The invention concerns a process for preparing a copper-comprising microporous aluminosilicate material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, a TETA or TEPA organic complexing agent and a DABCO-C4 structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with stirring in order to obtain crystallization of said copper-comprising microporous aluminosilicate material with AFX structure.

An internal combustion engine may include an electronic control unit configured to supply additives to an exhaust gas cleaning catalyst having a temperature not more than a predetermined temperature. The electronic control unit may execute abnormality diagnosis of the exhaust gas cleaning catalyst based on an ability for cleaning exhaust gas of the exhaust gas cleaning catalyst. When preforming abnormality diagnosis of the exhaust gas cleaning catalyst having the temperature not more than the predetermined temperature, the electronic control unit may reduce the amount of the additives supplied to the exhaust gas cleaning catalyst to less than the amount supplied when abnormality diagnosis of the exhaust gas cleaning catalyst having the temperature not more than the predetermined temperature is not executed.

A method and engine arrangement are provided for monitoring components in an exhaust aftertreatment system (EATS) including a diesel oxidation catalyst (DOC), a diesel particulate filter (DPF), and a selective catalytic reduction catalyst (SCR). A first O2 level is measured at a first location between the DOC and the DPF, a second O2 level is measured at a second location downstream of the SCR, a first NOx level is measured at, the first location, a second NOx level is measured at the second location, SCR efficiency is calculated based on the first and second NOx levels, and whether the DOC, the DPP. and the SCR are functioning property is determined based on whether the first O2 level is within a first O:2 target, whether the second O2 level is within a second O2 target, and whether SCR efficiency is within an SCR efficiency target.

An engine system for internal combustion and reformation of a fuel includes an engine, and a reforming reactor. The engine comprising an intake manifold for receiving a first fuel and an exhaust manifold for releasing an exhaust gas. The reforming reactor includes a first end portion, a second end, a wall having an outer surface and an inner surface. The inner surface defines an interior cavity for receiving the first fuel, a second fuel, reactants for the first fuel, or combinations thereof. The exhaust manifold of the system is sized and shaped for receiving a portion of the reforming reactor such that the exhaust gas flows along a surface of the reforming reactor within the exhaust manifold.

An exhaust purification system of an internal combustion engine includes a catalyst arranged in an exhaust passage of the internal combustion engine, a fuel supply device supplying fuel to the catalyst through the exhaust passage, and a control device configured to control the supply of fuel by the fuel supply device. The control device is configured to calculate a concentration in exhaust gas of fuel supplied to the exhaust passage by the fuel supply device and a saturation vapor pressure concentration of the fuel and supply fuel from the fuel supply device to the catalyst only when the concentration in the exhaust gas is higher than the saturation vapor pressure concentration.

The present invention is directed to solve problems in conventional HC-SCR systems and provide cost-effective exhaust gas treatment systems with high NOx removal rates especially at low temperatures. A hydrocarbon selective catalytic reduction (HC-SCR) system in which H.sub.2 is added to a diesel oxidation catalyst (DOC) along with hydrocarbon. In other words, it can be said as an exchange gas purification method including removing NOx from an exhaust gas by adding H.sub.2 to a diesel oxidation catalyst (DOC) along with hydrocarbon in a hydrocarbon selective catalytic reduction (HC-SCR) system.

The invention concerns a process for preparing a copper-comprising microporous aluminosilicate material with AFX structure, comprising at least the steps of mixing, in an aqueous medium, at least one aluminum source, at least one silicon source, at least one copper source, a TETA or TEPA organic complexing agent and a DABCO-C4 structuring agent, in order to obtain a gel, and hydrothermal treatment of said gel with stirring in order to obtain crystallization of said copper-comprising microporous aluminosilicate material with AFX structure.

An exhaust treatment catalyst (5) is arranged in the engine exhaust passage, and hydrogen generated in the reformer (6) is supplied through the hydrogen supply pipe (13) to the inside of the engine exhaust passage upstream of the exhaust treatment catalyst (5). Heat exchange fins (15) for heat exchange with exhaust gas flowing through the inside of the engine exhaust passage are formed on the outer circumferential surface of the hydrogen supply pipe (13) inserted inside the engine exhaust passage.

An exhaust purification system of an internal combustion engine provided with a heat and hydrogen generation device (50) and an exhaust purification catalyst (14) comprised of the three way catalyst. Heat and hydrogen generated in the heat and hydrogen generation device (50) is fed to the exhaust purification catalyst (14). When an air-fuel ratio of the air and fuel made to burn in the heat and hydrogen generation device (50) is made a predetermined target set air-fuel ratio, the air-fuel ratio of the exhaust gas discharged from the engine is controlled to the target adjusted air-fuel ratio required for making the air-fuel ratio of the gas flowing into the exhaust purification catalyst (14) the stoichiometric air-fuel ratio.

An integrated vehicle on-board system configured to generate hydrogen and to introduce the generated hydrogen into an exhaust gas stream of an internal combustion engine, the system including a water-splitting article configured to split water into hydrogen and oxygen and a hydrogen injection article configured to introduce the hydrogen into the exhaust gas stream, is effective for the abatement of carbon monoxide and/or hydrocarbons and/or nitrogen oxides. The introduction of hydrogen may be intermittent and/or during a cold-start period.