Implementations of systems and methods for detecting the failure of an selective catalytic reduction (SCR) catalyst may include a controller or one or more circuits for acquiring an ammonia to NOx ratio (ANR) value for exhaust gas flowing through an exhaust system, acquiring a conversion inefficiency value indicative of a conversion inefficiency of the SCR catalyst, acquire an NH.sub.3 slip value indicative of an amount of NH.sub.3 slip through the exhaust system downstream of the SCR catalyst, calculate a combined ANR/conversion inefficiency/NH3 slip (ACN) value based on the ANR value, conversion inefficiency value, and NH.sub.3 slip value, and indicating a failure of the SCR catalyst responsive to the calculated ACN value exceeding a predetermined threshold value.

Systems and apparatuses include a circuit structured to receive information indicative of a catalyst health, receive information from a sensor array indicative of a catalyst activity, determine a catalyst health management criteria has been met based on the information, determine a catalyst age based on the information indicative of the catalyst activity and the catalyst health management criteria being met, compare the determined catalyst age to a predetermined age threshold, and provide a notification when the determined catalyst age exceeds the predetermined age threshold.

A method for diagnosing NOx sensors in an exhaust aftertreatment system includes suspending reductant dosing in an exhaust aftertreatment system; purging a reductant deposit in a selective catalytic reduction (SCR) system of the exhaust aftertreatment system; adjusting at least one of an ignition timing and an engine speed for an engine to adjust an engine out nitrogen oxide (NOx) amount; receiving measured SCR inlet NOx data from a SCR inlet NOx sensor and measured SCR outlet NOx data from a SCR outlet NOx sensor; determining a phase shift between the measured SCR inlet and SCR outlet NOx data; applying the determined phase shift to the SCR outlet NOx data; and determining a diagnostic feature based on the SCR inlet NOx data and the phase shifted SCR outlet NOx data regarding a state of the SCR inlet and outlet NOx sensors.

A method for controlling a SCR catalytic converter of a vehicle, comprising a first step of modelling said at least one SCR catalytic converter as a plurality of NH3 storage cells (cell1, cell2, . . . , celln; cell1, cell2 . . . celln, cell1, cell2, . . . , celln), a second step of controlling only a first (cell1) of said plurality of storage cells, according to feedback control based on a reference value, and a third step of adapting said reference value on the basis of a storage level of at least another storage cell of said plurality of storage cells, wherein said first storage cell is arranged at an inlet of said SCR catalytic converter according an exhaust gas circulation.

Systems and methods of reducing the emissions of vehicles having a spark ignited internal combustion engine are provided. When the exhaust temperature is less than a set point temperature, the oxygen concentration of the exhaust is increased as the exhaust passes from a first stage catalytic converter to a second stage catalytic converter. The increased oxygen content of the exhaust improves the removal efficiency of carbon monoxide and/or hydrocarbons at the second stage catalytic converter without (or with minimal) reforming nitrogen oxide compounds. The oxygen concentration of the exhaust is not increased when the exhaust temperature is greater than the set point temperature.

A method of manufacturing an on-board diagnostic (OBD) limit part and a method of testing to evaluate an OBD system. The method of manufacturing the OBD limit part includes introducing a contaminant to a selective catalytic reduction (SCR) catalyst and contacting the contaminant with the SCR catalyst for a selected period of time. The method of manufacturing utilizes a vessel, the contaminant, and the SCR catalyst. The OBD limit part is a combination of the contaminant and the SCR catalyst within the vessel. The method of testing to evaluate the OBD system includes collecting data related to an exhaust gas before and after the exhaust gas is exposed to the OBD limit part, collecting an indication provided by the OBD system, and comparing the data related to the exhaust gas and the indication provided by the OBD system. The method of testing to evaluate the OBD system utilizes a system that includes an exhaust gas source, a first and a second fluid path, the OBD limit part, and the OBD system.

Provided is a method for accurately diagnosing a degree of degradation of an oxidation catalyst. A target gas detecting element configured to output an electromotive force corresponding to a concentration of a target gas is provided downstream of a catalyst in an exhaust path of an internal combustion engine. A sum of change amounts of an electromotive force in a time-variable profile thereof after the introduction of a gas atmosphere for diagnosis into the catalyst is set as a diagnosis index value. The gas atmosphere has been intentionally created in the engine and includes a target gas having a concentration higher than the concentration of a target gas during a steady operation state of the engine. The index value is then compared with a threshold corresponding to the temperature of the catalyst to diagnosis whether degradation exceeding an acceptable degree has occurred in the catalyst.

Provided is a method for accurately diagnosing a degree of degradation of an oxidation catalyst. A target gas detecting element configured to output an electromotive force corresponding to a concentration of a target gas is provided downstream of a catalyst in an exhaust path of an internal combustion engine. A maximum change amount of an electromotive force after the introduction of a gas atmosphere for diagnosis into the catalyst is set as a diagnosis index value. The gas atmosphere has been intentionally created in the engine and includes a target gas having a concentration higher than the concentration of a target gas in a steady operation state of the engine. The index value is then compared with a threshold corresponding to the temperature of the catalyst to diagnosis whether degradation exceeding an acceptable degree has occurred in the catalyst.

In a method for the diagnosis of an exhaust gas aftertreatment system for an internal combustion engine, the exhaust gas aftertreatment system comprises at least one NOx storage catalytic converter (10) and at least one SCR catalytic converter (30) which is arranged downstream of the NOx storage catalytic converter (10). According to the invention, a regeneration of the NOx storage catalytic converter (10) is blocked and/or interrupted in order to improve the frequency and/or quality of the diagnosis of the SCR catalytic converter (30).

In the case of a method for operating an exhaust gas aftertreatment system of a motor vehicle, the exhaust gas aftertreatment system comprises at least one NOx storage catalyst (10) and at least one SCR catalyst (30). According to the invention, when an inadequate function of the NOx storage catalyst (10) or of the SCR catalyst (30) is identified, at least one auxiliary measure is initiated which leads to a reduction of the NOx emissions of the motor vehicle.