A catalyst system includes an oxygen storage and release material that has at least one compound of the structure YMO.sub.3+δ, where M is selected from Mn, Co, Cu, Ce, Ti, Ni, Zn, Fe and any combination thereof, and where δ is ≥0. The oxygen storage and release material is configured to allow absorption and release oxygen depending on the conditions of a reagent stream such that sufficient oxygen is maintained for the catalytic removal of at least one of incompletely combusted hydrocarbons, CO, and NO. The catalyst system is useful in a catalytic converter such that oxygen is supplied under rich combustion conditions in an engine upstream of the catalytic converter inlet and oxygen is adsorbed and absorbed under lean rich combustion conditions in the engine.

A method for controlling an internal combustion engine with a catalytic converter for exhaust-gas aftertreatment, comprising specification of a target fill level profile is proposed, which fluctuates between an upper threshold value and a lower threshold value, of at least one exhaust-gas component that can be stored in the catalytic converter, determination of a present fill level of the at least one exhaust-gas component in the catalytic converter on the basis of a theoretical catalytic converter model, and control of the internal combustion engine so as to generate an exhaust gas with a target concentration of the at least one exhaust-gas component such that a deviation between the present fill level and the present target fill level in accordance with the target fill level profile is reduced. A processing unit and a computer program product for carrying out a method of said type, and a vehicle which is configured for carrying out the method, are likewise proposed.

A three-way catalyst article, and its use in an exhaust system for internal combustion engines, is disclosed. The catalyst article for treating exhaust gas comprising: a substrate comprising an inlet end, an outlet end with an axial length L; an inlet catalyst layer beginning at the inlet end and extending for less than the axial length L, wherein the inlet catalyst layer comprises an inlet palladium component; an outlet catalyst layer beginning at the outlet end and extending for less than the axial length L, wherein the outlet catalyst layer comprises an outlet rhodium component; and wherein the outlet catalyst layer overlaps with the inlet catalyst layer.

An internal combustion engine control device and a catalyst deterioration diagnostic method according to the present invention control the amount of fuel to be supplied to an internal combustion engine such that the air-fuel ratio of the exhaust on the downstream side of the exhaust purification catalyst is alternately switched between rich and lean, measure the oxygen storage capability of the exhaust purification catalyst during a measurement period within a reversal period of the air-fuel ratio, and diagnose deterioration of the exhaust purification catalyst based on a measurement value of the oxygen storage capability. A time point at which the output of an exhaust sensor indicates that the air-fuel ratio of the exhaust on the downstream side of the exhaust purification catalyst begins to change from a vicinity of a stoichiometric air-fuel ratio to rich or lean is set as the time of end of the measurement period.

An exhaust purification system of an internal combustion engine comprises a filter trapping particulate matter in exhaust gas, a differential pressure sensor detecting a differential pressure before and after the filter or a differential pressure between a pressure in the exhaust passage and an atmospheric pressure, a temperature sensor detecting a temperature of exhaust gas, and a deposition calculating part configured to calculate an amount of particulate matter deposited at the filter. The deposition calculating part is configured to calculate a first estimated value of an amount of the particulate matter based on the differential pressure, calculate a second estimated value of an amount of the particulate matter based on an amount of increase of temperature of the exhaust gas, and calculate an amount of the particulate matter based on the first estimated value and the second estimated value.

The present disclosure provides an exhaust gas purifying catalyst that may exhibit high purification performance both in a low temperature state immediately after an engine is started and during a high-load operation. The exhaust gas purifying catalyst disclosed herein contains at least one type of noble metal purifying exhaust gas, and includes a substrate, and a catalyst coat layer formed on a surface of the substrate. The catalyst coat layer is formed to have a stack structure including a lower layer provided on the substrate and an upper layer provided on the lower layer. The lower layer contains a noble metal and an oxide having an oxygen storage capacity. A noble metal-containing surface layer portion containing a noble metal is formed in at least a part of a surface portion of the upper layer. The upper layer does not contain an oxide having the oxygen storage capacity.

A method for controlling an internal combustion engine with a catalytic converter for exhaust-gas aftertreatment, comprising specification of a target fill level profile is proposed, which fluctuates between an upper threshold value and a lower threshold value, of at least one exhaust-gas component that can be stored in the catalytic converter, determination of a present fill level of the at least one exhaust-gas component in the catalytic converter on the basis of a theoretical catalytic converter model, and control of the internal combustion engine so as to generate an exhaust gas with a target concentration of the at least one exhaust-gas component such that a deviation between the present fill level and the present target fill level in accordance with the target fill level profile is reduced. A processing unit and a computer program product for carrying out a method of said type, and a vehicle which is configured for carrying out the method, are likewise proposed.

A method for adapting modeled reaction kinetics of a reaction taking place in a catalytic converter, with model-based fill level feedback control. The method includes specifying a setpoint value for at least one fill level of at least one exhaust-gas component that can be stored in the catalytic converter; calculating at least one fill level of the catalytic converter using a signal of an exhaust-gas sensor upstream of the catalytic converter and using a catalytic converter model with at least one storage capacity and reaction kinetics of the at least one reaction taking place in the catalytic converter; setting an air-fuel mixture such that the calculated fill level approximates the specified setpoint value; ascertaining a difference between a signal of the exhaust-gas sensor upstream of the catalytic converter and a signal of an exhaust-gas sensor downstream of the catalytic converter; and deactivating the fill-level-dependent setting of the air-fuel mixture.

Disclosed are a cerium-zirconium solid solution and a preparation method therefor and an application thereof, which belong to the field of adsorbing catalyst materials. The cerium-zirconium solid solution includes a cerium-zirconium solid solution phase with a Ce.sup.3+/Ce.sup.4+ molar ratio of 0.05-0.8:1. The cerium-zirconium solid solution phase in the cerium-zirconium solid solution of the present application includes trivalent cerium ions and tetravalent cerium ions in a specific ratio. The cerium-zirconium solid solution has a high oxygen storage and release rate, a high oxygen storage and release capacity, and the cerium-zirconium solid solution during the storage and release of oxygen has a stable structure and good catalytic performance; and the catalyst containing the cerium-zirconium solid solution has good catalytic performance under different fuel ratios.

A method of controlling a heating element for providing heat to a catalyst of a catalytic converter, the method comprising: determining a catalyst performance characteristic as a function of time, and varying the amount of heating provided by the heating element in response to a change in the catalyst performance characteristic being greater than a predetermined amount.