in relation to the total cation amount, and the molar ratio of (cerium+additional element):(zirconium) is within the range from 43:57 to 48:52.

The exhaust gas purification device includes a substrate, a first catalyst layer, and a second catalyst layer. The substrate includes an upstream end, a downstream end, and a porous partition wall defining a plurality of cells extending between the upstream end and the downstream end. The plurality of cells include an inlet cell opening at the upstream end and sealed at the downstream end, and an outlet cell adjacent to the inlet cell sealed at the upstream end and opening at the downstream end. The first catalyst layer is disposed on a surface of the partition wall in an upstream region. In a downstream region, the second catalyst layer is disposed inside the partition wall, and a second catalyst-containing wall including the partition wall and the second catalyst layer has a porosity of 35% or more.

A ceramic honeycomb body, suitable for use in exhaust gas processing, includes a honeycomb structure having a plurality of through-channels, a first portion of the plurality of through-channels have a first hydraulic diameter dh1, a second portion of the plurality of through-channels have a second hydraulic diameter that is smaller than the first hydraulic diameter dh1, the first hydraulic diameter dh1 is equal to or greater than 1.1 mm, and the first and second portions of through-channels, taken together, have a geometric surface area GSA greater than 2.9 mm.sup.−1. Diesel oxidation catalysts and methods of soot removal are also provided, as are other aspects.

An exhaust after treatment system for a vehicle includes an exhaust outlet pipe, having a first end that is connectable to a vehicle engine, for receiving exhaust gases from said vehicle engine, and having an outlet opening at a second end, arranged to eject the outlet gases, a catalytic converter, connected to the exhaust outlet pipe; and an electric heater element which is in heat conducting contact with the catalytic converter and adapted for pre-heating the catalytic converter. The heater element is positioned downstream of the catalytic converter with respect to the first end. Upon the vehicle being started, the heater element is switched on and gases are flowed from the second end, in the direction of the first end of the exhaust outlet pipe, through the catalytic converter for a pre-set period of time prior to passing exhaust gases from the engine towards the outlet opening at the second end.

Synergized platinum group metals (SPGM) with ultra-low PGM loadings employed as close-coupled (CC) three-way catalysts (TWC) systems with varied material compositions and configurations are disclosed. SPGM CC catalysts in which ZPGM compositions of binary or ternary spinel structures supported onto support oxides are coupled with commercialized PGM UF catalysts and tested under Federal Test Procedure FTP-75 within TGDI and PI engines. The performance of the TWC systems including SPGM CC (with ultra-low PGM loadings) catalyst and commercialized PGM UF catalyst is compared to the performance of commercialized PGM CC and PGM UF catalysts. The disclosed TWC systems indicate that SPGM CC TWC catalytic performance is comparable or even exceeds high PGM-based conventional TWC catalysts, with reduced tailpipe emissions.

The present invention pertains to a catalyst for use in the selective catalytic reduction (SCR) of nitrogen oxides comprising a monolithic substrate and a coating A, which comprises an oxidic metal carrier comprising an oxide of titanium and a catalytic metal oxide which comprises an oxide of vanadium wherein the mass ratio vanadium/titanium is 0.07 to 0.26.

An improved NO.sub.x sensor with an NH.sub.3 oxidation catalyst. A sensor module may include a support component, a NO.sub.x sensing material positioned on the support component, and an NH.sub.3 oxidation catalyst. The NH.sub.3 oxidation catalyst may be layered on top of the NO.sub.x sensing material or the NH.sub.3 oxidation catalyst may be positioned upstream of the NO.sub.x sensing material such that the NH.sub.3 oxidation catalyst selectively converts NH.sub.3 to N.sub.2 while permitting NO.sub.x through to the NO.sub.x sensing material.

An exhaust system for an internal combustion engine, the exhaust system comprising, a lean NO.sub.x trap, and a wall flow monolithic substrate having a pre-coated porosity of 40% or greater, and comprising an oxidation catalytic zone, the oxidation catalytic zone comprising a platinum group metal loaded on a first support, the first support comprising at least one inorganic oxide and a zinc compound.

An exhaust system for an internal combustion engine, the exhaust system comprising, a lean NO.sub.x trap (LNT), a wall flow monolithic substrate having a NO.sub.x storage and reduction zone thereon, the wall flow monolithic substrate having a pre-coated porosity of 40% or greater, the NO.sub.x storage and reduction zone comprising a platinum group metal loaded on a first support, the first support comprising one or more alkaline earth metal compounds, a mixed magnesium/aluminium oxide, cerium oxide, and at least one base metal oxide selected the group consisting of copper oxide, manganese oxide, iron oxide and zinc oxide.

The presently claimed invention provides a layered three-way catalyst composition for purification of exhaust gases from internal combustion engines; said catalyst comprises a first layer comprising i) palladium supported on at least one alumina component and at least one oxygen storage component; and ii) barium oxide; wherein said first layer is essentially free of strontium, and a second layer comprising: i) rhodium supported on at least one zirconia component and/or alumina component; ii) strontium oxide and/or barium oxide; and iii) optionally, palladium supported on at least one alumina component. The presently claimed invention also provides a process for preparing the layered three-way catalyst composition which involves a technique such as incipient wetness impregnation technique(A); co-precipitation technique (B); or co-impregnation technique(C). The process includes preparing a first layer; preparing a second layer; and depositing the second layer on the first layer followed by calcination. The presently claimed invention further provides a a layered three-way catalytic article in which the three-way catalyst composition is deposited on a substrate in a layered fashion and its preparation.