Methods of contacting a fluid comprising a light hydrocarbon with a metal-organic framework adsorbent having bis(pyrazolyl) ethanediimine ligands and internal pores; adsorbing the fluid in at least a portion of the internal pores of the metal-organic framework thereby creating an adsorbed fluid; storing the adsorbed fluid in the internal pores of the metal-organic framework; and releasing the adsorbed fluid from the internal pores of the metal-organic framework, wherein the metal-organic framework adsorbent undertakes a reversible phase transition upon adsorbing the fluid. Systems of a metal-organic framework having bis(pyrazolyl) ethanediimine ligands and internal pores, wherein the metal-organic framework undertakes a reversible phase transition upon adsorption and desorption of a light hydrocarbon fluid; wherein the fluid is stored in the internal pores of the metal-organic framework.

Provided are methods for storing a gas. An example method comprises providing a vessel containing a manifold system and an adsorbent, the manifold system comprising: a gas tubing, a filter disposed over openings in the gas tubing, a pressure relief valve, and an inlet coupled to the gas tubing and the vessel. The method further comprises introducing the gas into the manifold system via the inlet; circulating the gas in the gas tubing; flowing the gas through the openings in the gas tubing; and adsorbing the gas onto the adsorbent.

The invention relates to a power distribution system (1), especially a Power-over-Ethernet system, comprising at least one dominant sensor, which may be located within a powered device (4) like a lighting device, and at least one non-dominant sensor, which may be located within another powered device (4), wherein the power distribution system is adapted such that in a system low power mode the at least one dominant sensor (6) consumes power provided by a power providing unit (3) and the at least one non-dominant sensor (6) does not consume the provided power and that the power distribution system (1) switches from the system low power mode to a system high power mode, if the at least one dominant sensor (6) has sensed an event. Since in the system low power mode the at least one non-dominant sensor does not consume power, the power consumption can be reduced.

Systems and methods for heat exchange during gas adsorption and desorption cycling, one method including removing heat from an adsorbent material during gas adsorption to the adsorbent material; storing the removed heat for later use during desorption of gas from the adsorbent material; heating the adsorbent material during desorption of gas from the adsorbent material using at least a portion of the removed heat; and recycling heat during the step of heating to prepare a working fluid for the step of removing heat via temperature reduction of the working fluid.

A gas storage/supply system includes a gas storage material capable of reversibly absorbing and desorbing a gas, a gas storage tank having the gas storage material sealed therein, a chemical heat storage material capable of making a forward reaction and a reverse reaction with an operation medium, a chemical heat storage tank having the chemical heat storage material sealed therein, a heat exchange mechanism for transferring heat between the gas storage tank and the chemical heat storage tank, and a control mechanism for controlling the gas storage/supply system such that gas absorption heat released upon absorption of the gas to the gas storage material is stored in the chemical heat storage tank and gas desorption heat which is necessary for desorption of the gas from the gas storage material is supplied from the chemical heat storage tank.

An evaporated fuel processing device for processing evaporated fuel generated in a fuel tank includes a hollow case and an elastic adsorption member press-fit in the hollow case. The elastic adsorption member has a rectangular prismatic block shape. The elastic adsorption member includes an air-permeable elastic body and constituent granules of a granular adsorbent material disposed in the air-permeable elastic body. The constituent granules of a granular adsorbent material are configured to adsorb and desorb evaporated fuel.

The invention is related to a storage vessel (1) comprising a shaped body (3) of a porous solid, wherein the storage vessel (1) comprises a wall (5) with a section (7) comprising at least one inlet (9), wherein the storage vessel (1) has a central axis (11) and the central axis (11) is a longitudinal axis of the storage vessel (1) and/or perpendicular to a cross-sectional area of the at least one inlet (9), wherein the shaped body (3) covers at least 85% of an inner volume (13) of the storage vessel (1) and the shaped body (3) comprises an opening (19) in an axial direction (17), axial referring to the central axis (11) of the storage vessel (1), wherein the opening (19) extends from a first end (21) of the shaped body (3) to an opposing second end (23) of the shaped body (3) and wherein the storage vessel (1) comprises exactly one shaped body (3), which is formed in one piece. The invention is further related to a shaped body and use of the shaped body.

A method of storing gas comprises providing a recipient for receiving the gas and providing a porous gas storage material. The gas storage material comprises a cross-linked polymeric framework and a plurality of pores for gas sorption. The cross-linked polymeric framework comprises aromatic ring-containing monomeric units comprising at least two aromatic rings. The aromatic ring-containing monomeric units are linked by covalent cross-linking between aromatic rings to form a stable, rigid nanoporous material for storing the gas at pressures significantly greater than the atmospheric pressure, for example in excess of 100 bar. A possible application is the storage and transportation of compressed natural gas.

Mesoporous membranes have shown promising separation performance with a potential to lower the energy consumption, leading to a dramatic cost reduction. Recently, an extensive effort has been made on the design of membranes which brought a significant progress toward the synthesis of well-defined porous morphologies, most of which synthesized by surfactant-template methodology. Currently, the most well-designed state-of-the-art membranes using this technique are made from metals, polymers, carbon, silica, etc. In the present invention, we demonstrate mesoporous calcium-silicate particles having superior separation capacity and optimal permeability, thereby leading to reduced energy consumption for selective separation of gases/liquids and/or the combination thereof. We explore various methods to improve the calcium-silicate membranes properties by tuning pore density during the synthesis/aging process, while favoring the formation of uniformly distributed nanopores. Lowering particle density by controlling calcium to silicon ratio along with optimizing the surface area are essential in achieving our objective.

The present disclosure provides for a porous gas sorbent monolith with superior gravimetric working capacity and volumetric capacity, a gas storage system including a porous gas sorbent monolith of the present disclosure, methods of making the same, and method for storing a gas. The porous gas sorbent monolith includes a gas adsorbing material and a non-aqueous binder.