Patent classifications
F01N2570/14
EXHAUST GAS PURIFICATION CATALYST AND EXHAUST GAS PURIFICATION SYSTEM USING THE EXHAUST GAS PURIFICATION CATALYST
[Problem] Provided is an exhaust gas purification catalyst capable of exhibiting even higher exhaust gas purification performance without impairing Pd catalytic activity, and an exhaust gas purification system using the exhaust gas purification catalyst.
[Solution] Provided is an exhaust gas purification catalyst comprising a substrate and a catalyst layer provided on the substrate, said catalyst having a first section located upstream along a flow direction of the exhaust gas and a second section located downstream from the first section; the catalyst layer in the first section comprises a first catalyst layer comprising palladium and a second catalyst layer comprising rhodium and covering the first catalyst layer, wherein a pore volume proportion is 12% or more and less than 18% wherein the pore volume proportion is a proportion of a total volume of the pores, which have a pore diameter of 0.06 μm to 30.0 μm as measured by mercury press-in method and existing in the substrate and the catalyst layer in the first section to a volume of a entire first section; and a wash coat amount is 100 g/L to 190 g/L, wherein a wash coat amount is a mass per unit volume of the catalyst layer in the first section to the volume of the substrate existing in the first section.
Systems and methods for diagnosis of NOx storage catalyst
Systems, apparatuses, and methods include an upstream exhaust analysis circuit structured to determine a characteristic of an exhaust gas stream entering a nitrous oxide (NOx) storage catalyst; a prediction circuit structured to predict a downstream NOx concentration of an exhaust gas stream exiting the NOx storage catalyst based on a model of a NOx storage capacity or a dynamic response of the NOx storage catalyst; a downstream exhaust analysis circuit structured to determine a downstream NOx concentration of the exhaust gas stream exiting the NOx storage catalyst; and a comparison circuit structured to compare the predicted downstream NOx concentration to the determined downstream NOx concentration, and determine a health of the NOx storage catalyst based on the comparison.
SYSTEMS AND METHODS FOR DRY CHEMICAL REDUCTANT INSERTION IN AFTERTREATMENT SYSTEMS
A reductant insertion system for an after treatment system configured to decompose constituents of an exhaust gas, includes: a dry reductant tank configured to contain a dry reductant; a reductant delivery line configured to operatively couple the dry reductant tank to the after treatment system for delivery of the dry reductant to the after treatment system; and a pressurized gas source configured to communicate the dry reductant to the after treatment system through the reductant delivery line using pressurized gas.
SCR CATALYST HAVING EXCELLENT SULFUR TOLERANCE
Provided is an SCR catalyst for removing nitrogen oxides (NO.sub.x) from exhaust gas, comprising: 0.01-70 wt % of zeolite having an average pore size of 5 Å or more; 25-90 wt % of titanium dioxide (TiO.sub.2); and 4-10 wt % of vanadium pentoxide (V.sub.2O.sub.5). The SCR catalyst according to the present invention exhibits denitrification performance in a low-temperature area that is superior to that of a conventional SCR catalyst, has improved tolerance for a sulfur compound, and also has an excellent regeneration rate.
EXHAUST AFTERTREATMENT SYSTEM WITH THERMALLY CONTROLLED REAGENT DOSER
An exhaust aftertreatment system for use with an over-the-road vehicle is disclosed. The exhaust aftertreatment system includes a flash-boil doser mounted to an exhaust conduit and a catalyst coupled to the exhaust conduit. The flash-boil doser configured to inject heated and pressurized reducing agent into an exhaust passageway defined by the exhaust conduit for distribution throughout exhaust gases passed through the exhaust conduit. The catalyst configured to react the reducing agent with the nitrous oxide in the flow of exhaust gases to provide treated exhaust gases with a reduced nitrous oxide amount.
Exhaust gas after-treatment mixing device
The present application discloses an exhaust gas after-treatment mixing device including a casing, a mixing pipe and a partition plate fixed on a periphery of the mixing pipe. The partition plate includes a first plate on one side of the mixing pipe, a second plate on the other side of the mixing pipe and a third plate connecting the first plate and the second plate. The mixing pipe includes a first pipe portion and a second pipe portion. The first pipe portion is provided with at least two first openings located on two sides thereof, respectively. The exhaust gas after-treatment mixing device includes a first shielding plate and a second shielding plate shielding front ends of the first openings, respectively, so that most of exhaust gas needs to flow bypass the first shielding plate and the second shielding plate before entering the first openings.
Exhaust gas purification apparatus
An exhaust gas purification apparatus includes a three-way catalyst. The three-way catalyst includes a downstream catalyst layer and an upstream catalyst layer. The downstream catalyst layer is to be provided in an exhaust pipe. The downstream catalyst layer contains a noble metal material containing at least one of Pd, Rh, or Pt, and an OSC material containing at least ceria. The upstream catalyst layer is to be provided in the exhaust pipe closer to an engine than the downstream catalyst layer is. The upstream catalyst layer contains the noble metal material and the OSC material. The upstream catalyst layer contains the ceria at a content less than a content of the ceria in the downstream catalyst layer.
Mixed-metal oxide based catalysts
One or more embodiments relates to a method of catalytically converting a reactant gas mixture for pollution abatement of products of hydrocarbon fuel combustion. The method provides substituted mixed-metal oxides where catalytically active metals are substituted within the crystal lattice to create an active and well dispersed metal catalyst available to convert the reactant gas mixture. Embodiments may be used with gasoline and diesel fueled internal combustion engine exhaust, although specific embodiments may differ somewhat for each.
Method for controlling emissions of nitrogen oxides in exhaust of internal combustion engine
The invention relates to a control method that allows the mean quantity of nitrogen oxides per kilometer covered emitted by a vehicle fitted with an internal combustion engine associated with a post-treatment system to be kept below a predefined fixed threshold, for any journey made by the vehicle. The mean quantity emitted over a fixed elementary distance that has just been covered by the vehicle is calculated iteratively, together with a long-term conformity factor which is equal to the mean quantity emitted over the entire distance covered since the start of the journey. When it is found that the long-term conformity factor is above the threshold, the engine and/or the post-treatment system is regulated in such a way as to obtain, over the next fixed elementary distance, a mean quantity of nitrogen oxides per kilometer that is lower than the threshold value FC, for example equal to 90% of the threshold, whatever the engine operating point. Thus, the long-term conformity factor converges towards the threshold.
CATALYTIC WASHCOAT WITH ADDED ALUMINA FOR NOx ABATEMENT
The present disclosure provides catalyst compositions for NOx conversion and catalytic articles incorporating such catalyst compositions. Certain catalyst compositions include a zeolite with a silica-to-alumina ratio from 5 to 20 and sufficient Cu exchanged into cation sites of the zeolite such that the zeolite has a Cu/Al ratio of 0.1 to 0.5 and a CuO loading of 1 to 15 wt. %; and a copper trapping component in a concentration in the range of 1 to 20 wt. %, the copper trapping component including a plurality of particles having a particle size of about 0.5 to 20 microns. Certain catalyst compositions include, as the copper trapping component, alumina present as a plurality of alumina particles with a D.sub.90 particle size distribution in the range of 0.5 microns to 20 microns.