Provided herein is a catalytic article including a catalytic coating disposed on a substrate, wherein the catalytic coating comprises a bottom coating on the substrate and a top coating layer on the bottom coating layer, one such coating layer containing a platinum group metal on a refractory metal oxide support and the other such coating layer containing a ceria-containing molecular sieve. Such catalytic articles are effective toward treating exhaust gas streams of internal combustion engines and exhibit outstanding resistance to sulfur.

A method for monitoring a gas sensor (14) which comprises two electrochemical measuring cells (20, 30) and which is arranged in an exhaust tract (10) of an internal combustion engine (11), wherein the sensor elements (20, 30) exhibit a substantially identical sensitivity towards a first gas component and a different sensitivity towards a second gas component and are insensitive towards further gas components. In an operating state in which an exhaust gas stream at the gas sensor (14) contains less of the second gas component than of the first gas component a concentration of the first gas component is calculated from each of the sensor signals from the sensor elements (20, 30) and a defect in a sensor element (20, 30) is deduced from the concentrations of the first gas component.

Provided are a novel synthesis technique for producing pure phase aluminosilicate zeolite and a catalyst comprising the phase pure zeolite in combination with a metal, and methods of using the same.

A catalyst article including a substrate with an inlet end and an outlet end, a first zone and a second zone, where the first zone comprises: a) an ammonia slip catalyst (ASC) bottom layer comprising a platinum group metal on a support; and b) an SCR layer comprising a second SCR catalyst, the SCR layer located over the ASC bottom layer; where the second zone comprises a catalyst (second zone catalyst) selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); wherein the ASC bottom layer extends into the second zone; and where the first zone is located upstream of the second zone. The ASC bottom layer may include a blend of: (1) the platinum group metal on a support and (2) a first SCR catalyst.

Provided are a novel synthesis technique for producing a metal promoted aluminosilicate zeolite having a small pore framework comprising the step of reacting a synthesis gel comprising at least one promoter metal containing zeolite, a structure directing agent and an optional additional silica source; and methods of using the same.

A catalyst article including a substrate with an inlet side and an outlet side, a first zone and a second zone, where the first zone includes an ammonia slip catalyst (ASC) comprising a platinum group metal on a support and a first SCR catalyst; where the second zone includes a catalyst selected from the group consisting of a diesel oxidation catalyst (DOC) and a diesel exotherm catalyst (DEC); and where the first zone is located upstream of the second zone. The first zone may include a bottom layer with a blend of: (1) the platinum group metal on a support and (2) the first SCR catalyst; and a top layer comprising a second SCR catalyst, the top layer located over the bottom layer.

An engine control device is provided, which includes an oxidation catalyst provided in an exhaust passage to oxidize unburned fuel within exhaust gas, a NO.sub.x catalyst provided integrally with or downstream of the oxidation catalyst, a PM filter provided in the exhaust passage downstream of the oxidation catalyst to capture fine particulate matter within the exhaust gas, a fuel injector, and a controller. When the particulate matter is accumulated by a given amount, the controller starts a PM filter regeneration control to remove the particulate matter, and after this control is started and when the accumulation amount decreases by a given amount, the controller starts a NO.sub.x catalyst regeneration control to switch between a first state in which an air-fuel ratio of the exhaust gas is a stoichiometric air-fuel ratio or less and a second state in which the air-fuel ratio is higher than the stoichiometric air-fuel ratio.

A method of synthesizing a zeolite comprising the steps of: a. preparing an admixture containing (i) at least one source of alumina, (ii) at least one source of silica, and (iii) at least one structure directing agent (SDA) in hydroxide form, wherein the admixture is essentially free of alkali metals, wherein the at least one structure directing agent (SDA) in hydroxide form is N,N-diethyl-2,6-dimethylpiperidinium; and b. heating the admixture under autogenous pressure at a temperature and with stirring or mixing for a sufficient time to crystalize hydrogen-form zeolite crystals having an AEI framework.

A method of treating exhaust gas from an internal combustion engine includes sensing a temperature of the exhaust gas with a temperature sensor, comparing the sensed temperature with a threshold temperature, injecting a first reductant into the exhaust gas at a first location if the sensed temperature is less than the threshold temperature, and injecting a second reductant having a different composition than the first reductant into the exhaust gas at a second location if the sensed temperature is greater than the threshold temperature.

Various embodiments include a method of operating a diesel engine having an exhaust tract and an SCR-combined diesel particulate filter in the exhaust tract, wherein an aqueous urea solution is introduced into the exhaust tract, and an exhaust gas recirculation apparatus having an exhaust gas recirculation conduit branching off downstream of the SCR-combined diesel particulate filter for performing a low-pressure exhaust gas recirculation comprising: measuring an NH.sub.3 concentration in exhaust gas downstream of the SCR-combined diesel particulate filter; and upon exceeding a threshold value of the measured NH.sub.3 concentration, reducing the low-pressure exhaust gas recirculation rate based at least in part on the measured NH.sub.3 concentration.